化工进展 ›› 2020, Vol. 39 ›› Issue (2): 429-438.DOI: 10.16085/j.issn.1000-6613.2019-0890

• 特约评述 • 上一篇    下一篇

金属-有机框架材料在石化环保领域的应用

王成鸿1(),孟凡宁1,魏昕1,曹田田2,栾金义1()   

  1. 1.中国石油化工股份有限公司北京化工研究院环境保护研究所,北京 100013
    2.中国石油化工股份有限公司石油化工科学研究院催化裂化催化剂研究室,北京 100083
  • 收稿日期:2019-05-31 出版日期:2020-02-05 发布日期:2020-03-12
  • 通讯作者: 栾金义
  • 作者简介:王成鸿(1990—),男,工程师,博士研究生,研究方向为化学(环境)工程。E-mail:wangch.bjhy@sinopec.com

Environmental applications of metal-organic frameworks in petrochemical industries

Chenghong WANG1(),Fanning MENG1,Xin WEI1,Tiantian CAO2,Jinyi LUAN1()   

  1. 1.Environmental Protection Research Department, Sinopec Beijing Research Institute of Chemical Industry, Beijing 100013, China
    2.FCC Catalyst Research Department, Sinopec Research Institute of Petroleum Processing, Beijing 100083, China
  • Received:2019-05-31 Online:2020-02-05 Published:2020-03-12
  • Contact: Jinyi LUAN

摘要:

石油化工是我国的支柱产业,也是环境污染的主要来源。近年来,随着国家环保形势的日益严峻和相应环保法规的陆续出台,高效处理石化行业所涉及的各类污染问题已成为重中之重。作为一种新型的纳米多孔材料,金属-有机框架(MOF)在石化环保领域展现出了广阔的应用前景。该材料可作为高性能吸附剂、分离膜以及催化材料去除或降解石化行业中的典型污染物。本文系统梳理了MOF材料及其相关工艺在石化环保领域的潜在应用,重点介绍了近年来国内外取得的突破性进展,并在此基础上深入分析了该材料的应用现状、存在问题及未来的研发方向。总体而言,MOF材料具有比传统多孔材料更优异的结构特征和应用性能;展望未来,其能够作为吸附剂、分离膜或是催化材料在石化环保领域得到更大规模的推广与应用。

关键词: 金属-有机框架, 石化环保, 吸附, 膜分离, 催化氧化

Abstract:

Petrochemical industry is one of the core industries in China, whilst it is also a main source of environmental pollutions. Since the nation’s environmental situations become severer together with the fact that more and more environmental regulations have been installed, the effective remediation towards the typical petrochemical-related contaminations is now a priority topic. As a recently-developed class of material, metal-organic frameworks(MOF) have exhibited promising application potentials for environmental remediation in petrochemical industries. The materials could work as effective adsorbents, functional membranes as well as catalytic candidates to remove/separate/degrade petrochemical pollutants. This article reviews the relevant applications in this field, analyzes the most significant work, and finally discusses the future perspectives for the further development of MOF materials. Overall, MOF materials have exhibited better structural features and application performance. It shall work favorably as adsorbents, membranes and catalysts in the environmental areas of petrochemical industries in the future.

Key words: MOF, environmental remediation, petrochemical industry, adsorption, membrane, AOP

中图分类号: 

版权所有 © 《化工进展》编辑部


本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn