亲水基团性质对双亲性壳聚糖衍生物单分子膜性能的影响

doi:10.16085/j.issn.1000-6613.2015.02.029

化工进展 ›› 2015, Vol. 34 ›› Issue (02): 490-494,499.DOI: 10.16085/j.issn.1000-6613.2015.02.029

亲水基团性质对双亲性壳聚糖衍生物单分子膜性能的影响

毛扬帆, 辛梅华, 李明春

华侨大学材料科学与工程学院, 环境友好功能材料教育部工程中心, 福建厦门 361021

收稿日期:2014-05-22 修回日期:2014-06-17 出版日期:2015-02-05 发布日期:2015-02-05
通讯作者: 李明春,教授,博士生导师,研究方向为功能高分子材料研究。E-mail:mcli@hqu.edu.cn
作者简介:毛扬帆(1985-),女,博士研究生
基金资助:
福建省重点科技项目(2009H0030)、福建省自然科学基金(2011J01312,2012J01396)及科技部科技人员服务企业项目(2009GJC40030)

Effect of hydrophilic group on monolayer propertie of N,N-dilauryl chitosan derivatives

MAO Yangfan, XIN Meihua, LI Mingchun

College of Material Science and Engineering, Huaqiao University, Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Xiamen 361021, Fujian, China

Received:2014-05-22 Revised:2014-06-17 Online:2015-02-05 Published:2015-02-05

摘要/Abstract

摘要： 制备了双亲性O-磺化-N,N-双十二烷基壳聚糖(HSDLCS)、O-季铵化-N,N-双十二烷基壳聚糖(QADLCS)和O-羟丙基-N,N-双十二烷基壳聚糖(HPDLCS),研究了不同亲水基团对产物单分子膜性能的影响。结果表明,与N,N-双十二烷基壳聚糖(DLCS)相比,引入亲水基团后的产物其单分子膜具有较高的崩溃压(π_c)和最大压缩模量(C_s^-1,_max),凝聚性更好。与非离子型产物HPDLCS相比,离子型产物具有较大的π_c和C_s^-1,_max,其中阴离子型产物HSDLCS单分子膜的π_c(44.64mN/m)和C_s^-1,_max(84.27mN/m)最大,阳离子型产物QADLCS(π_c,42.01mN/m;C_s^-1,_max,82.99mN/m)次之,HSDLCS单分子膜具有较强的凝聚性和抗形变能力。

关键词: 壳聚糖, 亲水基团, 烷基化, 双亲性, 单分子膜

Abstract: O-sulfonated-N,N-dilauryl chitosan (HSDLCS),O-quaternized-N,N-dilauryl chitosan (QADLCS) and O-hydroxypropyl-N,N-dilauryl chitosan (HPDLCS) with similar substitution were synthesized. The effect of hydrophilic group on monolayer properties of N,N-dilauryl chitosan derivatives was studied. Experimental results indicated that monolayers of N,N-dilauryl chitosan derivatives with different hydrophilic group had larger collapse pressure π_c and maximum compression modulus (C_s^-1,_max) compared with N,N-dilauryl chitosan and also had better cohesion. Inonic products had larger collapse pressure π_c and maximum compression modulus (C_s^-1,_max) compared with nonionic product HPDLCS. Anionic HSDLCS monolayer had largest π_c (44.64mN/m)and C_s^-1,_max (84.27mN/m)among three products,and cationic QADLCS had second largest π_c (42.01mN/m) and C_s^-1,_max (82.99mN/m). HSDLCS monolayer had stronger cohesion and resistance to deformation capacity.

Key words: chitosan, hydrophilic group, dialkylated, amphiphilic, monolayers

中图分类号:

O636.1

毛扬帆, 辛梅华, 李明春. 亲水基团性质对双亲性壳聚糖衍生物单分子膜性能的影响[J]. 化工进展, 2015, 34(02): 490-494,499.

MAO Yangfan, XIN Meihua, LI Mingchun. Effect of hydrophilic group on monolayer propertie of N,N-dilauryl chitosan derivatives[J]. Chemical Industry and Engineering Progree, 2015, 34(02): 490-494,499.

参考文献

[1] Du Hongliang,Yang Xiaoye,Pang Xin,et al. The synthesis,self-assembling,and biocompatibility of a novel O-carboxymethyl chitosan cholate decorated with glycyrrhetinic acid[J]. Carbohydrate Polymers,2014,111:753-761.
[2] Larsson Mikael,Huang Wei-Chen,Hsiao Meng-Hsuan,et al. Biomedical applications and colloidal properties of amphiphilically modified chitosan hybrids[J]. Progress in Polymer Science,2013,38:1307-1328.
[3] Chen Chen,Cai Guoqiang,Zhang Haiwen,et al. Chitosan-poly(ε-caprolactone)-poly(ethylene glycol) graft copolymers:Synthesis,self-assembly,and drug release behavior[J]. Journal of Biomedical Materials Research A,2011,96(1):116-124.
[4] Li Yanyan,Zhang Shanshan,Meng Xiangjun,et al. The preparation and characterization of a novel amphiphilic oleoyl-carboxymethyl chitosan self-assembled nanoparticles[J]. Carbohydrate Polymers,2011,83:130-136.
[5] Wang Chee-Chan,Lin Li-Huei,Lee Hsun-Tsing,et al. Surface activity and micellization properties of chitosan-succinyl derivatives[J]. Colloids and Surfaces A:Physicochem. Eng. Aspects,2011,389:246-253.
[6] Youngjin Cho,Jun Tae Kim,Hyun Jin Park,et al. Preparation,characterization,and protein loading properties of N-acyl chitosan nanoparticles[J]. Journal of Applied Polymer Science,2012,124:1366-1371.
[7] 关品燊,辛梅华,李明春,等. O-季铵化-N,N-双烷基壳聚糖的单分子膜性质研究[J]. 化工进展,2011,30(12):2671-2675.
[8] 明如镜,辛梅华,李明春,等. O-季铵化-N,N-双十二烷基壳聚糖/胆固醇的混合单分子膜性质研究[J]. 材料研究学报,2010,34(3):254-258.
[9] Cheng Zhenhua,Huang Jun,Hu Sheng,et al. Effects of hydroxypropyl degree on physiochemical activities of chitosan from squid pens[J]. International Journal of Biological Macromolecules,2014,65:246-251.
[10] Xu Tao,Xin Meihua,Li Mingchun,et al. Synthesis,characterization,and antibacterial activity of N,O-quaternary ammonium chitosan[J]. Carbohydrate Research,2011,346:2445-2450.
[11] 高兴爽,刘万顺,韩宝芹,等. 羟丙基壳聚糖的制备、表征及其对角膜细胞生长的影响[J]. 中国海洋大学学报,2007,37(s2):131-134.
[12] Yin Qiang,Li Yan,Yin Qinjian,et al. Synthesis and rheological behavior of a novel N-sulfonate ampholyte chitosan[J]. Journal of Applied Polymer Science,2009,113:3382-3387.
[13] Zhang Qun,Zhao Hui Zhou,Dong Linfang,et al. Dilational rheological properties of sulphobetaines at the water-decane interface:Effect of hydrophobic group[J]. Colloids and Surfaces A: Physicochem. Eng. Aspects,2014,455:97-103.
[14] 王晓燕,卢祥国,姜维东. 正负离子和表面活性剂对水解聚丙烯酰胺分子线团尺寸的影响及其作用机理[J]. 高分子学报,2009(12):1259-1265.
[15] Huang Yun-Chiao,Jan Jeng-Shiung. Carboxylmethyl chitosan-graft-poly(γ-benzyl-L-glutamate) glycopeptides:Synthesis and particle formation as encapsulants[J]. Polymer,2014,55:540-549.
[16] Zhang Renjie,Li Wenhua,Mohwald Helmuth,et al. Shell modulation by tailoring substituents in chitosan for LbL-assembled microcapsules[J]. Journal of Colloid and Interface Science,2012,372:40-44.
[17] Fajardo André R,Piai Juliana F,Rubira Adley F,et al. Time-and pH-dependent self-rearrangement of a swollen polymer network based on polyelectrolytes complexes of chitosan/chondroitin sulfate[J]. Carbohydrate Polymers,2010,80:934-943.
[18] 刘金彦,廖永娟. 季铵盐二聚表面活性剂C₁₂-S₂-C₁₂·2Br复配体系在氯仿中形成反胶团的增溶水状态[J]. 应用化学,2013,30(7):846-851.

亲水基团性质对双亲性壳聚糖衍生物单分子膜性能的影响

Effect of hydrophilic group on monolayer propertie of N,N-dilauryl chitosan derivatives

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