4,4'-二叠氮二苯乙烯-2,2-二磺酸钠的应用及发展前景

doi:10.16085/j.issn.1000-6613.2018-1140

化工进展 ›› 2019, Vol. 38 ›› Issue (04): 1804-1814.DOI: 10.16085/j.issn.1000-6613.2018-1140

4,4'-二叠氮二苯乙烯-2,2-二磺酸钠的应用及发展前景

朱佳杰¹(),刘元伟^1,²,沈江南¹(),高从堦¹

1. 浙江工业大学海洋学院膜分离与水科学技术中心，浙江杭州310014
2. 滨州学院化工与安全学院，山东滨州256600

收稿日期:2018-05-31 修回日期:2018-11-11 出版日期:2019-04-05 发布日期:2019-04-05
通讯作者: 沈江南
作者简介:<named-content content-type="corresp-name">朱佳杰</named-content>（1994—），男，硕士研究生，研究方向为膜材料及膜分离技术。E-mail：<email>zhujj@zjut.edu.cn</email>。|沈江南，教授，博士生导师，研究方向为膜材料及膜分离技术。E-mail：<email>shenjn@zjut.edu.cn</email>。
基金资助:
国家自然科学基金(C126018278);浙江省科技厅援青项目(2018C26004)

Application and developing prospect of 4,4'-diazostilbene-2,2'-disulfonic acid disodium salt

Jiajie ZHU¹(),Yuanwei LIU^1,²,Jiangnan SHEN¹(),Congjie GAO¹

1. Center for Membrane Separation and Water Science & Technology, Ocean College, Zhejiang University of Technology，Hangzhou 310014, Zhejiang, China
2. Department of Chemical Engineering and Safety, Binzhou University, Binzhou 256600, Shandong, China

Received:2018-05-31 Revised:2018-11-11 Online:2019-04-05 Published:2019-04-05
Contact: Jiangnan SHEN

摘要/Abstract

摘要：

4,4'-二叠氮二苯乙烯-2,2-二磺酸钠（DAS）是一种带有磺酸基团的芳香类双叠氮化合物。分子中的叠氮基既可在Cu(Ⅰ)催化的点击化学反应体系中与端炔基形成三唑结构，也能在紫外辐射条件下于两端生成高活性氮宾自由基并插入聚合物链段。本文简单介绍了DAS参与的点击化学反应，简述了DAS的光化学交联原理及其相较于其他化学交联剂的优点，重点论述了近些年DAS在光刻、电池隔膜、分子印迹、医用材料、药物缓释和离子交换膜等领域相关的研究应用及发展前景。此外，提出将DAS与石墨烯、金属有机框架材料（MOF）、聚电解质及脂肪族聚合物等结合应用；设计与DAS结构相似的新型叠氮类分子；深入地探究光化学反应机理；实现叠氮基团的选择性插入等是未来研究的重要趋势。

关键词: 4,4'-二叠氮二苯乙烯-2,2-二磺酸钠, 点击化学, 光化学, 稳定性, 离子交换

Abstract:

4,4'-aiazostilbene-2,2'-disulfonic acid disodium salt (DAS) is an aromatic compound with two azido and sulfonic acid groups. When reacting with terminal alkynyl via Cu(Ⅰ)-catalyzed click chemistry reaction, the azido group produces triazole. Under UV irradiation, it also generates highly active nitrene radicals, which can be easily inserted into polymer chains. In this paper, the click chemistry reaction on DAS is briefly introduced. In addition, the photochemical cross-linking mechanism of DAS and its advantages are demonstrated. The recent applications of DAS in different fields of lithography, separators of batteries, molecular imprinting, medical materials, drug release, ion exchange membranes, and etc., are introduced and its developing prospect is made. Furthermore, combining DAS with graphene, metal organic framework material (MOF), polyelectrolyte, aliphatic polymer, and etc., and designing novel azide molecules similar to DAS are suggested to extend its applications. An outlook of exploring the UV reaction mechanism and the insertion of azide groups through controlling the conditions has been proposed.

Key words: 4, 4'-diazostilbene-2, 2'-disulfonic acid disodium salt, click chemistry, photochemistry, stability, ion exchange

中图分类号:

朱佳杰, 刘元伟, 沈江南, 高从堦. 4,4'-二叠氮二苯乙烯-2,2-二磺酸钠的应用及发展前景[J]. 化工进展, 2019, 38(04): 1804-1814.

Jiajie ZHU, Yuanwei LIU, Jiangnan SHEN, Congjie GAO. Application and developing prospect of 4,4'-diazostilbene-2,2'-disulfonic acid disodium salt[J]. Chemical Industry and Engineering Progress, 2019, 38(04): 1804-1814.

图/表 11

图1 通过点击化学合成磺化聚三唑（SPTA）的路线[9]

图2 制备端基交联的聚（亚苯基硫醚腈）类质子交换膜[16]

图3 基于层层组装在Si（100）衬底上的通过CuAAC反应形成分子多层薄膜的的示意图[43,44,45]

图4 基于PVP的半互穿聚合物网络在钒氧化还原液流电池中的应用[53]

图5 退火的PFSA/PVP-DAS（92/8/0.8）纳米纤维膜在水中浸泡20天前和在水中浸泡20天后的扫描电镜图[54]

图6 图案化表面的AFM表征[55]

图7 采用后渗透光化学交联策略构建的层层分子印迹纳米结构图[60]

图8 LbL技术与光化学结合制备基于GO的自支撑膜的过程图[64]

图9 通过LbL工艺制备ZnAl-LDH的过程图[66]

图10 后渗透与光交联结合的表面层改性阴离子交换膜示意图[72]

图11 利用带电荷叠氮分子设计制备脂肪族离子交换膜

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4,4'-二叠氮二苯乙烯-2,2-二磺酸钠的应用及发展前景

Application and developing prospect of 4,4'-diazostilbene-2,2'-disulfonic acid disodium salt

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