化工进展 ›› 2016, Vol. 35 ›› Issue (S1): 255-258.DOI: 10.16085/j.issn.1000-6613.2016.s1.041

• 材料科学与技术 • 上一篇    下一篇

四元溴化盐对碳钢的高温腐蚀实验研究

熊亚选1, 史建峰1, 吴玉庭2, 李德英1, 矫育青1, 马重芳2   

  1. 1. 北京建筑大学供热供燃气通风及空调工程北京市重点实验室, 北京 100044;
    2. 北京工业大学传热强化 与过程节能教育部重点实验室及传热与能源利用北京市重点实验室, 北京 100124
  • 收稿日期:2015-11-19 修回日期:2015-12-01 出版日期:2016-06-30 发布日期:2016-07-08
  • 通讯作者: 吴玉庭,博士,研究员。E-mail wuyuting@bjut.edu.cn。
  • 作者简介:熊亚选(1977-),男,博士,讲师,主要从事高温太阳能中高温利用和熔融盐蓄热研究等。E-mail xiongyaxuan@bucea.edu.cn。
  • 基金资助:
    国家自然科学基金(51206004)、北京市自然科学基金重点项目(3151001)及北京市科技新星项目(2011029)。

Experimental study on high temperature corrosion of carbon steel in quaternary bromide salts

XIONG Yaxuan1, SHI Jianfeng1, WU Yuting2, LI Deying1, JIAO Yuqing1, MA Chongfang2   

  1. 1. Beijing Key Laboratory of Heating, Gas Supply, Ventilation and Air Conditioning, Beijing University of Civil Engineering and Architecture, Beijing 100044, China;
    2. Key Laboratory of Enhanced Heat Transfer and Energy Conservation of Ministry of Education, Key Laboratory of Heat Transfer and Energy Conversion of Beijing Municipality, Beijing University of Technology, Beijing 100124, China
  • Received:2015-11-19 Revised:2015-12-01 Online:2016-06-30 Published:2016-07-08

摘要: 熔盐是一种高效传热蓄热工质,其在熔盐传热蓄热系统中对熔盐泵、阀门、各种传感器、管道等金属材料设备的腐蚀特性是熔盐应用的限制因素之一,因此确定熔盐对金属材料的腐蚀性能至关重要。为研究四元溴化盐对碳钢(Q235)的高温腐蚀性能,以浸没法在450℃温度下进行碳钢样片的静态腐蚀实验,得到样片在溴化盐腐蚀环境中的腐蚀动力曲线,并对样片腐蚀区域进行扫描电镜和X射线物相分析。实验结果表明,在高温溴化盐腐蚀环境中,碳钢样片被腐蚀的质量损失量随时间延长而增加,腐蚀360h后样片质量损失达到24.14mg/cm2;样片表面产生了电化学腐蚀,腐蚀产物以铁、锰的氧化物为主。

关键词: 四元溴化盐, 碳钢, 腐蚀, 浸没法, 太阳能, 混合

Abstract: Molten salt is a high-efficiency medium for heat transfer and storage.In systems for heat transfer and storage with molten salt, corrosion characteristic of molten salt on metal devices such as molten salt pumps, valves, all kinds of sensors and pipelines is a limiting factor to application of molten salt, so it is important to identify corrosion behavior of molten salt.Carbon steel is the most widely used metal material to make above devices, and study on corrosion characteristics of carbon steel in bromide salts has been relatively deficient.To investigate corrosion characteristics of quaternary bromide salts, static corrosion tests of carbon steel(Q235) were performed in quaternary bromide salts at 450℃ with immersion method, and corrosion kinetic curve of carbon steel samples was gained.Corroded areas were analyzed by scanning electron microscope (SEM) and X-ray diffraction (XRD).The results indicate that weight loss of carbon steel samples by corrosion increase with the extension of time and reach 24.14mg/cm2 after 360h in high temperature corrosion environment.The corrosion products mainly contain iron oxide and manganese oxide.

Key words: quaternary bromide salts, carbon steel, corrosion, immersion method, solar energy, mixing

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