多相管流体系水合物沉积/堵塞研究进展

doi:10.16085/j.issn.1000-6613.2024-1653

化工进展 ›› 2025, Vol. 44 ›› Issue (11): 6231-6243.DOI: 10.16085/j.issn.1000-6613.2024-1653

• 能源加工与技术 • 上一篇

多相管流体系水合物沉积/堵塞研究进展

郭恩岐¹(), 史博会¹^,²(), 陈好奇¹, 宋尚飞¹, 刘礼豪¹, 隋金昊¹, 朱羽墨¹, 宫敬¹^,²

^1.中国石油大学(北京)油气管道输送安全国家工程实验室，石油工程教育部重点实验室，城市油气输配技术北京市重点实验室，北京 102249
^2.中国石油大学(北京)碳中和示范性能源学院，北京 102249

收稿日期:2024-10-13 修回日期:2024-10-28 出版日期:2025-11-25 发布日期:2025-12-08
通讯作者: 史博会
作者简介:郭恩岐（2000—），女，博士研究生，研究方向为天然气水合物流动保障技术。E-mail：enqig@foxmail.com。
基金资助:
国家重点研发计划(2022YFC2806200);北京自然科学基金(23C20113)

Research progress of hydrate deposition/blockage in multiphase pipeline

GUO Enqi¹(), SHI Bohui¹^,²(), CHEN Haoqi¹, SONG Shangfei¹, LIU Lihao¹, SUI Jinhao¹, ZHU Yumo¹, GONG Jing¹^,²

^1.National Engineering Research Center of Oil and Gas Pipeline Transportation Safety, MOE Key Laboratory of Petroleum Engineering, Beijing Key Laboratory of Urban Oil and Gas Distribution Technology, China University of Petroleum Beijing 102249, China
^2.College of Carbon Neutral Energy, China University of Petroleum, Beijing 102249, China

Received:2024-10-13 Revised:2024-10-28 Online:2025-11-25 Published:2025-12-08
Contact: SHI Bohui

摘要/Abstract

摘要：

随着海洋油气资源不断走向深海，深水多相管流体系中因水合物生成引发堵塞的风险显著加剧。研究不同油气资源禀赋体系内多相管流中水合物生成沉积/堵塞的演变规律，是从定性分析转变为定量核算多相管路水合物堵塞风险、提出经济高效解决方案的关键。本文围绕近年来多相管流体系水合物沉积/堵塞的研究成果，阐述了水合物颗粒生成阶段受传热与传质等内在因素影响的作用规律，解析了水合物颗粒发生聚并及其与管壁界面黏附沉积形成水合物层的关键影响因素，梳理了水合物在含蜡、粉砂等复杂携固多相流动体系中生成、沉积的作用机制。最后设计构建了水合物沉积定量计算模型，并基于此提出了将机理-数据耦合方法引入水合物堵塞概率预测模型的研究思路，分析了制订堵塞定量评价指标的优势，为未来应用数据技术有效解决深水多相管流中水合物沉积/堵塞问题提供了重要技术支持。

关键词: 水合物, 沉积物, 多相流, 流动保障, 颗粒行为

Abstract:

As offshore oil and gas resources continue to move into the deep sea, the risk of blockage caused by hydrate formation in deep-water multiphase pipeline systems is significantly increased. Studying the change rules of hydrate formation and deposition/blockage processes in multiphase pipeline in different oil and gas resource endowment systems is the key to transforming from qualitative analysis to quantitative calculation of hydrate blockage risk in multiphase pipeline and proposing economical and efficient solutions. Based on the research results of hydrate deposition/blockage in multiphase pipeline systems in recent years, this paper expounds the influence of internal factors such as heat and mass transfer on the formation stage of hydrate particles, analyzes the key influencing factors of hydrate particle aggregation and its adhesion and deposition with the pipe wall interface to form hydrate layer, and sorts out the mechanism of hydrate formation and deposition in complex solid-carrying multiphase flow systems such as wax and silt. Finally, a quantitative calculation model of hydrate deposition is designed and constructed. Based on this, the research idea of introducing the mechanism-data coupling method into the hydrate blockage probability prediction model is proposed, and the advantages of formulating the quantitative evaluation index of blockage are analyzed. It provides important technical support for the future application of data technology to effectively solve the hydrate deposition/blockage problems in deep-water multiphase pipeline.

Key words: hydrate, deposition, multiphase flow, flow assurance, particle behavior

中图分类号:

TE832

郭恩岐, 史博会, 陈好奇, 宋尚飞, 刘礼豪, 隋金昊, 朱羽墨, 宫敬. 多相管流体系水合物沉积/堵塞研究进展[J]. 化工进展, 2025, 44(11): 6231-6243.

GUO Enqi, SHI Bohui, CHEN Haoqi, SONG Shangfei, LIU Lihao, SUI Jinhao, ZHU Yumo, GONG Jing. Research progress of hydrate deposition/blockage in multiphase pipeline[J]. Chemical Industry and Engineering Progress, 2025, 44(11): 6231-6243.

图/表 11

图1 不同体系“点沉积”与“线沉积”过程机理

图2 高压声悬浮实验装置[41]

图3 相对压降随管路重启时间的变化[54]

图4 环戊烷水合物与FeCO3产物膜接触不同时间后的形貌变化[57]

图5 水合物颗粒在不同流动体系中的受力分析示意图[66-67]

图6 水合物生成过程中气体消耗量与含蜡量（质量分数）的关系[76]

图7 盐-砂共存体系中水合物沉积机理示意图[79]

图8 气基体系OLGA水合物堵塞模拟计算逻辑框图[82]

图9 本文作者课题组建立的水合物沉积全过程机理模型[83]

图10 计算水合物堵塞概率的决策树模型[85]

图11 数据驱动的机器学习模型[86]

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多相管流体系水合物沉积/堵塞研究进展

Research progress of hydrate deposition/blockage in multiphase pipeline

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