浅析二氧化钛材料可见光降解室内VOCs的研究进展

doi:10.16085/j.issn.1000-6613.2024-1130

摘要/Abstract

摘要：

室内空气质量已成为公众关注的重要健康问题，光催化氧化（PCO）技术具有能耗低且效率高的特点，使其在室内挥发性有机化合物（VOCs）治理中展现出较大的潜力。在众多PCO材料中，二氧化钛（TiO₂）因其来源广、化学性质稳定、氧化能力强、毒性低等特点成为降解室内VOCs的优选催化剂，但其对可见光的利用率较低等问题限制了其在光催化领域的应用。本文综述了TiO₂材料的特性及其在室内VOCs治理方面的研究进展，详述了TiO₂可见光光催化降解室内典型VOCs的反应机理，梳理归纳了近年来提升TiO₂吸附和催化氧化性能的相关研究，分析介绍了近几年室内单/多组分VOCs降解的研究进展，并对未来TiO₂材料可见光下净化室内VOCs污染做出展望，为未来降解单/多组分VOCs及其混合物的研究提出建议。

关键词: 可见光光催化氧化, 催化剂, 室内空气污染物, 二氧化钛, 挥发性有机化合物

Abstract:

Indoor air quality has become an important health issue of public concern, and photocatalytic oxidation (PCO) technology has the characteristics of low energy consumption and high efficiency, which makes it show a greater potential in the treatment of indoor volatile organic compounds (VOCs). Among many PCO materials, titanium dioxide (TiO₂) has become the preferred catalyst for the degradation of indoor VOCs due to its wide source, stable chemical properties, strong oxidation ability, low toxicity, etc. However, its low utilization of visible light limits its application in the field of photocatalysis. This paper reviewed the research progress on the characteristic of TiO₂ materials and their use in indoor VOCs management, detailed the reaction mechanism of TiO₂ visible light photocatalytic degradation of typical indoor VOCs, compiled and summarized the relevant research on the enhancement of adsorption and catalytic oxidation properties of TiO₂ in recent years, introduced the research progress of indoor single/multi-component VOCs degradation in recent years and made an outlook for the future purification of indoor VOCs pollution by TiO₂ materials under visible light in order to provide an opportunity for the future degradation of single/multi-component VOCs. The research progress of indoor single/multi-component VOCs degradation in recent years was analyzed, and the future prospect of TiO₂ materials for visible light purification of indoor VOCs pollution was presented, and the suggestions for the future research on degradation of single/multi-component VOCs and their mixtures were proposed.

Key words: visible light photocatalytic oxidation, catalyst, indoor air pollutants, titanium dioxide, volatile organic compounds (VOCs)

中图分类号:

O643.36

王文君, 刘瑞鑫, 王军, 张庆磊, 侯立安. 浅析二氧化钛材料可见光降解室内VOCs的研究进展[J]. 化工进展, 2025, 44(9): 5351-5362.

WANG Wenjun, LIU Ruixin, WANG Jun, ZHANG Qinglei, HOU Li’an. Research progress of visible light degradation of indoor VOCs by titanium dioxide materials[J]. Chemical Industry and Engineering Progress, 2025, 44(9): 5351-5362.

图/表 7

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化合物	物质来源
甲醛	农药、涂料、压制木材、泡沫
乙醛	胶水、地板材料、皮革霉菌
对二氯苯	房间除臭剂、天花板材料
二氯甲烷	除漆剂、溶剂
苯乙烯	绝缘纺织品、消毒剂、塑料、油漆
丙烯醛	化石燃料燃烧、烟草烟雾
甲苯	油漆、聚氨酯泡沫、气凝胶
邻苯二甲酸酐	环氧树脂家具
挥发性胺	箱子的腐败退化
乙苯	建筑材料、溶剂、黏合剂
四氯乙烯	吸烟、二手烟
氯仿	穿着或干洗过的衣服、氯化水
芳烃	油漆、黏合剂、汽油、燃烧源
其他VOCs（酯类和酮类）	塑料、树脂、香水、增塑剂、香料

化合物	物质来源
甲醛	农药、涂料、压制木材、泡沫
乙醛	胶水、地板材料、皮革霉菌
对二氯苯	房间除臭剂、天花板材料
二氯甲烷	除漆剂、溶剂
苯乙烯	绝缘纺织品、消毒剂、塑料、油漆
丙烯醛	化石燃料燃烧、烟草烟雾
甲苯	油漆、聚氨酯泡沫、气凝胶
邻苯二甲酸酐	环氧树脂家具
挥发性胺	箱子的腐败退化
乙苯	建筑材料、溶剂、黏合剂
四氯乙烯	吸烟、二手烟
氯仿	穿着或干洗过的衣服、氯化水
芳烃	油漆、黏合剂、汽油、燃烧源
其他VOCs（酯类和酮类）	塑料、树脂、香水、增塑剂、香料

目标VOCs	催化剂	主要中间产物	分析方法	参考文献
甲苯	Sr₂Sb₂O₇	苯甲醇，苯甲醛，苯甲酸	in situ DRIFTS	[62]
	Pt/CeO₂	苄，苯甲醇，苯甲醛，苯甲酸，甲酸盐	in situ DRIFTS	[63]
	MIL-125(Ti)	苯甲醇，苯甲醛，苯甲酸，甲酸盐和乙酸盐	FTIR，GC-MS	[64]
	Co₃O₄/TiO₂	苯甲醇，苯甲醛，苯甲酸，丙酮	in situ DRIFTS	[65]
	TiO₂/CeO₂	苯甲醇，苯甲醛和苯甲酸，甲酸和草酸	UV-Vis DRS	[66]
苯	nano-TiO₂	苯酚，对苯二酚，对苯并醌，儿茶酚，邻苯并醌	DFT，CG-MS	[67]
	W-MnO₂	苯，苯甲酸，马来酸，乙酸	in situ DRIFTS	[68]
	Mn-Cu/Al₂O₃	一氧化碳，甲酸	FTIR	[69]
甲醛	MnOOH/MnO₂	甲酸	FTIR	[70]
	CaSn(OH)₆	甲酸	in situ DRIFTS	[71]
	TiO₂/硅藻土	甲酸，甲酸盐	in situ DRIFTS	[72]

目标VOCs	催化剂	主要中间产物	分析方法	参考文献
甲苯	Sr₂Sb₂O₇	苯甲醇，苯甲醛，苯甲酸	in situ DRIFTS	[62]
	Pt/CeO₂	苄，苯甲醇，苯甲醛，苯甲酸，甲酸盐	in situ DRIFTS	[63]
	MIL-125(Ti)	苯甲醇，苯甲醛，苯甲酸，甲酸盐和乙酸盐	FTIR，GC-MS	[64]
	Co₃O₄/TiO₂	苯甲醇，苯甲醛，苯甲酸，丙酮	in situ DRIFTS	[65]
	TiO₂/CeO₂	苯甲醇，苯甲醛和苯甲酸，甲酸和草酸	UV-Vis DRS	[66]
苯	nano-TiO₂	苯酚，对苯二酚，对苯并醌，儿茶酚，邻苯并醌	DFT，CG-MS	[67]
	W-MnO₂	苯，苯甲酸，马来酸，乙酸	in situ DRIFTS	[68]
	Mn-Cu/Al₂O₃	一氧化碳，甲酸	FTIR	[69]
甲醛	MnOOH/MnO₂	甲酸	FTIR	[70]
	CaSn(OH)₆	甲酸	in situ DRIFTS	[71]
	TiO₂/硅藻土	甲酸，甲酸盐	in situ DRIFTS	[72]