卡拉胶-魔芋胶复合凝胶基香精微胶囊的制备与表征

doi:10.16085/j.issn.1000-6613.2021-2650

化工进展 ›› 2022, Vol. 41 ›› Issue (S1): 376-381.DOI: 10.16085/j.issn.1000-6613.2021-2650

卡拉胶-魔芋胶复合凝胶基香精微胶囊的制备与表征

李鲁¹(), 鲍穗¹, 张李明¹, 汪然¹, 陶正红¹, 杨兴祥²()

^1.安徽中烟工业有限责任公司，安徽合肥 230031
^2.中科院合肥技术创新工程院，安徽合肥 230088

收稿日期:2021-12-28 修回日期:2022-04-25 出版日期:2022-10-20 发布日期:2022-11-10
通讯作者: 杨兴祥
作者简介:李鲁（1982—），男，研究方向为精细化工。E-mail：greenlilu@163.com。
基金资助:
安徽省重大科技专项(18030901083)

Preparation and characterization of carrageenan-konjac gum hybrid gel for encapsulating fragrance

LI Lu¹(), BAO Sui¹, ZHANG Liming¹, WANG Ran¹, TAO Zhenghong¹, YANG Xingxiang²()

^1.China Tobacco Anhui Industrial, Co. , Ltd. ，Hefei 230031, Anhui, China
^2.CAS (Hefei) Institute of Technology Innocation, Hefei 230088, Anhui, China

Received:2021-12-28 Revised:2022-04-25 Online:2022-10-20 Published:2022-11-10
Contact: YANG Xingxiang

摘要/Abstract

摘要：

微胶囊工艺可有效避免香精香料等物质的挥发,合适的囊壁材料对于胶囊的力学性能和封装行为都至关重要。本研究以卡拉胶和魔芋胶为主要的囊壁材料，通过分析不同食品胶的凝胶行为和力学性能，确定了最佳配方。卡拉胶和魔芋胶的协同作用有利于在中性和酸性条件下形成热可逆的弹性凝胶，并应用于香精香料的封装。文中阐述了复合胶体的协同作用机理，并对复合胶体的混合凝固过程进行了表征。此外，还研究了基于最佳配方的复合胶体与不同生产设备和特定内容物的相容性，并评估了其在大规模食品工业生产中的潜力。

关键词: 凝胶, 黏度, 魔芋胶, 卡拉胶

Abstract:

The encapsulation strategies are efficient in preventing evaporation of fragrance volatile. Appropriate wall material is important for the mechanical properties and packaging behavior of the capsule. In this research, carrageenan and konjac gum were selected as main encapsulation wall materials and the optimal formula was determined. The synergy of carrageenan and konjac gum caused a thermally reversible elastic gel under neutral and acidic conditions, which can be applied in encapsulating fragrance. The synergistic mechanism was elaborated and the coagulation process of the composite colloid was characterized at the same time. In addition, the compatibility of composite colloid based on the best formula with different production instruments and individual core materials were investigated, and its potential for large-scale production was evaluated.

Key words: gels, viscosity, konjac gum, carrageenan

中图分类号:

李鲁, 鲍穗, 张李明, 汪然, 陶正红, 杨兴祥. 卡拉胶-魔芋胶复合凝胶基香精微胶囊的制备与表征[J]. 化工进展, 2022, 41(S1): 376-381.

LI Lu, BAO Sui, ZHANG Liming, WANG Ran, TAO Zhenghong, YANG Xingxiang. Preparation and characterization of carrageenan-konjac gum hybrid gel for encapsulating fragrance[J]. Chemical Industry and Engineering Progress, 2022, 41(S1): 376-381.

图/表 7

图1 胶体的基本特性

图2 单组分胶体及复合胶体的SEM图

图3 红外光谱图

图4 DSC曲线

图5 滴注法生产胶囊的质量波动情况

图6 胶囊的压力与合格率

图7 脉冲滴丸设备以配方F7为外壳制备胶囊的示意图

参考文献 10

1	SANDOLO C, BULONE D, MANGIONE M R, et al. Synergistic interaction of Locust Bean Gum and Xanthan investigated by rheology and light scattering[J]. Carbohydrate Polymers, 2010, 82(3): 733-741.
2	BRENNER T, WANG Z, ACHAYUTHAKAN P, et al. Rheology and synergy of κ-carrageenan/locust bean gum/konjac glucomannan gels[J]. Carbohydrate Polymers, 2013, 98(1): 754-760.
3	FITZSIMONS S M, TOBIN JT, MORRIS E R. Synergistic binding of konjac glucomannan to xanthan on mixing at room temperature[J]. Food Hydrocolloids, 2008, 22(1): 36-46.
4	WILLIAMS P A, CLEGG S M, LANGDON M J, et al. Investigation of the gelation mechanism in kappa-carrageenan konjac mannan mixtures using differential scanning calorimetry and electron-spin-resonance spectroscopy[J]. Macromolecules, 1993, 26(20): 5441-5446.
5	WANG Y L, LI Z H, WEI Y. Rheology and influence factor of low-concentration Konjac gum solutions[J]. Journal of Central South University of Technology, 2008, 15:516-519.
6	PERINELLI D R, PALMIERI G F, CESPI M, et al. Encapsulation of flavours and fragrances into polymeric capsules and cyclodextrins inclusion complexes: An update[J]. Molecules, 2020, 25(24)
7	CRESCENZI V, SKJAK-BRAEK G, DENTINI M, et al. A high field NMR study of the products ensuing from Konjak Glucomannan C(6)-oxidation followed by enzymatic C(5)-epimerization[J]. Biomacromolecules, 2002, 3(6): 1343-1352.
8	WANG N, TIAN J, WANG L, et al. Fucoidan hydrogels induced by k-carrageenan: Rheological, thermal and structural characterization[J]. International Journal of Biological Macromolecules, 2021, 191: 514-520.
9	ALVAREZ-MANCENIDO F, LANDIN M, LACIK I, et al. Konjac glucomannan and konjac glucomannan/xanthan gum mixtures as excipients for controlled drug delivery systems. Diffusion of small drugs[J]. International Journal of Pharmaceutics, 2008, 349(1-2): 11-18.
10	IIJIMA M, HATAKEYAMA T, HATAKEYAMA H. Gel-sol-gel transition of kappa-carrageenan and methylcellulose binary systems studied by differential scanning calorimetry[J]. Thermochimica Acta, 2014, 596: 63-69.

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卡拉胶-魔芋胶复合凝胶基香精微胶囊的制备与表征

Preparation and characterization of carrageenan-konjac gum hybrid gel for encapsulating fragrance

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