化工进展 ›› 2020, Vol. 39 ›› Issue (1): 387-394.DOI: 10.16085/j.issn.1000-6613.2019-0574

• 资源与环境化工 • 上一篇    下一篇

流化床垃圾焚烧炉飞灰沉积实验

唐智(),陈晓平(),刘道银,梁财,马吉亮   

  1. 东南大学能源热转换及其过程测控教育部重点实验室,江苏 南京 210096
  • 收稿日期:2019-04-12 出版日期:2020-01-05 发布日期:2020-01-14
  • 通讯作者: 陈晓平
  • 作者简介:唐智(1986—),男,博士研究生,研究方向为固体废弃物处理及能源利用。E-mail:tangzhi@seu.edu.cn
  • 基金资助:
    国家自然科学基金(51776040)

Experimental investigation of ash deposition on heating surfaces in a municipal solid waste (MSW) bubbling fluidized beds

Zhi TANG(),Xiaoping CHEN(),Daoyin LIU,Cai LIANG,Jiliang MA   

  1. Key Laboratory of Energy Thermal Conversion and Process Control of Ministry of Education, Southeast University, Nanjing 210096, Jiangsu, China
  • Received:2019-04-12 Online:2020-01-05 Published:2020-01-14
  • Contact: Xiaoping CHEN

摘要:

在自行搭建的小型流化床积灰试验台上选用流化床垃圾焚烧炉对流管束浮灰,模拟焚烧炉烟气环境下开展飞灰沉积实验。首先分析浮灰理化特性,结果表明:随着粒径增大,浮灰中CaO和SO3含量逐渐降低,而SiO2和Al2O3的含量逐渐增加;碱金属Na和K以及卤素Cl的含量在粒径较小的浮灰中含量最高。其次重点研究了浮灰粒径、烟气温度和换热管表面温度对飞灰沉积特性的影响规律,结果表明:积灰中主要富含Ca、S、Si和Al等元素,积灰中CaO和SO3含量比浮灰高,而Al2O3和SiO2含量比浮灰低;积灰量随着烟气温度升高而增加;粒径对灰沉积影响作用显著,大粒径灰颗粒难沉积而小粒径灰粒易沉积;管壁温度在600℃时,积灰量最小。积灰中CaO和SO3的含量随着管壁温度升高而减少,而难熔Al2O3和SiO2的含量随着管壁温度升高而增加。

关键词: 流化床, 废物处理, 沉积物, 对流受热面, 碱金属

Abstract:

Experiments were carried out to examine the ash depositon characteristics in a bench-scale circulating fluidized bed (CFB). The influence of ash particle sizes, flue gas temperatures and heat exchange tube surfaces temperature (500℃, 550℃, 600℃ and 650℃) on ash deposit formation rate was investigated. The results indicated that with the increase of particle size, the content of CaO and SO3 in the loose-like fouling ash gradually decreased, while the content of SiO2 and Al2O3 increased gradually. The contents of the alkali metals Na and K and the halogen Cl were the highest in the ash with a smaller particle size. The ash deposition is mainly rich in elements such as Ca, S, Si and Al. The content of CaO and SO3 in the ash is higher than that in the fouling ash, while the content of Al2O3 and SiO2 is lower. The deposition mass increases as the temperature of the flue gas increases, and decrease as the particle size range of the fly ash increases. The effect of particle size on ash deposition is significant. Large-size ash particles are difficult to deposit while small-size ash particles are easy to deposit. The deposition mass achieve a minimum at the probe surface temperature of 600℃. The content of CaO and SO3 decreases as the probe surface increases, while the content of refractory Al2O3 and SiO2 increases as the wall temperature increases.

Key words: fluidized-bed, waste treatment, deposition, convection heating surfaces, alkali metals

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