化工进展 ›› 2023, Vol. 42 ›› Issue (9): 4603-4615.DOI: 10.16085/j.issn.1000-6613.2022-2005

• 能源加工与技术 • 上一篇    下一篇

含碳掺氨燃料的研究进展

赖诗妮1,2(), 江丽霞3, 李军1,2,4,5(), 黄宏宇1,2,5, 小林敬幸6   

  1. 1.中国科学院广州能源研究所,广东 广州 510640
    2.中国科学技术大学能源科学与技术学院,广东 广州 510640
    3.中国科学院重大科技任务局,北京 100864
    4.江西省碳中和研究中心,江西 南昌 330096
    5.南方海洋科学与工程广东省实验室(广州),广东 广州 511458
    6.名古屋大学化学系统工程系,日本 名古屋 464-8603
  • 收稿日期:2022-10-27 修回日期:2022-11-29 出版日期:2023-09-15 发布日期:2023-09-28
  • 通讯作者: 李军
  • 作者简介:赖诗妮(1999—),女,硕士研究生,研究方向为氨基燃料燃烧。E-mail:sa21178008@mail.ustc.edu.cn
  • 基金资助:
    南方海洋科学与工程广东省实验室(广州)人才团队引进重大专项(GML2019ZD0108);广东省重点领域研发计划(2020B0202010004)

Research progress of ammonia blended fossil fuel

LAI Shini1,2(), JIANG Lixia3, LI Jun1,2,4,5(), HUANG Hongyu1,2,5, KOBAYASHI Noriyuki6   

  1. 1.Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, Guangdong, China
    2.School of Energy Science and Engineering, University of Science and Technology of China, Guangzhou 510640, Guangdong, China
    3.Bureau of Major R&D Programs, Chinese Academy of Sciences, Beijing 100864, China
    4.Jiangxi Carbon Neutralization Research Center, Nanchang 330096, Jiangxi, China
    5.Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou), Guangzhou 511458, Guangdong, China
    6.Department of Chemical Systems Engineering, Nagoya University, Nagoya 464-8603, Japan
  • Received:2022-10-27 Revised:2022-11-29 Online:2023-09-15 Published:2023-09-28
  • Contact: LI Jun

摘要:

随着经济和社会的发展,国家对能源的需求量越来越大,这与化石能源短缺、环境污染、温室效应等问题相矛盾,因此寻找高效清洁的替代燃料势在必行。氨的体积能量密度较高、成本低且完全燃烧时产物的污染性小,具有成为新时代绿色能源的潜力。但它的燃烧性能较差,通常需要掺混煤、CH4和合成气等燃料来改善。本文主要介绍了含碳掺氨的煤掺氨和甲烷掺氨混合燃料在基础燃烧特性和燃烧应用优化方面的研究进展。总结了不同燃烧策略及燃烧器设计中掺混氨燃料的燃烧特性和排放规律,为未来工业化应用研究提供一定的参考。但在实际应用氨燃料过程中仍存在不少挑战,未来可进一步对优化分级燃烧的策略、改善相关燃烧设备的结构、调整含氨燃料的喷射方式等方面进行研究,以实现高效低污染氨燃料的应用目标。

关键词: 燃料, 氨, 甲烷, 煤燃烧, 氮氧化物

Abstract:

Fossil fuels meet most of the world’s energy demand today. But too much use of conventional fossil fuels is causing many severe problems, such as environmental pollution, global warming and energy crisis. Therefore, looking for environmentally friendly fuels is very necessary. Ammonia has attracted more and more attention because it is a carbon free carrier with advantages of high energy density and low cost. However, ammonia usually need to co-fire with some fuels such as coal, CH4 and syngas to improve the combustion characteristics of pure ammonia. This article introduces a detailed development of ammonia/coal and ammonia/methane as fuels for main applications such as boiler and gas turbine. It summarizes the fundamental combustion characteristics and the application research progress of ammonia blends. What’s more, the current understanding of combustion characteristics and the emission characteristics are also summarized. However, using ammonia blends as alternative fuels still has many challenges. In future, the improvement of combustion strategies, equipment and injection strategies is very urgent in order to apply ammonia as a practical fuel with high efficiency and low emission.

Key words: fuel, ammonia, methane, coal combustion, nitrogen oxides

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