化工进展 ›› 2024, Vol. 43 ›› Issue (S1): 590-596.DOI: 10.16085/j.issn.1000-6613.2024-0723

• 资源与环境化工 • 上一篇    下一篇

原油组分及蜡晶结构对JH页岩油结构破坏与恢复的影响规律

尹然1(), 穆野2, 霍富永1, 曹钦亮3, 蔺港归1, 王毅杰2, 黄启玉2()   

  1. 1.长庆工程设计有限公司,陕西 西安 710005
    2.中国石油大学(北京)机械与储运工程学院,油气管道输送安全国家工程实验室,城市油气输配技术北京市重点实验室,北京 102249
    3.中国石油天然气股份有限公司长庆油田分公司新能源项目部,陕西 西安 710005
  • 收稿日期:2024-04-30 修回日期:2024-07-02 出版日期:2024-11-20 发布日期:2024-12-06
  • 通讯作者: 黄启玉
  • 作者简介:尹然(1990—),男,博士,研究方向为复杂多相流动保障。E-mail:Ranyinyy@outlook.com
  • 基金资助:
    国家自然科学基金重点项目(51534007);国家自然科学基金面上项目(51374224)

Influence of crude oil composition and wax crystal structure on the damage and recovery of JH shale oil structure

YIN Ran1(), MU Ye2, HUO Fuyong1, CAO Qinliang3, LIN Ganggui1, WANG Yijie2, HUANG Qiyu2()   

  1. 1.Changqing Engineering Design Co. , Ltd. , Xi'an 710005, Shaanxi, China
    2.College of Mechanical and Transportation Engineering, National Engineering Laboratory for Pipeline Safety, Beijing Key Laboratory of Urban Oil and Gas Distribution Technology, China University of Petroleum (Beijing), Beijing 102249, China
    3.Clean Power Development Project Department of Petrochina Changqing Oil Field Company, PetroChina Co. , Ltd. , Xi'an 710005, Shaanxi, China
  • Received:2024-04-30 Revised:2024-07-02 Online:2024-11-20 Published:2024-12-06
  • Contact: HUANG Qiyu

摘要:

当前油气并重、常非并举的能源发展战略有效推动了页岩油的开发进程,对其高效安全集输工艺技术重视度显著提高。通过室内实验测定了JH页岩油的基础物性,明确了其凝点低、密度小、含蜡量高、轻质组分多、无沥青质、少胶质和蜡晶结构强度弱的特点。集输过程中其蜡晶结构易被破坏会导致动态黏度于凝点附近迅速降低。集油温度低于凝点时,停输后其动态屈服应力显著低于静态值。停输后,静态降温过程中更多蜡晶析出导致凝油结构强度迅速恢复;无降温条件下其结构强度恢复速度极慢,凝点以下9℃停输12h后所得动态屈服应力仅为静态值的8.5%。为保证输送安全,需在避免地温条件过低或停输后存在大幅降温条件下开展再启动操作,若有必要可采用间歇性启动方式降低凝油屈服应力,保证再启动安全。

关键词: 含蜡页岩油, 基础物性, 流变特性, 黏度, 屈服应力, 流动安全

Abstract:

The current energy development strategy of developing simultaneously oil and gas, as well as conventional and unconventional energy sources, effectively promotes the development process of shale oil, and the attention to its efficient and safe gathering and transportation process technology has been significantly increased. In this paper, the basic physical properties of JH shale oil were determined by indoor experiments, and its characteristics of low freezing point, low density, high wax content, high number of light components, no asphaltene, few colloids and weak wax crystal structure were identified. The wax crystal structure is easy to be destroyed during the gathering and transportation process, which will lead to the rapid decrease of dynamic viscosity near the freezing point. When the temperature of oil gathering is lower than the freezing point, the dynamic yield stress is significantly lower than the static value after stopping the transportation. After stopping the transportation, more wax crystals are precipitated during the static cooling process, which leads to the rapid recovery of condensate structural strength; under the condition of no temperature drop, the structural strength recovery is very slow, and the dynamic yield stress obtained after stopping the transportation for 12h at 9℃ below the freezing point is only 8.5% of the static value. In order to ensure the transportation safety, it is necessary to avoid the restart operation under the condition of low ground temperature or large temperature drop after stopping the transportation, and if necessary, intermittent startup can be used to reduce the yield stress of condensate, so as to ensure the restart safety.

Key words: waxy shale oil, basic physical properties, rheological properties, viscosity, yield stress, flow safety

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