碳四烷烃化合物催化氧化的技术研究进展

doi:10.16085/j.issn.1000-6613.2016.06.016

化工进展 ›› 2016, Vol. 35 ›› Issue (06): 1758-1765.DOI: 10.16085/j.issn.1000-6613.2016.06.016

碳四烷烃化合物催化氧化的技术研究进展

周贤太^1,2, 罗庆金³, 胡先念³, 纪红兵^1,2

1. 中山大学化学与化学工程学院, 广东广州 510275;
2. 中山大学惠州研究院, 广东惠州 516081;
3. 惠州宇新化工有限责任公司, 广东惠州 516081

收稿日期:2016-02-01 修回日期:2016-03-05 出版日期:2016-06-05 发布日期:2016-06-05
通讯作者: 纪红兵,教授,博士生导师。E-mail:jihb@mail.sysu.edu.cn。
作者简介:周贤太(1974-),男,博士,副教授。
基金资助:
国家杰出青年科学基金(21425627)、国家自然科学基金(21376278,21576302)及广东省科技重大专项(2013A090100006)项目。

Progress in the catalytic oxidation of C4 alkanes

ZHOU Xiantai^1,2, LUO Qingjin³, HU Xiannian³, JI Hongbing^1,2

1. School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, Guangdong, China;
2. Huizhou Research Institute of Sun Yat-sen University, Huizhou 516081, Guangdong, China;
3. Huizhou Yuxin Chemical Co., Ltd., Huizhou 516081, Guangdong, China

Received:2016-02-01 Revised:2016-03-05 Online:2016-06-05 Published:2016-06-05

摘要/Abstract

摘要： 碳四烷烃包括正丁烷和异丁烷,主要来自炼油厂和石化装置。目前大部分碳四烷烃的利用途径单一,大多用作燃料等低值消耗,未能实现碳四烷烃资源的高值化利用。随着化工行业产品精细化率的发展、资源利用率的提高,碳四烃类化合物的综合利用日益受到人们的关注。针对碳四烷烃资源的化工利用现状,本文介绍了碳四烷烃催化氧化制备有机化工产品的技术进展,包括正丁烷氧化制备顺酐和乙酸、异丁烷氧化制备甲基丙烯酸和叔丁基过氧化氢等。总结了碳四烷烃催化氧化技术的特点,认为温和条件下的仿生催化氧化技术将在实现碳四烷烃氧化过程中发挥重要的作用。

关键词: 碳四, 烷烃, 正丁烷, 异丁烷, 催化

Abstract: C4 alkanes of n-butane and isobutane are mainly from refineries and petrochemical plants. At Present,most C4 alkanes are used as fuel or in other low value consumptions,which could not realize the high value of their utilizations. With the development of the fine chemical industry and the improvement of resource utilization rate,the comprehensive utilization of C4 alkanes has attracted more and more attentions. The technical progress in the preparation of organic chemicals from the catalytic oxidation of C4 alkanes is reviewed,including the oxidation of n-butane to maleic anhydride and acetic acid,the oxidation of isobutane to methacrylic acid and tert-butyl hydroperoxide. The features of catalytic oxidation of C4 alkanes were summarized. The biomimetic catalytic oxidation technology is considered to play key role in the catalytic oxidation of C4 alkanes under mild conditions.

Key words: C4 hydrocarbon, alkane, n-butane, isobutene, catalysis

中图分类号:

TQ032

周贤太, 罗庆金, 胡先念, 纪红兵. 碳四烷烃化合物催化氧化的技术研究进展[J]. 化工进展, 2016, 35(06): 1758-1765.

ZHOU Xiantai, LUO Qingjin, HU Xiannian, JI Hongbing. Progress in the catalytic oxidation of C4 alkanes[J]. Chemical Industry and Engineering Progree, 2016, 35(06): 1758-1765.

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碳四烷烃化合物催化氧化的技术研究进展

Progress in the catalytic oxidation of C4 alkanes

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