超双疏含氟聚合物的研究进展

doi:10.16085/j.issn.1000-6613.2019-0943

摘要/Abstract

摘要：

超双疏功能性材料在当代化工材料中有着重要的地位，其独特的界面性能使得其在各个领域的应用中大显身手。本文介绍了近年来国内外对含氟聚合物在超双疏领域的研究近况，包括超双疏含氟聚合物的结构特点和合成方法等。含氟聚合物的表面拥有超低的表面能和独特的空间排列方式，通过对比不同结构的含氟聚合物分子与其性能的关系以及对各类含氟聚合物合成方法的调研，发现含氟聚合物作为超双疏涂层材料的使用十分广泛，其结构中含氟单体主要为氟取代丙烯酸酯类，合成方法多为乳液聚合。超疏水含氟聚合物与纳米颗粒材料的结合是当今研究的热点，文中列举了大量研究实例，希望其中的研究方法和合成路线等能对今后该领域的研究起到一定的借鉴作用。

关键词: 超双疏, 含氟聚合物, 涂层, 聚合, 纳米结构

Abstract:

Super-amphiphobic functional materials play an important role in contemporary chemical materials, and their unique interface properties make them outstanding in various fields. In this paper, the recent research progress of fluoropolymers in the field of super-amphiphobic at home and abroad is introduced, including the structural characteristics and synthesis methods of super-amphiphobic fluoropolymers. The surface of fluoropolymers has ultra-low surface energy and unique spatial arrangement. By comparing the relationship between fluoropolymers with different structures and their properties, as well as the synthesis methods of various fluoropolymers, the investigation shows that fluoropolymer is the most widely used as super super-amphiphobic coating material. Its fluorine-containing monomer is mainly fluorinated acrylate, and its synthesis methods are mostly emulsion polymerization. The combination of superhydrophobic fluoropolymers and nano-particle materials is a hotspot in current research. A large number of research examples are listed in this paper. It is hoped that the research methods and synthetic routes can play a reference role in future research.

Key words: super-amphiphobic, fluoropolymers, coating, polymerization, nanostructure

中图分类号:

TQ317

梁雷,王彦玲,张杉. 超双疏含氟聚合物的研究进展[J]. 化工进展, 2020, 39(3): 1070-1079.

Lei LIANG,Yanling WANG,Shan ZHANG. Research progress of super-amphiphobic fluoropolymers[J]. Chemical Industry and Engineering Progress, 2020, 39(3): 1070-1079.

图/表 1

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