耦合膜分离的新型CO2低温捕集系统性能优化

doi:10.16085/j.issn.1000-6613.2019-1579

化工进展 ›› 2020, Vol. 39 ›› Issue (7): 2884-2892.DOI: 10.16085/j.issn.1000-6613.2019-1579

耦合膜分离的新型CO₂低温捕集系统性能优化

田华¹(), 孙瑞¹, 宋春风²^,³, 邓帅³, 石凌峰¹, 康克¹, 舒歌群¹()

^1.天津大学内燃机燃烧学国家重点实验室，天津 300072
^2.天津大学环境科学与工程学院，天津 300072
^3.中低温热能高效利用教育部重点实验室(天津大学)，天津 300350

出版日期:2020-07-05 发布日期:2020-07-10
通讯作者: 舒歌群
作者简介:田华（1984—），特聘研究员，博士生导师，研究方向为能源动力系统节能减排。E-mail：thtju@tju.edu.cn。
基金资助:
国家自然科学基金面上项目(51676133)

Optimization of novel hybrid cryogenic CO₂ capture process with membrane separation

Hua TIAN¹(), Rui SUN¹, Chunfeng SONG²^,³, Shuai DENG³, Lingfeng SHI¹, Ke KANG¹, Gequn SHU¹()

^1.State Key Laboratory of Engines, Tianjin University, Tianjin 300072, China
^2.School of Environmental Science and Technology, Tianjin University, Tianjin 300072, China
^3.Key Laboratory of Efficient Utilization of Low and Medium Grade Energy (Tianjin University), Ministry of Education, Tianjin 300350, China

Online:2020-07-05 Published:2020-07-10
Contact: Gequn SHU

摘要/Abstract

摘要：

CO₂捕集作为温室气体排放控制的有效手段已成为重要研究课题。作为新兴捕集技术之一，低温CO₂捕集因产品纯度高、无附加污染等优势受到关注。然而，该技术能耗和捕集率对于气体中CO₂浓度十分敏感，对于高CO₂浓度气体可获得较高的CO₂捕集率和较低能耗水平。基于此，本文提出了耦合膜分离的新型CO₂低温捕集系统，通过膜材料选择渗透性实现待捕集气体CO₂浓度主动调控，并在最优浓度下进行CO₂低温捕集。首先基于不同传统低温捕集系统特点，对比分析了不同耦合系统模式，从而确定了最优耦合系统结构。针对最优耦合系统进行了运行参数优化，并分别基于实现系统捕集能耗最低与捕集率最高的目标，获得了膜渗透侧CO₂浓度与进气CO₂浓度间的关系式，为该耦合系统中膜组件选型提供指导。研究表明，本文提出的耦合系统捕集能耗为1.92MJ/kgCO₂，相比于传统单一低温系统捕集能耗可降低16.5%。

关键词: 二氧化碳捕集, 低温, 膜, 耦合系统, 优化

Abstract:

As an effective means of greenhouse gas emission control, CO₂ capture has become an important research topic. As one of the emerging technologies, cryogenic CO₂ capture has received attention due to its technological advantages in product purity. However, energy consumption and CO₂ recovery in the cryogenic CO₂ capture are very sensitive to feed gas CO₂ concentration, and the high CO₂ concentration feed gas is beneficial for obtaining a higher CO₂ recovery and a lower energy consumption level simultaneously. Therefore, a novel hybrid cryogenic CO₂ capture process with membrane separation was proposed. The feed gas CO₂ concentration was actively controlled by membrane selectivity, hence cryogenic CO₂ capture was carried out at the optimal concentration. In this paper, based on the characteristics of different traditional cryogenic capture processes, different hybrid process modes were compared and analyzed to determine the optimal hybrid process structure. The optimal operating parameters of the hybrid process were determined, and the relationship between membrane permeate side CO₂ concentration and feed gas CO₂ concentration was obtained based on the goal of achieving the lowest energy consumption and the highest CO₂ recovery, providing guidance for the selection of membrane modules in the hybrid process. The energy consumption of the proposed hybrid process is 1.92MJ/kgCO₂, which was reduced by 16.5% compared to the traditional cryogenic process.

Key words: CO₂ capture, cryogenic, membranes, hybrid process, optimization

中图分类号:

X701.7

田华, 孙瑞, 宋春风, 邓帅, 石凌峰, 康克, 舒歌群. 耦合膜分离的新型CO₂低温捕集系统性能优化[J]. 化工进展, 2020, 39(7): 2884-2892.

Hua TIAN, Rui SUN, Chunfeng SONG, Shuai DENG, Lingfeng SHI, Ke KANG, Gequn SHU. Optimization of novel hybrid cryogenic CO₂ capture process with membrane separation[J]. Chemical Industry and Engineering Progress, 2020, 39(7): 2884-2892.

参考文献

1	BUI M, ADJIMAN C S, BARDOW A, et al. Carbon capture and storage (CCS): the way forward[J]. Energy & Environmental Science, 2018, 11(5): 1062-1176.
2	METZ B, DAVIDSON O, DE CONINCK H. Carbon dioxide capture and storage: special report of the intergovernmental panel on climate change [M]. Cambridge: Cambridge University Press, 2005.
3	SONG Chunfeng, LIU Qingling, DENG Shuai, et al. Cryogenic-based CO₂ capture technologies: state-of-the-art developments and current challenges[J]. Renewable & Sustainable Energy Reviews, 2019, 101: 265-278.
4	TUINIER M J, SINT ANNALAND M VAN, KUIPERS J A M. A novel process for cryogenic CO₂ capture using dynamically operated packed beds—An experimental and numerical study[J]. International Journal of Greenhouse Gas Control, 2011, 5(4): 694-701.
5	NALETOV V A, LUKYANOV V L, KULOV N N, et al. An experimental study of desublimation of carbon dioxide from a gas mixture[J]. Theoretical Foundations of Chemical Engineering, 2014, 48(3): 312-319.
6	CLODIC D, HITTI R EL, YOUNES M, et al. CO₂ capture by anti-sublimation thermo-economic process evaluation [C]// DOE/NETL. 4th Annual Conference on Carbon Capture and Sequestration, Alexandria, USA: National Energy Technology Laboratory, 2005: 2-5.
7	BERSTAD D, ANANTHARAMAN R, NEKS? P. Low-temperature CO₂ capture technologies-applications and potential[J]. International Journal of Refrigeration, 2013, 36(5): 1403-1416.
8	XU Jiayou, WANG Zhi, QIAO Zhihua, et al. Post-combustion CO₂ capture with membrane process: practical membrane performance and appropriate pressure[J]. Journal of Membrane Science, 2019, 581: 195-213.
9	孙亚伟, 谢美连, 刘庆岭, 等. 膜法分离燃煤电厂烟气中CO₂的研究现状及进展[J]. 化工进展, 2017, 36(5): 1880-1889.
9	SUN Yawei, XIE Meilian, LIU Qingling, et al. Membrane-based carbon dioxide separation from flue gases of coal-fired power plant — current status and developments[J]. Chemical Industry and Engineering Progress, 2017, 36(5): 1880-1889.
10	FAVRE E. Membrane processes and postcombustion carbon dioxide capture: challenges and prospects[J]. Chemical Engineering Journal, 2011, 171(3): 782-793.
11	BELAISSAOUI B, WILLSON D, FAVRE E. Membrane gas separations and post-combustion carbon dioxide capture: parametric sensitivity and process integration strategies[J]. Chemical Engineering Journal, 2012, 211: 122-132.
12	BELAISSAOUI B, LE MOULLEC Y, WILLSON D, et al. Hybrid membrane cryogenic process for post-combustion CO₂ capture[J]. Journal of Membrane Science, 2012, 415: 424-434.
13	ZHANG Xiangping, SINGH B, HE Xuezhong, et al. Post-combustion carbon capture technologies: energetic analysis and life cycle assessment[J]. International Journal of Greenhouse Gas Control, 2014, 27: 289-298.
14	MAT N C, LIPSCOMB G G. Global sensitivity analysis for hybrid membrane-cryogenic post combustion carbon capture process[J]. International Journal of Greenhouse Gas Control, 2019, 81: 157-169.
15	WANG Y N, PFOTENHAUER J M, ZHI Xiaoqin, et al. Transient model of carbon dioxide desublimation from nitrogen-carbon dioxide gas mixture[J]. International Journal of Heat and Mass Transfer, 2018, 127: 339-347.
16	袁灵成. 基于低温凝华法的二氧化碳捕集技术理论与实验研究[D]. 杭州: 浙江大学, 2015.
16	YUAN Lingcheng. Theoretical and experimental investigation of cryogenic CO₂ capture by desublimation [D]. Hangzhou: Zhejiang University, 2015.
17	JAGER A, SPAN R. Equation of state for solid carbon dioxide based on the Gibbs free energy[J]. Journal of Chemical and Engineering Data, 2012, 57(2): 590-597.
18	ZHAI Haibo, RUBIN E S. Techno-economic assessment of polymer membrane systems for postcombustion carbon capture at coal-fired power plants[J]. Environmental Science & Technology, 2013, 47(6): 3006-3014.
19	YANG Wenchao, LI Shuhong, LI Xianliang, et al. Analysis of a new liquefaction combined with desublimation system for CO₂ separation based on N₂/CO₂ phase equilibrium[J]. Energies, 2015, 8(9): 9495-9508.
20	SONG Chunfeng, LIU Qingling, JI Na, et al. Reducing the energy consumption of membrane-cryogenic hybrid CO₂ capture by process optimization[J]. Energy, 2017, 124: 29-39.
21	BOUNACEUR R, LAPE N, ROIZARD D, et al. Membrane processes for post-combustion carbon dioxide capture: a parametric study[J]. Energy, 2006, 31(14): 2556-2570.
22	SONG Chunfeng, KITAMURA Y, LI Shuhong, et al. Design of a cryogenic CO₂ capture system based on Stirling coolers[J]. International Journal of Greenhouse Gas Control, 2012, 7: 107-114.

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耦合膜分离的新型CO₂低温捕集系统性能优化

Optimization of novel hybrid cryogenic CO₂ capture process with membrane separation

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