氧化石墨烯改性吸水树脂的制备及应用

doi:10.16085/j.issn.1000-6613.2020-0348

摘要/Abstract

摘要：

氧化石墨烯改性吸水树脂综合了氧化石墨烯和吸水树脂的优势，在水处理吸附、药物缓释、组织工程等领域有广阔的应用前景。目前有关氧化石墨烯改性吸水树脂的制备方法、性能及应用缺少相关的综述。因此，本文主要分四部分来综述近几年氧化石墨烯改性吸水树脂的研究进展。第一部分简要介绍了氧化石墨烯的结构特性及作为吸水树脂改性剂的特点；第二部分主要综述了氧化石墨烯改性吸水树脂的主要聚合工艺；第三部分主要介绍了氧化石墨烯对吸水树脂微观结构和宏观性能的影响；最后，介绍了氧化石墨烯改性吸水树脂在废水处理、缓解“热岛效应”、柔性器件及医用材料等领域的应用，并分析了其存在的问题，为后续开展氧化石墨烯改性吸水树脂的相关研究及应用提供了参考。

关键词: 氧化石墨烯, 改性, 吸水树脂, 吸附, 聚合

Abstract:

Graphene oxide modified superabsorbent combines the advantages of graphene oxide and superabsorbent, and has a broad application prospect in the fields of water treatment adsorption, drug slow release and tissue engineering. At present, the preparation methods, properties and applications of graphene oxide modified superabsorbents have not been reviewed. Therefore, this paper was mainly divided into four parts to review the research progress of graphene oxide modified superabsorbent in recent years. In the first part, the structural properties of graphene oxide and its properties as a superabsorbent modifier were briefly introduced. In the second part, the main preparation processes of graphene oxide modified superabsorbent were summarized. The third part mainly presented the effect of graphene oxide on the microstructure and properties of superabsorbent. Finally, the applications of graphene oxide modified superabsorbent in wastewater treatment, reduction of “heat island effect”, flexible devices and medical materials were proposed, and the existing problems were analyzed, which provided the references for the follow-up research and application of graphene oxide modified superabsorbent.

Key words: graphene oxide, modification, superabsorbent, adsorption, polymerization

中图分类号:

TB34

王向鹏, 郑云香, 宗丽娜, 张春晓, 吴伟. 氧化石墨烯改性吸水树脂的制备及应用[J]. 化工进展, 2020, 39(12): 5125-5135.

Xiangpeng WANG, Yunxiang ZHENG, Lina ZONG, Chunxiao ZHANG, Wei WU. Progress in graphene oxide modified superabsorbent and its application[J]. Chemical Industry and Engineering Progress, 2020, 39(12): 5125-5135.

参考文献

1	GHASRI M, JAHANDIDEH A, KABIRI K, et al. Glycerol-lactic acid star-shaped oligomers as efficient biobased surface modifiers for improving superabsorbent polymer hydrogels[J]. Polymers for Advanced Technologies, 2019, 30(2): 390-399.
2	HUANG S, WU L, LI T, et al. Facile preparation of biomass lignin-based hydroxyethyl cellulose super-absorbent hydrogel for dye pollutant removal[J]. International Journal of Biological Macromolecules, 2019, 137: 939-947.
3	QIAO D, TU W, WANG Z, et al. Influence of crosslinker amount on the microstructure and properties of starch-based superabsorbent polymers by one-step preparation at high starch concentration[J]. International Journal of Biological Macromolecules, 2019, 129: 679-685.
4	XIAO Y, CHANG J. Preparation and characterization of bio-and UV-degradable superabsorbent hydrogels based on a novel cross-linker[J]. Soft Materials, 2020, 18(1): 8-16.
5	CHENG S, LIU X, ZHEN J, et al. Preparation of superabsorbent resin with fast water absorption rate based on hydroxymethyl cellulose sodium and its application[J]. Carbohydrate Polymers, 2019, 225: 115214-115223.
6	SAFAEI F, KHALILI S, KHORASANI S N, et al. Preparation of an acrylic acid-based superabsorbent composite: investigation of synthesis parameters[J]. Chemical Papers, 2020, 74(3): 939-949.
7	ZHU W, ZHANG Y, WANG P, et al. Preparation and applications of salt-resistant superabsorbent poly(acrylic acid-acrylamide/fly ash) composite[J]. Materials, 2019, 12(4): 596-605.
8	SHIN H, KIM S, HAN Y K, et al. Preparation of a monolithic and macroporous superabsorbent polymer via a high internal phase pickering emulsion template[J]. Journal of Applied Polymer Science, 2019, 136(42): 48133-48142.
9	NEAMJAN N, WIWATTANANUKUL R, HIANGRAT K, et al. Preparation of superabsorbent polymer from sugarcane bagasse via extrusion process[J]. Sugar Tech., 2019, 21(2): 296-300.
10	YU X, WANG Z, LIU J, et al. Preparation, swelling behaviors and fertilizer-release properties of sodium humate modified superabsorbent resin[J]. Materials Today Communications, 2019, 19: 124-130.
11	KENAWY E R, AZAAM M M, EL-NSHAR E M. Sodium alginate-g-poly(acrylic acid-co-2-hydroxyethyl methacrylate)/montmorillonite superabsorbent composite: preparation, swelling investigation and its application as a slow-release fertilizer[J]. Arabian Journal of Chemistry, 2019, 12(6): 847-856.
12	KHAN H, CHAUDHARY J P, MEENA R. Anionic carboxymethylagarose-based pH-responsive smart superabsorbent hydrogels for controlled release of anticancer drug[J]. International Journal of Biological Macromolecules, 2019, 124: 1220-1229.
13	ZHOU M, ZOU J, GUO X, et al. Superabsorbent nanocomposite and its properties[J]. Journal of Macromolecular Science, Part A, 2019, 56(5): 496-505.
14	FANG S, WANG G, XING R, et al. Synthesis of superabsorbent polymers based on chitosan derivative graft acrylic acid-co-acrylamide and its property testing[J]. International Journal of Biological Macromolecules, 2019, 132: 575-584.
15	ASHKANI M, BOUHENDI H, KABIRI K, et al. Synthesis of poly(2-acrylamido-2-methyl propane sulfonic acid) with high water absorbency and absorption under load (AUL) as concrete grade superabsorbent and its performance[J]. Construction and Building Materials, 2019, 206: 540-551.
16	DABBAGHI A, JAHANDIDEH A, KABIRI K, et al. The synthesis and incorporation of a star-shaped bio-based modifier in the acrylic acid based superabsorbent: a strategy to enhance the absorbency under load[J]. Polymer-Plastics Technology and Materials, 2019, 58(15): 1678-1690.
17	DABBAGHI A, JAHANDIDEH A, KABIRI K, et al. Novel environmentally friendly superabsorbent hydrogel hybrids from synthesized star-shaped bio-based monomers and acrylic acid[J]. Journal of Polymers and the Environment, 2019, 27(9): 1988-2000.
18	LIU X, LUAN S, LI W. Utilization of waste hemicelluloses lye for superabsorbent hydrogel synthesis[J]. International Journal of Biological Macromolecules, 2019, 132: 954-962.
19	单国荣, 张宁. 氧化石墨烯复合水凝胶研究进展[J]. 化工学报, 2018, 69(2): 535-545.
19	SHAN Guorong, ZHANG Ning. Research progress on graphene oxide composite hydrogels[J]. CIESC Journal, 2018, 69(2): 535-545.
20	马垚, 于飞, 马杰. 石墨烯/有机物复合吸附剂的设计及其在水处理中的应用[J]. 化学进展, 2017, 29(6): 582-592.
20	MA Yao, YU Fei, MA Jie. Design of grapheme/composite adsorbent and its application in water treatment[J]. Progress in Chemistry, 2017, 29(6): 582-592.
21	VOIRY D, YANG J, KUPFERBERG J, et al. High-quality graphene via microwave reduction of solution-exfoliated graphene oxide[J]. Science, 2016, 353(6306): 1413-1416.
22	DONG L, YANG J, CHHOWALLA M, et al. Synthesis and reduction of large sized graphene oxide sheets[J]. Chemical Society Reviews, 2017, 46(23): 7306-7316.
23	HEGDE M, YANG L, VITA F, et al. Strong graphene oxide nanocomposites from aqueous hybrid liquid crystals[J]. Nature Communications, 2020, 11(1): 1-7.
24	ALAM S N, SHARMA N, KUMAR L. Synthesis of graphene oxide (GO) by modified hummers method and its thermal reduction to obtain reduced graphene oxide (rGO)[J]. Graphene, 2017, 6(1): 1-18.
25	PEI S, WEI Q, HUANG K, et al. Green synthesis of graphene oxide by seconds timescale water electrolytic oxidation[J]. Nature Communications, 2018, 9(1): 1-9.
26	ZAABA N I, FOO K L, HASHIM U, et al. Synthesis of graphene oxide using modified hummers method: solvent influence[J]. Procedia Engineering, 2017, 184: 469-477.
27	PENG W, LI H, LIU Y, et al. A review on heavy metal ions adsorption from water by graphene oxide and its composites[J]. Journal of Molecular Liquids, 2017, 230: 496-504.
28	刘静静, 楚晖娟, 魏宏亮, 等. 石墨烯基水凝胶的研究进展[J]. 化学进展, 2015, 27(11): 1591-1603.
28	LIU Jingjing, CHU Huijuan, WEI Hongliang, et al. Progress in hydrogels based on graphene[J]. Progress in Chemistry, 2015, 27(11): 1591-1603.
29	李然, 刘小建, 李岚, 等.石墨烯/氧化石墨烯基复合水凝胶的研究进展[J]. 材料导报, 2016, 30(S1): 244-251.
29	LI Ran, LIU Xiaojian, LI Lan, et al. Review on graphene/graphene oxide-based hydrogels[J]. Materials Review, 2016, 30(S1): 244-251.
30	崔汶静, 陈建, 谢纯, 等. 聚丙烯酸钠/氧化石墨烯复合材料的制备和性能[J]. 炭素, 2012(1):13-17.
30	CUI Wenjing, CHEN Jian, XIE Chun, et al. Preparation and properties of sodium polycrylate/graphene oxide composites[J]. Carbon, 2012(1):13-17.
31	PERIASAMY A P, WU W, RAVINDRANATH R, et al. Polymer/reduced graphene oxide functionalized sponges as superabsorbents for oil removal and recovery[J]. Marine Pollution Bulletin, 2017, 114(2):888-895.
32	WU G, CHENG Y, WANG Z, et al. In situ polymerization of modified graphene/polyimide composite with improved mechanical and thermal properties[J]. Journal of Materials Science: Materials in Electronics, 2017, 28(1): 576-581.
33	HOSSEINI S M, SHAHROUSVAND M, SHOJAEI S, et al. Preparation of superabsorbent eco-friendly semi-interpenetrating network based on cross-linked poly acrylic acid/xanthan gum/graphene oxide (PAA/XG/GO): characterization and dye removal ability[J]. International Journal of Biological Macromolecules, 2020, 19: 40525-40537.
34	WANG Z, NING A, XIE P, et al. Synthesis and swelling behaviors of carboxymethyl cellulose-based superabsorbent resin hybridized with graphene oxide[J]. Carbohydrate Polymers, 2017, 157: 48-56.
35	HUANG Y, ZENG M, REN J, et al. Preparation and swelling properties of graphene oxide/poly (acrylic acid-co-acrylamide) super-absorbent hydrogel nanocomposites[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2012, 401: 97-106.
36	GORJI M, KARIMI M, MASHAIEKHI G, et al. Superabsorbent, breathable graphene oxide-based nanocomposite hydrogel as a dense membrane for use in protective clothing[J]. Polymer-Plastics Technology and Materials, 2019, 58(2): 182-192.
37	张聂, 卢小菊, 孟鸳. 氧化石墨烯增强聚丙烯酰胺水凝胶的力学性能[J]. 高分子材料科学与工程, 2019, 35(9): 53-61.
37	ZHANG Nie, LU Xiaoju, MENG Yuan. Mechanical properties of graphene oxide enhanced polyacrylamide hydrogels[J]. Polymeric Materials Science and Engineering, 2019, 35(9): 53-61.
38	刘翠云, 高喜平, 刘捷, 等. SA/PAM/GO纳米复合水凝胶的制备和性能[J]. 材料研究学报, 2015, 29(7): 517-522.
38	LIU Cuiyun, GAO Xiping, LIU Jie, et al. Preparation and properties of sodium alginate/polyacrylamide/graphene oxide nanocomposite hydrogels[J]. Chinese Journal of Materials Research, 2015, 29(7): 517-522.
39	HE Z, SHEN A, GUO Y, et al. Cement-based materials modified with superabsorbent polymers: a review[J]. Construction and Building Materials, 2019, 225: 569-590.
40	HOSSEINZADEH H, RAMIN S. Fast and enhanced removal of mercury from aqueous solutions by magnetic starch-g-poly (acryl amide)/graphene oxide nanocomposite superabsorbents[J]. Polymer Science Series B, 2016, 58(4): 457-473.
41	ZHU L, LIU Y, ZHOU B, et al. Synthesis and the swelling behavior of sodium alginate graft poly (acrylic acid-co-acrylamide)/graphite oxide super absorbent composite[J]. Polymer Science, Series B, 2019, 61(5): 680-690.
42	TANG Y, GUAN C, LIU Y, et al. Preparation and absorption studies of poly (acrylic acid-co-2-acrylamide-2-methyl-1-propane sulfonic acid)/graphene oxide superabsorbent composite[J]. Polymer Bulletin, 2019, 76(3): 1383-1399.
43	WEI X, HUANG T, YANG J, et al. Green synthesis of hybrid graphene oxide/microcrystalline cellulose aerogels and their use as superabsorbents[J]. Journal of Hazardous Materials, 2017, 335: 28-38.
44	周爱军, 夏瑞, 孙贺雷, 等. 氧化石墨烯改性吸水树脂[J]. 胶体与聚合物, 2018, 36(3): 124-126.
44	ZHOU Aijun, XIA Rui, SUN Helei, et al. Graphene oxide modified absorbent resin[J]. Chinese Journal of Colloid & Polymer, 2018, 36(3): 124-126.
45	FERREIRA N N, FERREIRA L M B, CARDOSO V M O, et al. Recent advances in smart hydrogels for biomedical applications: from self-assembly to functional approaches[J]. European Polymer Journal, 2018, 99: 117-133.
46	WANG W, ZHAO Y, YI H, et al. Preparation and characterization of self-assembly hydrogels with exfoliated montmorillonite nanosheets and chitosan[J]. Nanotechnology, 2017, 29(2): 025605.
47	HUANG Y, ZENG M, FENG Z, et al. Graphene oxide-based composite hydrogels with self-assembled macroporous structures[J]. RSC Advances, 2016, 6(5): 3561-3570.
48	ZHAO H, JIAO T, ZHANG L, et al. Preparation and adsorption capacity evaluation of graphene oxide-chitosan composite hydrogels[J]. Science China Materials, 2015, 58: 811-818.
49	李亮, 喻航达, 邱唯楚, 等. 海藻酸钠/氧化石墨烯复合水凝胶的制备与性能[J]. 武汉工程大学学报, 2018, 40(6): 641-644.
49	LI Liang, YU Hangda, QIU Weichu, et al. Preparation and properties of sodium alginate/graphene oxidecompoiste hydrogels[J]. Journal of Wuhan Institute of Technology, 2018, 40(6): 641-644.
50	XIA X, ZHANG X, YI S, et al. Preparation of high specific surface area composite carbon cryogels from self-assembly of graphene oxide and resorcinol monomers for supercapacitors[J]. Journal of Solid State Electrochemistry, 2016, 20(6): 1793-1802.
51	李欣儒, 郑力军, 石华强, 等. P(AA-AM)复合石墨烯凝胶暂堵剂的研制及性能评价[J]. 应用化工, 2019, 48(8): 1805-1808.
51	LI Xinru, ZHENG Lijun, SHI Huaqiang, et al. Preparation and characterization of P(AA-AM) composite grapheme temporary plugging agent[J]. Applied Chemical Industry, 2019, 48(8): 1805-1808.
52	GE H, MA Z. Microwave preparation of triethylenetetramine modified graphene oxide/chitosan composite for adsorption of Cr(Ⅵ)[J]. Carbohydrate Polymers, 2015, 131: 280-287.
53	XIE R, REN P, JIAN H, et al. Preparation and properties of graphene oxide-regenerated cellulose/polyvinyl alcohol hydrogel with pH-sensitive behavior[J]. Carbohydrate Polymers, 2016, 138: 222-228.
54	RABIPOUR M, POUR Z S, SAHRAEI R, et al. pH-sensitive nanocomposite hydrogels based on poly (vinyl alcohol) macromonomer and graphene oxide for removal of cationic dyes from aqueous solutions[J]. Journal of Polymers and the Environment, 2020, 28(2): 584-597.
55	LEE S, LEE H, SIM J H, et al. Graphene oxide/poly (acrylic acid) hydrogel by γ-ray pre-irradiation on graphene oxide surface[J]. Macromolecular Research, 2014, 22(2): 165-172.
56	DAI H, ZHANG Y, MA L, et al. Synthesis and response of pineapple peel carboxymethyl cellulose-g-poly(acrylic acid-co-acrylamide)/graphene oxide hydrogels[J]. Carbohydrate Polymers, 2019, 215: 366-376.
57	ZHU L, WANG F, LIU Y, et al. Preparation and absorption properties of poly(acrylic acid-co-acrylamide)/graphite oxide superabsorbent composite[J]. Advances in Polymer Technology, 2018, 37(8): 3680-3688.
58	TANG Y, TANG H, WANG F, et al. Synthesis and swelling behavior of poly(acrylic acid)/graphite oxide superabsorbent composite[J]. Polymer Science, Series B, 2019, 61(4): 471-478.
59	ZHU L, LIU Y, WANG F, et al. Preparation and the swelling properties of sodium alginate graft poly(acrylic acid-co-2-acrylamide-2-methyl propane sulfonic acid)/graphene oxide hydrogel composite[J]. Advances in Polymer Technology, 2018, 37(8): 2885-2893.
60	王欢, 张萍, 陈佑宁. 氧化石墨烯/聚海藻酸钠丙烯酸凝胶的制备及溶胀性能研究[J]. 精细石油化工, 2017, 34(1): 34-39.
60	WANG Huan, ZHANG Ping, CHEN Youning. Preparation and swelling properties of grapheneoxide/poly(sodium alginate-co-acrylic acid) absorbent hydrogel nanocomposites[J]. Speciality Petrochemicals, 2017, 34(1): 34-39.
61	龚志明, 江丽芳. 氧化石墨烯壳聚糖复合水凝胶合成与溶胀研究[J]. 山东化工, 2018, 47(5): 42-45.
61	GONG Zhiming, JIANG Lifang. Synthesis and swelling properties of chitosan graphene oxide hygrogel[J]. Shandong Chemical Industry, 2018, 47(5): 42-45.
62	ZHANG H, ZHAI D, HE Y. Graphene oxide/polyacrylamide/carboxymethyl cellulose sodium nanocomposite hydrogel with enhanced mechanical strength: preparation, characterization and the swelling behavior[J]. RSC Advances, 2014, 4(84): 44600-44609.
63	JI J, YU X, CHENG P, et al. Assembly of polypyrrole-graphene oxide hydrogel nanocomposites and their swelling properties[J]. Journal of Macromolecular Science, Part B, 2015, 54(9): 1122-1131.
64	ROBATI D, MIRZA B, RAJABI M, et al. Removal of hazardous dyes-BR 12 and methyl orange using graphene oxide as an adsorbent from aqueous phase[J]. Chemical Engineering Journal, 2016, 284: 687-697.
65	DAS L, DAS P, BHOWAL A, et al. Synthesis of hybrid hydrogel nano-polymer composite using graphene oxide, chitosan and PVA and its application in waste water treatment[J]. Environmental Technology & Innovation, 2020, 18: 100664-100672.
66	VARAPRASAD K, JAYARAMUDU T, SADIKU E R. Removal of dye by carboxymethyl cellulose, acrylamide and graphene oxide via a free radical polymerization process[J]. Carbohydrate Polymers, 2017, 164: 186-194.
67	GAN L, LI H, CHEN L, et al. Graphene oxide incorporated alginate hydrogel beads for the removal of various organic dyes and bisphenol a in water[J]. Colloid and Polymer Science, 2018, 296(3): 607-615.
68	DONG C, LU J, QIU B, et al. Developing stretchable and graphene-oxide-based hydrogel for the removal of organic pollutants and metal ions[J]. Applied Catalysis B: Environmental, 2018, 222: 146-156.
69	SAHRAEI R, GHAEMY M. Synthesis of modified gum tragacanth/graphene oxide composite hydrogel for heavy metal ions removal and preparation of silver nanocomposite for antibacterial activity[J]. Carbohydrate Polymers, 2017, 157: 823-833.
70	PIAO Y, CHEN B. Synthesis and mechanical properties of double cross-linked gelatin-graphene oxide hydrogels[J]. International Journal of Biological Macromolecules, 2017, 101: 791-798.
71	PENG X, LIU T, SHANG C, et al. Mechanically strong janus poly(N-isopropylacrylamide)/graphene oxide hydrogels as thermo-responsive soft robots[J]. Chinese Journal of Polymer Science, 2017, 35(10): 1268-1275.
72	ZHANG D, YANG S, CHEN Y, et al. 60Co γ-ray irradiation crosslinking of chitosan/graphene oxide composite film: swelling, thermal stability, mechanical, and antibacterial properties[J]. Polymers, 2018, 10(3): 294.
73	谢标明, 朱和康, 杨越, 等. 聚丙烯酸/氧化石墨烯复合水凝胶制备及对亚甲基蓝吸附[J]. 精细化工, 2018, 35(1): 108-117.
73	XIE Biaoming, ZHU Hekang, YANG Yue, et al. Synthesis of poly (acrylic acid)/ graphene oxide composite hydrogels and their adsorption properties for methylene blue dye[J]. Fine Chemicals, 2018, 35(1): 108-117.
74	YAN X, YANG J, CHEN F, et al. Mechanical properties of gelatin/polyacrylamide/graphene oxide nanocomposite double-network hydrogels[J]. Composites Science and Technology, 2018, 163: 81-88.
75	王趁义, 王国贺, 王凤玲, 等. 氧化石墨烯改性聚（丙烯酸/丙烯酰胺）高吸水树脂的制备及性能研究[J]. 化工新型材料, 2019, 47(5): 90-95.
75	WANG Chenyi, WANG Guohe, WANG Fengling, et al. Preparation and property of P(AA/AM) SAP modified by GO[J]. New Chemical Materials, 2019, 47(5): 90-95.
76	HUANG S, SHEN J, LI N, et al. Dual pH-and temperature-responsive hydrogels with extraordinary swelling/deswelling behavior and enhanced mechanical performances[J]. Journal of Applied Polymer Science, 2015, 132(9): 41530-41538.
77	MALEKI A, HAJIZADEH Z, SHARIFI V, et al. A green, porous and eco-friendly magnetic geopolymer adsorbent for heavy metals removal from aqueous solutions[J]. Journal of Cleaner Production, 2019, 215: 1233-1245.
78	BOLISETTY S, PEYDAYESH M, MEZZENGA R. Sustainable technologies for water purification from heavy metals: review and analysis[J]. Chemical Society Reviews, 2019, 48(2): 463-487.
79	YADAV V B, GADI R, KALRA S. Clay based nanocomposites for removal of heavy metals from water: a review[J]. Journal of Environmental Management, 2019, 232: 803-817.
80	何梦奇, 徐继红, 段贤扬, 等. GO/GA-g-PAMPS复合水凝胶的制备及其对阳离子染料的吸附性能[J]. 精细化工, 2020, 37(5): 924-932.
80	HE Mengqi, XU Jihong, DUAN Xianyang, et al. Preparation of GO/GA-g-PAMPS composite hydrogels and study on dye adsorption properties[J]. Fine Chemicals, 2020, 37(5): 924-932.
81	CHANG Z, CHEN Y, TANG S, et al. Construction of chitosan/polyacrylate/graphene oxide composite physical hydrogel by semi-dissolution/acidification/sol-gel transition method and its simultaneous cationic and anionic dye adsorption properties[J]. Carbohydrate Polymers, 2020, 229: 115431-115440.
82	LI X, ZHOU H, WU W, et al. Studies of heavy metal ion adsorption on chitosan/sulfydryl-functionalized graphene oxide composites[J]. Journal of Colloid and Interface Science, 2015, 448: 389-397.
83	LIANG Z, WU S, WANG Y, et al. The relationship between urban form and heat island intensity along the urban development gradients[J]. Science of the Total Environment, 2020, 708: 135011-135023.
84	董强, 凌天清, 熊出华. 聚乙烯醇分子结构对聚乙烯醇/氧化石墨烯复合材料吸水保水性能的影响[J]. 高分子材料科学与工程, 2019, 35(5): 38-43.
84	DONG Qiang, LING Tianqing, XIONG Chuhua. Microstructure and water absorption properties of polyvinyl alcoholand preparation of polyvinyl alcohol/graphene oxide composites with high water absorbing properties[J]. Polymeric Materials Science and Engineering, 2019, 35(5): 38-43.
85	邵宇, 吴称意, 程超, 等.海藻酸钠-g-聚丙烯酰胺/氧化石墨烯复合水凝胶的制备及控释行为[J]. 高分子材料科学与工程, 2018, 34(4): 104-109.
85	SHAO Yu, WU Chenyi, CHENG Chao, et al. Preparation and controlled release behavior of sodium alginate-g-polyacrylamide/graphene oxide composite hydrogel[J]. Polymeric Materials Science and Engineering, 2018, 34(4): 104-109.
86	LIU C, LIU H, LU C, et al. Polyethyleneimine-modified graphene oxide/PNIPAM thermoresponsive hydrogels with rapid swelling/deswelling and improved mechanical properties[J]. Journal of Materials Science, 2017, 52(19): 11715-11724.

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