多种类型液滴蒸发综述

doi:10.16085/j.issn.1000-6613.2018-1476

摘要/Abstract

摘要： 液滴蒸发过程是伴随着复杂变化但又没有统一且充分认知的的过程，是目前一个重要的研究热点，在许多科学应用中起到关键作用。本文介绍了液滴蒸发的历史研究过程，综述了3种不同类型液滴，即纯液滴、二元混合溶液液滴和聚合物溶液液滴蒸发过程的研究成果，分析了液滴蒸发过程中和蒸发结束后沉积物的影响因素，简述了液滴的研究成果在实际生活中的应用。现有研究表明，不同类型液滴的蒸发过程受到多种因素的影响，比如溶液中的纳米粒子、环境温度和压力等。这些因素还会影响到沉积物的图案和大小。目前，研究人员已经研究出典型的液滴蒸发过程（接触线固定和接触角固定模式），讨论出液滴蒸发基本理论。对一些常见的二元及多元溶液，研究人员已经发现它们与纯溶液蒸发过程的不同之处，并且已经在科学界进行了大量的研究及讨论，建立出数学模型。最后重点介绍了液滴蒸发在医学领域的研究成果、应用和未来发展的方向，比如通过生物液滴蒸发后的沉积物的纳米层，跟正常沉积物对比结果来检测疾病等。最后对液滴蒸发理论的现状、潜力和未来发展需求进行了总结和展望。

关键词: 蒸发, 纳米粒子, 纳米技术, 沉积物

Abstract: Droplet evaporation is a complex process that is accompanied by complex changes but not uniform and well recognized, and this is an important research hotspot and plays a key role in many scientific applications. This paper introduces the historical research process of droplet evaporation, and this research results of three different types of droplets evaporation processes are reviewed, such as pure droplets, binary mixed solution droplets and polymer solution droplets. The influencing factors of droplet evaporation and sediment after evaporation were analyzed, and the application of droplet research results in real life is briefly introduced. Existing studies have shown that the evaporation process of different types of droplets is affected by a variety of factors, such as nanoparticles in solution, ambient temperature, pressure and so on. And these factors also influence the pattern and size of the sediment. Currently, researchers have developed a typical droplet evaporation process (contact line fixation and contact Angle fixation mode), and the basic theory of droplet evaporation has been discussed. For some common binary and multi-component solutions, researchers have found that their evaporation process differ from the pure solution evaporation process, and have done a lot of research and discussion in the scientific community to establish a mathematical model. Finally, the research results, applications, and directions for future development of droplet evaporation in the medical field are highlighted. For example, the nano-layers of sediments after evaporation of biological droplets are compared with normal sediments to detect diseases. Finally, the recent progress, potential and future development requirements of droplet evaporation theory are summarized and forecasted.

Key words: evaporation, nanoparticles, nanotechnology, deposition

中图分类号:

TK124

柴琳, 杨文哲, 刘斌, 陈爱强. 多种类型液滴蒸发综述[J]. 化工进展, 2018, 37(S1): 19-28.

CHAI Lin, YANG Wenzhe, Liu Bin, Chen Aiqiang. Various types of droplet evaporation: summarize[J]. Chemical Industry and Engineering Progress, 2018, 37(S1): 19-28.

参考文献

[1] YOUNG T. Ⅲ. An essay on the cohesion of fluids[J]. Philosophical Transactions of the Royal Society of London, 1805, 95:65-87.
[2] FUKATANI Y, OREJON D, KITA Y, et al. Effect of ambient temperature and relative humidity on interfacial temperature during early stages of drop evaporation[J]. Physical Review E, 2016, 93(4-1):043103.
[3] POMPE T, HERMINGHAUS S. Three-phase contact line energetics from nanoscale liquid surface topographies[J]. Physical Review Letters, 2000, 85(9):1930-1933.
[4] JERISON E R, XU Y, WILEN L A, et al. Deformation of an elastic substrate by a three-phase contact line.[J]. Physical Review Letters, 2011, 106(18):186103-4.
[5] OREJON D, SHANAHAN M E R, TAKATA Y, et al. Kinetics of evaporation of pinned nanofluid volatile droplets at subatmospheric pressures[J]. Langmuir, 2016, 32(23):5812-5820.
[6] SEFIANE K. Patterns from drying drops[J]. Advances in Colloid & Interface Science, 2014, 206(2):372-381.
[7] BARDALL A, DANIELS K E, SHEARER M. Deformation of an elastic substrate due to a resting sessile droplet[J]. European Journal of Applied Mathematics, 2018, 29(2):281-300.
[8] PICKNETT R G, BEXON R. Evaporation of sessile or pendant drops in still air[J]. Journal of Colloid & Interface Science, 1977, 61(2):336-350.
[9] TONINI S, COSSALI G E. An analytical model of liquid drop evaporation in gaseous environment[J]. International Journal of Thermal Sciences, 2012, 57(57):45-53.
[10] SAZHIN S S. Advanced models of fuel droplet heating and evaporation[J]. Progress in Energy & Combustion Science, 2006, 32(2):162-214.
[11] HOLYST R. Evaporation processes:100 years of misconceptions[J]. Chemical Engineer -London then Rugby, 2008;806:36-37.
[12] FENWICK E, MAXWELL J C. A bibliography of James Clerk Maxwell. Part 1[M]. Edinburgh:Edward Fenwick, 2009.
[13] ERBIL H Y. ChemInform abstract:evaporation of pure liquid sessile and spherical suspended drops:a review[J]. Advances in Colloid & Interface Science, 2012, 43(16):67-86.
[14] PICKNETT R G, BEXON R. Evaporation of sessile or pendant drops in still air[J]. Journal of Colloid & Interface Science, 1977, 61(2):336-350.
[15] ALSAN MERIC R, YILDIRIM ERBIL H. Evaporation of sessile drops on solid surfaces:pseudospherical cap geometry[J]. Langmuir, 1998, 14(7):1915-1920.
[16] LANGMUIR I. The Evaporation of small spheres[J]. Physical Review, 1918, 12(5):368-370.
[17] TOPLEY BRYAN, ROBERT WHYTLAW-GRAY LXXX. Experiments on the rate of evaporation of small spheres as a method of determining diffusion coefficients. â" the diffusion coefficient of iodine[J]. Philosophical Magazine, 1927, 4(24):873-888.
[18] GUDRIS N, KULIKOWA L. Die verdampfung kleiner wassertropfen[J]. Zeitschrift Für Physik, 1924, 25(1):121-132.
[19] HOUGHTON H G. A study of the evaporation of small water drops[J]. Physics, 1933, 4(12):419-424.
[20] DAVIS E J, SCHWEIGER G. Background[M]//The Airborne Microparticle. Springer Berlin Heidelberg, 2002:1-65.
[21] BRADLEY R S, EVANS M G, WHYTLAWGRAY R W. The rate of evaporation of droplets; evaporation and diffusion coefficients, and vapour pressures of dibutyl phthalate and butyl stearate[J]. Proceedings of the Royal Society of London, 1946, 186(1006):368-390.
[22] DAVIS E J, SCHWEIGER G. The airborne microparticle[M]. Berlin:Springer 2013.
[23] BRADLEY R S, SHELLARD A D. The rate of evaporation of droplets. Ⅲ. Vapour pressures and rates of evaporation of straight-Chain paraffin hydrocarbons[J]. Proceedings of the Royal Society of London, 1949, 198(1053):239-251.
[24] FREEBAIRN D, LINTON D, HARKINJONES E, et al. Electrical methods of controlling bacterial adhesion and biofilm on device surfaces[J]. Expert Rev Med Devices, 2013, 10(1):85-103.
[25] MATAR O, CRASTER R, SEFIANE K. Pinning, retraction and terracing of evaporating droplets containing nanoparticles[J]. Langmuir the ACS Journal of Surfaces & Colloids, 2009, 25(6):3601-36019.
[26] KIM J H, AHN S I, KIM J H, et al. Evaporation of water droplets on polymer surfaces.[J]. Langmuir the ACS Journal of Surfaces & Colloids, 2007, 23(11):6163-6169.
[27] BUFFONE C, SEFIANE K. Investigation of thermocapillary convective patterns and their role in the enhancement of evaporation from pores[J]. International Journal of Multiphase Flow, 2004, 30(9):1071-1091.
[28] SHAHIDZADEHBONN N, RAFAI S, AZOUNI A, et al. Evaporating droplets[J]. Journal of Fluid Mechanics, 2006, 549:307-313.
[29] DEEGAN R D, BAKAJIN O, DUPONT T F, et al. Capillary flow as the cause of ring stains from dried liquid drops[J]. Nature, 1997, 389(6653):827-829.
[30] DEEGAN R D, BAKAJIN O, DUPONT T F, et al. Contact line deposits in an evaporating drop[J]. Phys. Rev. E, 2000, 62(1PtB):756-765.
[31] GHASEMI H, WARD C A. Energy transport by thermocapillary convection during sessile-water-droplet evaporation[J]. Physical Review Letters, 2010, 105(13):136102-4.
[32] BUFFONE C, SEFIANE K, CHRISTY J R E. Experimental investigation of self-induced thermocapillary convection for an evaporating meniscus in capillary tubes using micro-particle image velocimetry[J]. Physics of Fluids, 2005, 17(5):1261-129.
[33] CHRISTY J R, HAMAMOTO Y, SEFIANE K. Flow transition within an evaporating binary mixture sessile drop[J]. Physical Review Letters, 2011, 106(20):205701.
[34] HAMAMOTO Y, CHRISTY J R E, SEFIANE K. The flow characteristics of an evaporating ethanol water mixture droplet on a glass substrate[J]. Journal of Thermal Science & Technology, 2012, 7(3):425-436.
[35] 金艳艳, 单彦广. 水-乙醇二元混合固着液滴的蒸发特性[J]. 化工学报, 2018, 69(7):2908-2915.
[36] CHIANG C K, LU Y W. Evaporation phase change processes of water/methanol mixtures on superhydrophobic nanostructured surfaces[J]. Journal of Micromechanics & Microengineering, 2011, 21(7):075003.
[37] HOPKINS R J, REID J P. A comparative study of the mass and heat transfer dynamics of evaporating ethanol/water, methanol/water, and 1-propanol/water aerosol droplets[J]. Journal of Physical Chemistry B, 2006, 110(7):3239-3249.
[38] CHEN X, WEIBEL J A, GARIMELLA S V. Water and ethanol droplet wetting transition during evaporation on omniphobic surfaces[J]. Scientific Reports, 2015, 5:17110.
[39] HOPKINS R J, REID J P. Evaporation of ethanol/water droplets:examining the temporal evolution of droplet size, composition and temperature[J]. Journal of Physical Chemistry A, 2005, 109(35):7923-7931.
[40] 王茉, 刘璐, 王鹏程, 等. 乙醇溶液液滴降压蒸发过程传热传质特性[J]. 化工进展, 2016, 35(3):717-721.
[41] MORIKAWA A, KEⅡ T. Change in interfacial tension during mass transfer-I.:Evaporation of n-propyl alcohol from its aqueous pendant drop[J]. Chemical Engineering Science, 1965, 20(3):255-259.
[42] HAMAMOTO Y, CHRISTY J R E, SEFIANE K. The flow characteristics of an evaporating ethanol water mixture droplet on a glass substrate[J]. Journal of Thermal Science & Technology, 2012, 7(3):425-436.
[43] 张文彬, 廖龙光, 于同旭, 等. 溶液液滴蒸发变干的环状沉积[J]. 物理学报, 2013, 62(19):361-368.
[44] WU S, LI W B, SHI F, et al. Observation of colloidal particle deposition during the confined droplet evaporation process[J]. Acta Physica Sinica, 2015, 64(9):96101-9.
[45] SEFIANE K, BENNACER R. Nanofluids droplets evaporation kinetics and wetting dynamics on rough heated substrates[J]. Adv. Colloid Interface Sci, 2009, 147(147/148):263-271.
[46] HU H, LARSON R G. Marangoni effect reverses coffee-ring depositions.[J]. Journal of Physical Chemistry B, 2006, 110(14):7090-4.
[47] ASKOUNIS A, SEFIANE K, KOUTSOS V, et al. The effect of evaporation kinetics on nanoparticle structuring within contact line deposits of volatile drops[J]. Colloids & Surfaces A, Physicochemical & Engineering Aspects, 2014, 441(3):855-866.
[48] ASKOUNIS A, SEFIANE K, KOUTSOS V, et al. Effect of particle geometry on triple line motion of nano-fluid drops and deposit nano-structuring.[J]. Adv. Colloid Interface Sci., 2015, 222:44-57.
[49] PARSA M, HARMAND S, SEFIANE K, et al. Effect of substrate temperature on pattern formation of nanoparticles from volatile drops[J]. Langmuir the ACS Journal of Surfaces & Colloids, 2015, 31(11):3354-3367.
[50] 刘斌, 单亮亮, 邸倩倩, 等. 底板属性对液滴蒸发过程的影响[J]. 工程热物理学报, 2017(9):1940-1943.
[51] 王东民, 董丽宁, 全晓军. 改性SiO₂纳米颗粒沸腾沉积层的形成原理及其沸腾换热[J]. 化工学报, 2018, 69(10):4200-4205.
[52] ASKOUNIS A, SEFIANE K, KOUTSOS V, et al. The effect of evaporation kinetics on nanoparticle structuring within contact line deposits of volatile drops[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects, 2014, 441(3):855-866.
[53] LIU B, BENNACER R, BOUVET A. Evaporation of methanol droplet on the teflon surface under different air velocities[J]. Applied Thermal Engineering, 2011, 31(17):3792-3798.
[54] OREJON D, SEFIANE K, SHANAHAN M E R. Evaporation of nanofluid droplets with applied DC potential[J]. J. Colloid Interface Sci., 2013, 407(10):29-38.
[55] HU H, LARSON R G. Marangoni effect reverses coffee-ring depositions.[J]. Journal of Physical Chemistry B, 2006, 110(14):7090-4.
[56] HE Q, HALLINAN K P. A new particle image velocimetry technique for three-dimensional full field fluid flow measurement in evaporating films[J]. Experimental Thermal & Fluid Science, 1998, 17(3):230-237.
[57] HEGSETH J J, RASHIDNIA N, CHAI A. Natural convection in droplet evaporation[J]. Physical Review E Statistical Physics Plasmas Fluids & Related Interdisciplinary Topics, 1996, 54(2):1640-1644.
[58] STEINCHEN A, SEFIANE K. Self-organised marangoni motion at evaporating drops or in capillary menisci - thermohydrodynamical model[J]. Journal of Non-Equilibrium Thermodynamics, 2005, 40(1):1017-1051.
[59] ZHONG Y, ZHUO Y, WANG Z, et al. Marangoni convection induced by simultaneous mass and heat transfer during evaporation of n-heptane/ether binary liquid mixture[J]. International Journal of Heat & Mass Transfer, 2017, 108:812-821.
[60] HU Y C, ZHOU Q, YE H M, et al. Peculiar surface profile of poly(ethylene oxide) film with ring-like nucleation distribution induced by marangoni flow effect[J]. Colloids & Surfaces, 2013, 428(13):39-46.
[61] HU H, LARSON R G. Analysis of the effects of marangoni stresses on the microflow in an evaporating sessile droplet[J]. Langmuir the ACS Journal of Surfaces & Colloids, 2005, 21(9):3972.
[62] ZHANF Y J, LIU Z, QIAN Y, et al. Pattern formation mechanism via evaporation of colloidal droplet containing PTFE particles and NaCl[J]. Chemical Journal of Chinese Universities, 2014, 35(6):1258-1266.
[63] 马力, 仇性启, 王健, 等. 单液滴蒸发影响因素实验研究[J]. 现代化工, 2013, 33(1):103-106.
[64] 刘松, 聂万胜, 苏凌宇, 等. 高温高压环境下煤油液滴蒸发过程实验研究[J]. 火箭推进, 2017, 43(2):25-31.
[65] KIM J H, PARK S B, KIM J H, et al. Polymer transports inside evaporating water droplets at various substrate temperatures[J]. J. Phys. Chem. C, 2011, 115(31):15375-15383.
[66] 黄镇宇, 殷科, 周志军, 等. 尿素水溶液液滴的蒸发特性[J]. 化工进展, 2014, 33(4):817-823.
[67] GAN X, YAO D, WU F, et al. Modeling and simulation of urea-water-solution droplet evaporation and thermolysis processes for SCR systems[J]. Chinese Journal of Chemical Engineering, 2016, 24(8):1065-1073.
[68] BALDWIN K A, ROEST S, FAIRHURST D J, et al. Monolith formation and ring-stain suppression in low-pressure evaporation of poly(ethylene oxide) droplets[J]. Journal of Fluid Mechanics, 2012, 695(3):321-329.
[69] TEKIN E, SMITH P J, SCHUBERT U S. Inkjet printing as a deposition and patterning tool for polymers and inorganic particles[J]. Soft Matter, 2008, 4(4):703-713.
[70] BUFFONE C, COULLOUX J, ALONSO B, et al. Capillary pressure in graphene oxide nanoporous membranes for enhanced heat transport in loop heat pipes for aeronautics[J]. Experimental Thermal & Fluid Science, 2016, 78:147-152.
[71] LIU B, BENNACER R, SEFIANE K, et al. Transient effects in evaporating sessile drops:with and without heating[J]. Journal of Heat Transfer, 2016, 138(9):14.
[72] 徐志明, 张一龙, 王景涛, 等. 两种阴离子对析晶污垢沉积的影响[J]. 化工学报, 2015, 66(6):2268-2273.
[73] NAYAK N C, SHIN K. Human serum albumin mediated self-assembly of gold nanoparticles into hollow spheres[J]. Nanotechnology, 2008, 19(26):265603.
[74] ABDOLLAHI S N, NADERI M, AMOABEDINY G. Synthesis and characterization of hollow gold nanoparticles using silica spheres as templates[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects, 2013, 436(35):1069-1075.
[75] LI X, LI Y, YANG C, et al. Liposome induced self-assembly of gold nanoparticles into hollow spheres[J]. Langmuir the ACS Journal of Surfaces & Colloids, 2004, 20(9):3734-9.
[76] EBRAHIMI A, DAK P, SALM E, et al. Nanotextured superhydrophobic electrodes enable detection of attomolar-scale DNA concentration within a droplet by non-faradaic impedance spectroscopy[J]. Lab on A Chip, 2013, 13(21):4248-56.
[77] 康垚, 王素真, 樊江莉, 等. 无机纳米药物载体在肿瘤诊疗中的研究进展[J]. 化工学报, 2018, 69(1):128-140.
[78] 胡平, 常恬, 陈震宇, 等. 纳米Fe₃O₄磁性颗粒表面改性及其在医学和环保领域的应用[J]. 化工学报, 2017, 68(7):2641-2652.
[79] STEINCHEN A, SEFIANE K, SANFELD A. Nano-encapsulation as high pressure devices for folding-unfolding proteins[J]. Journal of Colloid & Interface Science, 2011, 355(2):509-511.
[80] YAKHON T A, SEDOVA O A, SANIN A G, et al. On the existence of regular structures in liquid human blood serum (plasma) and phase transitions in the course of its drying[J]. Technical Physics, 2003, 48(4):399-403.
[81] SEFIANE K. On the formation of regular patterns from drying droplets and their potential use for bio-medical applications[J]. Journal of Bionic Engineering, 2010, 7(4):S82-S93.
[82] SHABALIN V N, SHATOKHINA S N, DUTOV V V, et al. Method of diagnosing complicated urolithiasis and prognosticating urolithiasis:EP 0504409[P]. 1996.