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杂多酸催化剂催化氧化脱硫研究进展

张海燕,代跃利,蔡 蕾   

  1. 东北石油大学化学化工学院,黑龙江 大庆 163318
  • 出版日期:2013-04-05 发布日期:2013-04-05

Research progress of heteropoly acid catalyzed oxidative desulfurization

ZHANG Haiyan,DAI Yueli,CAI Lei   

  1. School of Chemistry and Chemical Engineering,Northeast Petroleum University,Daqing 163318,Heilongjiang,China
  • Online:2013-04-05 Published:2013-04-05

摘要: 介绍了杂多酸催化剂在燃料油氧化脱硫中的应用研究进展。详细叙述了过渡金属、碱金属和稀土金属杂多酸催化剂、杂多酸季铵盐催化剂、杂多酸离子液体催化剂和以碳材料、二氧化钛、二氧化硅、高分子材料等为载体的负载型杂多酸催化剂,阐述了各种杂多酸催化剂的特点及脱硫效果,指出综合应用杂多酸催化剂特性开发活性高、耗氧少、重复使用性强的优良新型杂多酸催化剂是催化氧化深度脱硫的重要研究方向。

关键词: 杂多酸, 脱硫, 催化氧化

Abstract: Research progress of applications of heteropoly acid catalyst in the oxidative desulfurization of fuel oil was introduced. Heteropoly acid catalysts,including those containing transition metal,alkali metal,rare earth metal,quaternary ammonium salt,ionic liquid and catalysts supported on carriers,such as carbon materials,titanium dioxide,silica,polymer materials were described and the characteristics and catalytic effects of the catalysts were summerized.Comprehensive utilization of heteropoly acid catalysts’ properties and the development of novel high performance heteropoly acid catalysts with high activity,less oxygen consumption and strong reusability were important research topics for deep desulfurization through catalytic oxidation.

Key words: heteropoly acids, desulfurization, catalytic oxidation

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