化工进展 ›› 2022, Vol. 41 ›› Issue (S1): 318-330.DOI: 10.16085/j.issn.1000-6613.2022-0692
收稿日期:
2022-04-18
修回日期:
2022-05-03
出版日期:
2022-10-20
发布日期:
2022-11-10
通讯作者:
卢炯元
作者简介:
张洪铭(1997—),男,硕士研究生,研究方向为膜分离技术。E-mail:1051257882@qq.com。
基金资助:
ZHANG Hongming1(), LU Jiongyuan1,2(), WANG Sanfan1,2
Received:
2022-04-18
Revised:
2022-05-03
Online:
2022-10-20
Published:
2022-11-10
Contact:
LU Jiongyuan
摘要:
阴离子交换膜(AEMs)作为燃料电池的核心部件,其发展得到了普遍关注。然而,AEMs中聚合物骨架和阳离子基团无序的直接相连的结构导致了膜在应用过程中存在离子电导率低、碱稳定性差和机械性能不足等问题,因此对连接二者的分子结构进行设计,开发综合性能优异的AEMs很有必要。本文介绍了AEMs选择性透过的基本机理,并从不同的分子结构出发,总结了近年来应用较为广泛的嵌段结构、接枝结构、交联结构、局部高密度结构以及由局部高密度结构与其他三种结构组成的复合结构AEMs的研究进展;从离子电导率、碱稳定性、机械性能以及吸水率等方面对AEMs的性能提升进行了归纳,重点关注AEMs离子电导率和吸水率的权衡问题,并从分子结构及其组合使用的角度对燃料电池用AEMs的未来发展方向进行了展望。
中图分类号:
张洪铭, 卢炯元, 王三反. 燃料电池用阴离子交换膜分子结构研究进展[J]. 化工进展, 2022, 41(S1): 318-330.
ZHANG Hongming, LU Jiongyuan, WANG Sanfan. Research progress on molecular structure of anion exchange membrane for fuel cells[J]. Chemical Industry and Engineering Progress, 2022, 41(S1): 318-330.
AEMs | 每个侧链上的季铵基团数量/个 | 20℃时离子电导率/mS·cm-1 | 吸水率/% | 溶胀率/% |
---|---|---|---|---|
CS-1 | 1 | 30 | 143 | 70 |
CS-2 | 2 | 35 | 100 | 43 |
CS-3 | 3 | 41 | 82 | 34 |
CS-4 | 4 | 60 | 70 | 27 |
CS-5 | 5 | 65 | 65 | 19 |
CS-6 | 6 | 64 | 62 | 18 |
表1 接枝不同数量季铵基团AEMs的参数和性能
AEMs | 每个侧链上的季铵基团数量/个 | 20℃时离子电导率/mS·cm-1 | 吸水率/% | 溶胀率/% |
---|---|---|---|---|
CS-1 | 1 | 30 | 143 | 70 |
CS-2 | 2 | 35 | 100 | 43 |
CS-3 | 3 | 41 | 82 | 34 |
CS-4 | 4 | 60 | 70 | 27 |
CS-5 | 5 | 65 | 65 | 19 |
CS-6 | 6 | 64 | 62 | 18 |
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