化工进展 ›› 2019, Vol. 38 ›› Issue (04): 1833-1838.DOI: 10.16085/j.issn.1000-6613.2018-0784

• 材料科学与技术 • 上一篇    下一篇

硬脂酸/十八醇/乙酸钠复合相变材料蓄/放热性能

陈之帆(),孙志高(),汤小蒙,刘晓,李娟,李翠敏   

  1. 苏州科技大学环境科学与工程学院,江苏 苏州 215009
  • 收稿日期:2018-04-15 修回日期:2018-06-21 出版日期:2019-04-05 发布日期:2019-04-05
  • 通讯作者: 孙志高
  • 作者简介:<named-content content-type="corresp-name">陈之帆</named-content>(1994—),男,硕士研究生。E-mail:<email>782338326@qq.com</email>。|孙志高,博士,教授,主要从事储能与节能技术方面的研究。E-mail:<email>szg.yzu@163.com</email>。
  • 基金资助:
    江苏省高校自然科学研究重大项目(16KJA480001);江苏省自然科学基金(BK20170382);江苏省住建厅科技项目(2016ZD134);苏州市建设科研项目(2017-20);江苏省研究生科研创新计划项目(KYCX17-2066)

Study on the charging and discharging characteristics of stearic acid/stearyl alcohol/sodium acetate composite phase change materials

Zhifan CHEN(),Zhigao SUN(),Xiaomeng TANG,Xiao LIU,Juan LI,Cuimin LI   

  1. School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu, China
  • Received:2018-04-15 Revised:2018-06-21 Online:2019-04-05 Published:2019-04-05
  • Contact: Zhigao SUN

摘要:

首次将无机相变材料乙酸钠和混合有机相变材料(硬脂酸和十八醇)复合,获得三元复合相变材料。有机和无机相变材料复合可有效解决无机相变材料在相变过程中存在相分离、过冷度大和有机相变材料热导率低的缺点。利用同心套管蓄/放热实验台测试了乙酸钠/硬脂酸/十八醇三元复合相变材料的蓄/放热性能,分析了流体流量及温度对相变材料蓄/放热过程的影响,并结合Fluent数值模拟和实验结果分析了相变过程中相界面的移动规律。研究结果表明,三元复合相变材料在蓄热过程中自然对流起主导作用,放热过程中导热起主导作用,蓄热所需时间小于放热所需时间。蓄热过程中,相变材料的上部相界面横向移动明显快于下部;放热过程中,相变材料的上、下部相界面均匀地径向移动。

关键词: 相变, 热传导, 自然对流, 蓄/放热, 数值模拟

Abstract:

Ternary composite phase change material is prepared from sodium acetate, stearic acid and stearyl alcohol. Composite material could effectively reduce the phase separation and supercooling degree of inorganic phase change material and improve the thermal conductivity of organic phase change material. The performance of charging and discharging of the ternary composite phase charge material with sodium acetate, stearic acid and stearyl alcohol is investigated in a double-pipe heat exchanger. The effect of the temperature and flow of hot water on the process of heat charge and discharge is studied. The movement of phase interface is also analyzed, based on the results of CFD numerical simulation and experiment. The experimental results show that natural convection is the dominant way of heat transfer during the heat charge, but heat conduction plays the leading role during the heat discharge. The time required for heat charge is less than that for heat discharge. The upper phase interface of the phase change material moves significantly faster than the lower one during the heat charge process, while both the upper and the lower phase interfaces uniformly moves in the radial direction during the heat discharge process.

Key words: phase change, heat conduction, natural convection, heat charge and discharge, numerical simulation

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