化工进展 ›› 2017, Vol. 36 ›› Issue (10): 3904-3910.DOI: 10.16085/j.issn.1000-6613.2017-0784

• 资源与环境化工 • 上一篇    下一篇

垃圾衍生燃料掺混污泥共热解特性及动力学分析

林顺洪1,2, 李伟1,2, 柏继松1,2, 吕全伟1,2, 江辽1,2, 莫榴1,2, 李玉1,2   

  1. 1. 重庆科技学院机械与动力工程学院, 重庆 401331;
    2. 重庆科技学院重庆垃圾焚烧发电技术研究院, 重庆 401331
  • 收稿日期:2017-04-28 修回日期:2017-06-22 出版日期:2017-10-05 发布日期:2017-10-05
  • 通讯作者: 柏继松,副教授,研究方向为固体废弃物能源化利用技术.
  • 作者简介:林顺洪(1973-),男,硕士,教授,研究方向为固体废弃物能源化利用技术.E-mail:dim001@163.com.
  • 基金资助:
    重庆市生活垃圾资源化处理工程技术研究中心能力提升项目(cstc2014pt-gc20001)及基于机械炉排的生活垃圾焚烧及气化燃烧关键技术成果转化项目(KJZH14108)。

Co-pyrolysis characteristics and kinetic analysis of refuse derived fuel (RDF) blends sludge

LIN Shunhong1,2, LI Wei1,2, BAI Jisong1,2, LÜ Quanwei1,2, JIANG Liao1,2, MO Liu1,2, LI Yu1,2   

  1. 1. College of Mechanical and Power Engineering, Chongqing University of Science and Technology, Chongqing 401331, China;
    2. Chongqing Waste to Energy Research & Technology Institute, Chongqing University of Science and Technology, Chongqing 401331, China
  • Received:2017-04-28 Revised:2017-06-22 Online:2017-10-05 Published:2017-10-05

摘要: 利用热重-红外联用分析仪(TG-FTIR)研究了垃圾衍生燃料(RDF)、污泥及混合热解的反应动力学和气体产物析出特性。研究结果表明,RDF与污泥混合热解过程存在协同作用。当污泥的掺混比例为50%时,整个热解过程表现为促进作用,且在500~1000℃温度段的促进效果最为明显。采用Coats-Redfern法对热解过程进行动力学分析发现,RDF与污泥混合热解反应在低温段(240~380℃)和高温段(670~740℃)符合2级反应规律,而在中温段(430~540℃)符合1级反应规律;相对于RDF单独热解,RDF掺混污泥共热解的活化能明显降低。FTIR分析发现,RDF掺混污泥共热解对CO2和CO的析出影响不大,对CH4的产生有明显促进作用。同时,共热解也导致HCl、NH3和HCN等污染物析出增加。本研究结果可为RDF和污泥共热解工艺的开发与设计提供数据支撑。

关键词: 垃圾衍生燃料, 污泥, 热重-红外联用, 热解, 动力学, 气相产物

Abstract: In this paper,the reaction kinetic and gas product characteristics of pyrolysis of refuse derived fuel(RDF),sludge and their mixture were studied by using thermogravimetric analysis-Fourier transform infrared spectrometer(TG-FTIR). The results showed that there was synergistic effect in the co-pyrolysis process of sludge and RDF. When the proportion of sludge is 50%,the whole pyrolysis process presented promotion effect,and the effect is the most obvious at the temperature range from 500℃ to 1000℃. The Coats-Redfern method was used to analyze the kinetic parameters of the pyrolysis process. The results indicated that the co-pyrolysis reaction of RDF and sludge in the low temperature stage(240-380℃)and high temperature stage(670-740℃)conforms to the second-order reaction law,while meets the first-order reaction law in the middle temperature stage (430-540℃). Compared with RDF pyrolysis,the activation energy of co-pyrolysis of RDF and sludge decreased obviously,which indicated that co-pyrolysis could promote the pyrolysis reaction process. FTIR analysis showed that the co-pyrolysis of RDF and sludge has little effect on the precipitation of CO2 and CO,but promotes the production of CH4. Meanwhile,the co-pyrolysis results in an increase in the precipitation of HCl,NH3 and HCN as well. The results of this study could provide data support for the development and design of the co-pyrolysis process of RDF and sludge.

Key words: refuse derived fuel(RDF), sludge, TG-FTIR, pyrolysis, kinetic, gas product

中图分类号: 

京ICP备12046843号-2;京公网安备 11010102001994号
版权所有 © 《化工进展》编辑部
地址:北京市东城区青年湖南街13号 邮编:100011
电子信箱:hgjz@cip.com.cn
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn