正渗透过程中汲取质反向渗透研究进展

doi:10.16085/j.issn.1000-6613.2015.10.004

化工进展 ›› 2015, Vol. 34 ›› Issue (10): 3540-3550.DOI: 10.16085/j.issn.1000-6613.2015.10.004

正渗透过程中汲取质反向渗透研究进展

谢朋¹, 张忠国¹, 孙涛¹, 吴月¹, 吴秋燕¹, 李继定², 李珊¹

1 轻工业环境保护研究所, 北京 100089;
2 清华大学化学工程系化学工程国家重点联合实验室, 北京 100084

收稿日期:2014-11-04 修回日期:2015-03-25 出版日期:2015-10-05 发布日期:2015-10-05
通讯作者: 张忠国,男,博士,研究员,从事废水深度处理技术研究工作。E-mailcn.zhang@163.com。
作者简介:谢朋(1989—),男,硕士研究生,从事膜分离技术研究工作。
基金资助:
国家科技部“科研院所技术开发研究专项资金”项目(2011EG111022,2012EG111122,2013EG111129)、国家质量监督检验检疫总局“公益性行业科研专项经费”项目(201310289-3)、北京市科学技术研究院创新团队项目(IG201204N)、海外人才专项资助项目(OTP-2013-015)及科技创新工程项目(II-3)。

Research progress of reverse draw solute permeation in forward osmosis process

XIE Peng¹, ZHANG Zhongguo¹, SUN Tao¹, WU Yue¹, WU Qiuyan¹, LI Jiding², LI Shan¹

1 Environmental Protection Research Institute of Light Industry, Beijing 100089, China;
2 State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Received:2014-11-04 Revised:2015-03-25 Online:2015-10-05 Published:2015-10-05

摘要/Abstract

摘要： 正渗透(FO)作为一种浓度驱动的膜技术,因其膜污染轻、能耗低和回收率高等优点而逐渐成为膜技术领域的研究热点之一。汲取质的反向渗透是正渗透过程中不可忽视的现象,但其研究相对比较滞后。本文主要介绍了汲取质反渗模型的研究进展,分析了渗透压差、膜表面流速、膜结构与膜材料、温度、汲取质种类、膜取向、离子水力半径等因素对汲取质反向渗透的影响情况,并发现汲取质的反向渗透通量可由其浓度或汲取液渗透压的一元多项式表达。总体而言,FO模式的汲取质反渗模型经过不断发展已相对比较完善,而压力阻尼渗透(PRO)模式的反渗模型则缺陷较大,有待进一步研究;此外,关于汲取质反渗过程影响因素及其影响机制的研究对于汲取质、膜材料的选择与开发,以及正渗透过程的优化均具有重要的指导作用,因此会引起越来越多的关注。

关键词: 正渗透, 压力阻尼渗透, 汲取质, 汲取液, 反向渗透, 浓差极化

Abstract: As a concentration-driven membrane process, forward osmosis (FO) is becoming one of the hot spots in the field of membrane technology because of its low fouling, low energy consumption, and high water recovery. Reverse draw solute permeation is a significant phenomenon in FO process, but the research on it is behind other phenomena in FO field. In this paper, the research progress of draw solute reverse osmosis models is reviewed and the effects of such factors as osmosis pressure, membrane surface velocity, membrane structure and materials, solution temperature, draw solute type, membrane orientation, and ionic radius of draw solute on reverse osmosis are analyzed. Draw solute flux can be formulated by a one-dimensional polynomial equation of concentration or osmotic pressure of draw solution. On the whole, the reverse draw solute model of pressure-retarded osmosis (PRO) mode is not as satisfactory as that of FO mode and needs further research. In addition, the research on reverse draw solute permeation is helpful for selecting or developing draw solute and membrane material and optimizing the FO process, so it would attract more and more attention.

Key words: forward osmosis (FO), pressure-retarded osmosis (PRO), draw solute, draw solution, reverse permeation, concentration polarization

中图分类号:

X703.1

谢朋, 张忠国, 孙涛, 吴月, 吴秋燕, 李继定, 李珊. 正渗透过程中汲取质反向渗透研究进展[J]. 化工进展, 2015, 34(10): 3540-3550.

XIE Peng, ZHANG Zhongguo, SUN Tao, WU Yue, WU Qiuyan, LI Jiding, LI Shan. Research progress of reverse draw solute permeation in forward osmosis process[J]. Chemical Industry and Engineering Progree, 2015, 34(10): 3540-3550.

参考文献

[1] Bharadwaj R,Singh D,Mahapatra A. Seawater desalination technologies[J]. International Journal of Nuclear Desalination,2008,3(2):151-159.

[2] Paul D. Microelectronics water treatment system overview[J]. Ultrapure Water,2009,26(5):38-40.

[3] Melo M,Schluter H,Ferreira J,et al. Advanced performance evaluation of a reverse osmosis treatment for oilfield produced water aiming reuse[J]. Desalination,2010,250(3):1016-1018.

[4] McCutcheon J R,McGinnis R L,Elimelech M. A novel ammonia-carbon dioxide forward (direct) osmosis desalination process[J]. Desalination,2005,174(1):1-11.

[5] McCutcheon J R,McGinnis R L,Elimelech M. Desalination by ammonia-carbon dioxide forward osmosis:Influence of draw and feed solution concentrations on process performance[J]. Journal of Membrane Science,2006,278(1):114-123.

[6] Kravath R E,Davis J A. Desalination of sea water by direct osmosis[J]. Desalination,1975,16(2):151-155.

[7] Tan C H,Ng H Y. A novel hybrid forward osmosis-nanofiltration (FO-NF) process for seawater desalination:Draw solution selection and system configuration[J]. Desalination and Water Treatment,2010,13(1-3):356-361.

[8] Choi J S,Kim H,Lee S,et al. Theoretical investigation of hybrid desalination system combining reverse osmosis and forward osmosis[J]. Desalination and Water Treatment,2010,15(1-3):114-120.

[9] Achilli A,Cath T Y,Marchand E A,et al. The forward osmosis membrane bioreactor:A low fouling alternative to MBR processes[J]. Desalination,2009,239(1):10-21.

[10] Holloway R W,Childress A E,Dennett K E,et al. Forward osmosis for concentration of anaerobic digester centrate[J]. Water Research,2007,41(17):4005-4014.

[11] Cornelissen E R,Harmsen D,De Korte K F,et al. Membrane fouling and process performance of forward osmosis membranes on activated sludge[J]. Journal of Membrane Science,2008,319(1):158-168.

[12] Cartinella J L,Cath T Y,Flynn M T,et al. Removal of natural steroid hormones from wastewater using membrane contactor processes[J]. Environmental Science & Technology,2006,40(23):7381-7386.

[13] Petrotos K B,Quantick P,Petropakis H. A study of the direct osmotic concentration of tomato juice in tubular membrane-module configuration. I. The effect of certain basic process parameters on the process performance[J]. Journal of Membrane Science,1998,150(1):99-110.

[14] Petrotos K B,Quantick P C,Petropakis H. Direct osmotic concentration of tomato juice in tubular membrane-module configuration. II. The effect of using clarified tomato juice on the process performance[J]. Journal of Membrane Science,1999,160(2):171-177.

[15] Garcia-Castello E M,McCutcheon J R,Elimelech M. Performance evaluation of sucrose concentration using forward osmosis[J]. Journal of membrane science,2009,338(1):61-66.

[16] Lee K L,Baker R W,Lonsdale H K. Membranes for power generation by pressure-retarded osmosis[J]. Journal of Membrane Science,1981,8(2):141-171.

[17] SeppaÈlaÈ A,Lampinen M J. Thermodynamic optimizing of pressure-retarded osmosis power generation systems[J]. Journal of Membrane Science,1999,161(1):115-138.

[18] Achilli A,Cath T Y,Childress A E. Power generation with pressure retarded osmosis:An experimental and theoretical investigation[J]. Journal of Membrane Science,2009,343(1):42-52.

[19] Cath T Y,Childress A E,Elimelech M. Forward osmosis:Principles,applications,and recent developments[J]. Journal of Membrane Science,2006,281(1):70-87.

[20] Phillip W A,Yong J S,Elimelech M. Reverse draw solute permeation in forward osmosis:modeling and experiments[J]. Environmental Science & Technology,2010,44(13):5170-5176.

[2

[1] Hancock N T,Cath T Y. Solute coupled diffusion in osmotically driven membrane processes[J]. Environmental Science & Technology,2009,43(17):6769-6775.

[22] Cath T Y,Childress A E,Elimelech M. Forward osmosis:principles,applications,and recent developments[J]. Journal of Membrane Science,2006,281(1):70-87.

[23] Loeb S,Titelman L,Korngold E,et al. Effect of porous support fabric on osmosis through a Loeb-Sourirajan type asymmetric membrane[J]. Journal of Membrane Science,1997,129(2):243-249.

[24] Tang C Y,She Q,Lay W C L,et al. Coupled effects of internal concentration polarization and fouling on flux behavior of forward osmosis membranes during humic acid filtration[J]. Journal of Membrane Science,2010,354(1):123-133.

[25] Gray G T,McCutcheon J R,Elimelech M. Internal concentration polarization in forward osmosis:role of membrane orientation[J]. Desalination,2006,197(1):1-8.

[26] Yong J S,Phillip W A,Elimelech M. Coupled reverse draw solute permeation and water flux in forward osmosis with neutral draw solutes[J]. Journal of Membrane Science,2012,392:9-17.

[27] Suh C,Lee S. Modeling reverse draw solute flux in forward osmosis with external concentration polarization in both sides of the draw and feed solution[J]. Journal of Membrane Science,2013,427:365-374.

[28] Song X,Liu Z,Sun D D. Nano gives the answer:breaking the bottleneck of internal concentration polarization with a nanofiber composite forward osmosis membrane for a high water production rate[J]. Advanced Materials,2011,23(29):3256-3260.

[29] Mehta G D,Loeb S. Performance of permasep B-9 and B-10 membranes in various osmotic regions and at high osmotic pressures[J]. Journal of Membrane Science,1979,4:335-349.

[30] Zou S Z A L. Relating solution physicochemical properties to internal concentration polarization in forward osmosis[J]. Jornal of Mmbrane Science,2011,(1-2):459-467.

[3

[1] Gray G T,McCutcheon J R,Elimelech M. Internal concentration polarization in forward osmosis:Role of membrane orientation[J]. Desalination,2006,197(1):1-8.

[32] McCutcheon J R,Elimelech M. Influence of concentrative and dilutive internal concentration polarization on flux behavior in forward osmosis[J]. Journal of Membrane Science,2006,284(1):237-247.

[33] Ng H Y,Tang W,Wong W S. Performance of forward (direct) osmosis process:Membrane structure and transport phenomenon[J]. Environmental Science & Technology,2006,40(7):2408-2413.

[34] Chanukya B S,Patil S,Rastogi N K. Influence of concentration polarization on flux behavior in forward osmosis during desalination using ammonium bicarbonate[J]. Desalination,2013,312:39-44.

[35] Tiraferri A,Yip N Y,Straub A P,et al. A method for the simultaneous determination of transport and structural parameters of forward osmosis membranes[J]. Journal of Membrane Science,2013,444:523-538.

[36] Gu B,Kim D Y,Kim J H,et al. Mathematical model of flat sheet membrane modules for FO process:Plate-and-frame module and spiral-wound module[J]. Journal of Membrane Science,2011,379(1):403-415.

[37] Xiao D,Tang C Y,Zhang J,et al. Modeling salt accumulation in osmotic membrane bioreactors:Implications for FO membrane selection and system operation[J]. Journal of Membrane Science,2011,366(1):314-324.

[38] Tang C Y,She Q,Lay W C L,et al. Modeling double-skinned FO membranes[J]. Desalination,2011,283:178-186.

[39] 边丽霞,方彦彦,王晓琳. 正渗透过程中水与溶质的传递现象[J]. 化工学报,2014,65(7):2813-2820.

[40] 吴晴. 正渗透过程中驱动溶质反渗规律研究[D]. 哈尔滨:哈尔滨工业大学,2013

[41] Gruber M F,Johnson C J,Tang C Y,et al. Computational fluid dynamics simulations of flow and concentration polarization in forward osmosis membrane systems[J]. Journal of Membrane Science,2011,379(1):488-495.

[42] Sagiv A,Semiat R. Finite element analysis of forward osmosis process using NaCl solutions[J]. Journal of Membrane Science,2011,379(1):86-96.

[43] Su J,Chung T S. Sublayer structure and reflection coefficient and their effects on concentration polarization and membrane performance in FO processes[J]. Journal of Membrane Science,2011,376(1):214-224.

[44] Lu X,Boo C,Ma J,et al. Bidirectional diffusion of ammonium and sodium cations in forward osmosis:Role of membrane active layer surface chemistry and charge[J]. Environmental Science & Technology,2014,48(24):14369-14376.

[45] Boo C,Khalil Y F,Elimelech M. Performance evaluation of trimethylamine-carbon dioxide thermolytic draw solution for engineered osmosis[J]. Journal of Membrane Science,2015,473:302-309.

[46] 宗同强,赵玉宏,李娜. 正渗透膜成分与结构分析[J]. 广州化学,2013,38(2):37-41.

[47] 李海军,张捍民,杨凤林. 对称正渗透膜制备及膜性能表征[J]. 环境科学与技术,2013,36(12):10-14.

[48] Wang K Y,Ong R C,Chung T S. Double-skinned forward osmosis membranes for reducing internal concentration polarization within the porous sublayer[J]. Industrial & Engineering Chemistry Research,2010,49(10):4824-4831.

[49] Yang Q,Wang K Y,Chung T S. Dual-layer hollow fibers with enhanced flux as novel forward osmosis membranes for water production[J]. Environ. Sci. Technol.,2009,43:2800-2805.

[50] Fang Y,Bian L,Wang X. Understanding membrane parameters of a forward osmosis membrane based on nonequilibrium thermodynamics[J]. Journal of Membrane Science,2013,437:72-81.

[51] 吴秋燕,张忠国,杨柳,等.正渗透汲取液的研究进展[J]. 环境科学与技术,2015,38(6):139-145.

[52] Tan C H,Ng H Y. Modified models to predict flux behavior in forward osmosis in consideration of external and internal concentration polarizations[J]. Journal of Membrane Science,2008,324:209-219.

[53] Mi B,Elimelech M. Chemical and physical aspects of organic fouling of forward osmosis membranes[J]. Journal of Membrane Science,2008,320:292-302.

[54] Qin J J,Kekre K A,Oo M H,et al. Preliminary study of osmotic membrane bioreactor:Effects of draw solution on water flux and air scouring on fouling[J]. Water Science & Technology,2010,62(6):1353-1360.

[55] Tang C Y,She Q,Lay W C L,et al. Coupled effects of internal concentration polarization and fouling on flux behavior of forward osmosis membranes during humic acid filtration[J]. Journal of Membrane Science,2010,354(1):123-133.

[56] 张朝章. 关于唐南(Donnan)平衡的讨论[J]. 安徽大学学报:自然科学版,1986,(1):35-44.

正渗透过程中汲取质反向渗透研究进展

Research progress of reverse draw solute permeation in forward osmosis process

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 13

编辑推荐

Metrics

本文评价

[1]	刘翔, 何林, 从海峰, 隋红, 李鑫钢. 双胺“可逆”溶剂强化正渗透脱盐及过程优化[J]. 化工进展, 2022, 41(11): 6158-6166.
[2]	朱腾义, 曹再植. 正渗透-膜蒸馏耦合工艺在高难度废水处理中的应用研究进展[J]. 化工进展, 2021, 40(11): 5894-5906.
[3]	罗方, 王晶, 姚之侃, 张林, 陈欢林. 正渗透膜特征参数测试方法研究进展[J]. 化工进展, 2021, 40(1): 31-38.
[4]	汤依莲, 李士洋, 孙志娟, 高从堦, 薛立新. 具有三维聚酰胺脱盐网络结构的无纺布复合正渗透膜[J]. 化工进展, 2020, 39(12): 5170-5181.
[5]	方丽瑶,吕慧,付佳蓓,左浩然,刘慧清,曹贵平. 聚苯乙烯磺酸钠掺杂正渗透膜的制备及其性能[J]. 化工进展, 2019, 38(10): 4684-4692.
[6]	李猛, 姚宇健, 张轩, 王连军. 薄层复合膜的纳米改性：设计、制备及应用[J]. 化工进展, 2019, 38(01): 365-381.
[7]	肖芹芹, 徐世昌, 王越, 王红柳. 正渗透膜污染影响因素的研究与分析[J]. 化工进展, 2018, 37(01): 359-367.
[8]	胡念, 左浩然, 付佳蓓, 吕慧, 童奕皓, 刘慧清, 曹贵平. 石墨烯掺杂聚砜基正渗透膜的结构和性能[J]. 化工进展, 2017, 36(12): 4524-4532.
[9]	高婷婷, 解利昕, 徐世昌, 冯丽媛, 杜亚威, 周晓凯. 碳酸氢铵为汲取液正渗透海水淡化研究[J]. 化工进展, 2017, 36(06): 2051-2056.
[10]	马岩红1，丁昀1，杨庆1，2，3，李鹏1. 正渗透膜材料的研究进展[J]. 化工进展, 2014, 33(12): 3299-3303.
[11]	解利昕，辛婧，解奥. 三乙酸纤维素正渗透膜的制备与性能[J]. 化工进展, 2014, 33(10): 2700-2706.
[12]	施人莉，杨庆峰. 正渗透膜分离的研究进展 [J]. 化工进展, 2011, 30(1): 66-.
[13]	李刚1，李雪梅1，王铎2，何涛1，高从堦2. 正渗透膜技术及其应用 [J]. 化工进展, 2010, 29(8): 1388-.