活化过硫酸盐氧化法修复有机污染土壤的研究进展

doi:10.16085/j.issn.1000-6613.2018-0719

摘要/Abstract

摘要： 过硫酸盐在不同活化因子的作用下可产生具有强氧化性的硫酸根自由基（SO₄^-·），能氧化分解众多的有机化合物，同时因其具有的氧化能力强、反应速度快及应用范围广等特点，近年来在环境污染治理领域备受关注。本文在对活化过硫酸盐氧化机理分析的基础上，综述了国内外利用过渡金属离子、氧化剂、热、强碱及联合活化等多种方式活化过硫酸盐修复有机物污染土壤的研究现状，并对活化过硫酸盐修复污染土壤的影响因素如氧化剂的添加量及添加方式、初始pH和反应时间进行了综述。此外，对活化过硫酸盐氧化法与电动修复、微生物修复、表面活性剂洗脱、固化稳定化等技术在土壤修复中的联合应用同样进行了的阐述。最后提出了活化过硫酸盐应用于土壤修复领域存在的问题，并对今后的研究方向进行了展望。

关键词: 过硫酸盐, 氧化, 活化, 自由基, 修复, 有机污染物

Abstract: As one of the most promising methods in chemical oxidation, activated persulfate oxidation has a fabulous prospect in environmental pollution control due to its characteristics of strong oxidizing ability, fast reaction speed and wide application range. It can be activated by initiators to form sulfate radical, which can degrade many organic contaminations and has a significant effect on the remediation of organic contaminated soil. This paper reviewed the mechanism of persulfate oxidation, and provided an overview on the research progress of the activation methods of persulfate oxidation for the remediation of organic contaminated soil under different conditions including transition metal ions, oxidants, thermal activation and alkali activation. It also reviewed the influencing factors of activated persulfate oxidation such as persulfate concentration, pH, reaction time and adding method of persulfate. Moreover, the application of activated persulfate oxidation combined with other technologies in soil remediation was expounded. Finally, the existing limit and prospects of activated persulfate oxidation technology for soil remediation were prospected.

Key words: persulfate, oxidation, activation, free radicals, remediation, organic contaminants

中图分类号:

肖鹏飞, 姜思佳. 活化过硫酸盐氧化法修复有机污染土壤的研究进展[J]. 化工进展, 2018, 37(12): 4862-4873.

XIAO Pengfei, JIANG Sijia. Research progress in remediation of organic contaminated soil by activated persulfate oxidation[J]. Chemical Industry and Engineering Progress, 2018, 37(12): 4862-4873.

参考文献

[1] WATTS R J, AHMAD M, HOHNER A K, et al. Persulfate activation by glucose for in situ chemical oxidation[J]. Water Reseach, 2018, 133:247-254.
[2] BESHA A T, BEKELE D N, NAIDU R, et al. Recent advances in surfactant-enhance in-situ chemical oxidation for the remediation of non-aqueous phase liquid contaminated soils and aquifers[J]. Environmental Technology & Innovation, 2018, 9:303-322.
[3] LEMAIRE J, BUES M, KABECHE T, et al. Oxidant selection to treat an aged PAH contaminated soil by in situ chemical oxidation[J]. Journal of Environmental Chemical Engineering, 2013, 1:1261-1268.
[4] FUMAN O S, TEEL A L, WATTS R J. Mechanism of base activation of persulfate[J]. Environmental Science & Technology, 2010, 44:6423-6428.
[5] SIEGRIST R L, URYNOWICZ M A, WEST O R, et al. Principles and practices of in situ chemical oxidation using permanganate[M]. Columbus, OH:Battelle Press, 2001:505.
[6] 刘红梅, 褚华强, 陈家斌, 等. 过硫酸盐在地下水和土壤修复中的应用[J]. 现代化工, 2015, 35(4):42-46. LIU H M, CHU H Q, CHEN J B, et al. Application of persulfate in remediating groundwater and soil[J]. Modern Chemical Industry, 2015, 35(4):42-46.
[7] 吴丽颖, 王炳煌, 张圆春, 等. 凝胶球负载零价铁活化过硫酸盐降解偶氮染料废水[J]. 化工进展, 2017, 36(6):2318-2324. WU L Y, WANG B H, ZHANG Y C, et al. Degradation of Reactive Black 5(RBK5) by gelatin balls loading iron activating sodium persulfate[J]. Chemical industry and Engineering Progress, 2017, 36(6):2318-2324.
[8] LIANG C, CHIEN Y C, LIN Y L. Impacts of ISCO persulfate, peroxide and permanganate oxidants on soils:soil oxidant demand and soil properties[J]. Soil and Sediment Contamination:an International Journal, 2012, 21(6):701-719.
[9] PETRI B. In situ chemical oxidation of contaminated soil and groundwater using persulfate:a review[J]. Critical Reviews in Environmental Science and Technology, 2010, 40:55-91.
[10] HORI H, YAMAMOTO A, HAYAKAWA E, et al. Efficient decomposition of environmentally persistent perfluorocarboxylic acids by use of persulfate as a photochemical oxidant[J]. Environ. Sci. Technol., 2005, 39(7):2383-2388.
[11] NETA P, MADHAVAN V, ZEMEL H, et al. Rate constants and mechanism of reaction of SO₄^-• with aromatic compounds[J]. Am. Chem. Soc., 1977, 99(1):163-164.
[12] TORALF B, WOLFGANG B, ROLF M. Investigations of eactions of selected azaarenes with radicals in water[J]. J. Phys. Chem. A, 1998, 102(34):6760-6765.
[13] KHUSAN S L, SEMESKO. Quantum-chemical modeling of the detachment of hydrogen atoms by the sulfate radical anion[J]. Russian Journal of Physical Chemistry, 2006, 80:366-371.
[14] ANIPISITAKIS G P, DIONYIOU D D. Degradation of organic contaminants in water with sulfate radicals generated by the conjunction of peroxymonosulfate with cobalt[J]. Environmental Science and Technology, 2003, 37:4790-4797.
[15] PADMAJA S Z B, NETA P, HUIE R E. Rate constants for reactions of SO₄^-• radicals in acetonitrile[J]. International Journal of Chemical Kinetics, 1993, 25:193-198.
[16] GAYATHRI P, DORATHI R P J, PALANIYELU K. Sonochemical degradation of textile dyes in aqueous solution using sulphate radicals activated by immobilized cobalt ions[J]. Ultrasonics Sonochemistry, 2010(3):566-571.
[17] 魏海江, 杨兴伦, 叶茂, 等. 活化过硫酸钠氧化法修复DDTs污染场地土壤研究[J]. 土壤, 2014, 46(3):504-511. WEI H J, YANG X L, YE M, et al. Application of activated persulfate oxidation method in degradating DDT in field contaminated soil[J]. Soils, 2014, 46(3):504-511.
[18] 王春艳, 李晓亮, 董芬, 等. 化学氧化修复PAHs污染土壤的性质及毒性变化[J]. 北京化工大学学报(自然科学版), 2012, 39(4):95-100. WANG C Y, LI X L, DONG F, et al. Changes in polyaromatic hydrocarbons contaminated soil properties and phytotoxicity under chemical oxidation[J]. Journal of Beijing University of Chemical Technology (Natural Science), 2012, 39(4):95-100.
[19] 赵丹, 廖晓勇, 阎秀兰, 等. 不同化学氧化剂对焦化污染场地多环芳烃的修复效果[J]. 环境科学, 2011, 32(3):857-863. ZHAO D, LIAO X Y, YAN X L, et al. Chemical oxidants for remediation of soils contaminated with polycyclic aromatic hydrocarbons at a coking site[J]. Environmental Science, 2011, 32(3):857-863.
[20] 孙崇凤, 朱宇恩, 李海龙, 等. 苯胺在土壤中的自然降解作用及化学氧化修复技术研究[J]. 山西大学学报(自然科学版), 2015, 38(1):165-172. SUN C F, ZHU Y E, LI H L, et al. Natural degradation and chemical oxidation remediation of aniline in soil[J]. Journal of Shanxi University(Nat. Sci. Ed.), 2015, 38(1):165-172.
[21] 黎舒雯, 陆敏, 刘敏, 等. 化学氧化剂对多环芳烃污染土壤的修复效果研究[J]. 山东农业大学学报(自然科学版), 2016, 47(3):378-382. LI S W, LU M, LIU M, et al. The remedial effect of oxidants on soils contaminated by polycyclic aromatic hydrocarbons[J]. Journal of Shandong Agricultural University (Natural Science Edition), 2016, 47(3):378-382.
[22] 张宏玲, 李森, 张杨, 等. 过渡金属离子活化过硫酸盐去除土壤中的芘[J]. 环境工程学报, 2016, 10(10):6009-6014. ZHANG L L, LI S, ZHAGN Y, et al. Removal of pyrene in contaminated soil by transition metal ions activated persulfate[J]. Chinese Journal of Environmental Engineering, 2016, 10(10):6009-6014.
[23] 高金龙, 马玉琳, 孟庆来, 等. 二价铁活化过硫酸盐降解土壤中十溴联苯醚[J]. 环境工程学报, 2016, 10(12):7339-7343. GAO J L, MA Y L, MENG Q L, et al. Degradation of decabromodiphenyl ether in soil by sulfate activated with ferrous ions[J]. Chinese Journal of Environmental Engineering, 2016, 10(12):7339-7343.
[24] RASTOGI A, Al-ABED S R, DIONYSIOU D D. Sulfate radicalbased ferrous-peroxymonosulfate oxidative system for PCBs degradation in aqueous and sediment systems[J]. Applied Catalysis B:Environmental, 2009, 85:171-179.
[25] LIANG C, BRUELL C J, MARLEY M C, et al. Persulfate oxidation for in situ remediation of TCE. Ⅱ. Activated by chelated ferrous ion[J]. Chemosphere, 2004, 55(9):1225-1233.
[26] 刘晓文, 李荣飞, 李霞, 等. 过硫酸钠原位修复三氯乙烯污染土壤的模拟研究[J]. 环境科学学报, 2013, 33(11):2935-2940. LIU X W, LI R F, LI X, et al. A model of in situ remediation of TCE-contaminated soil by sodium persulfate[J]. Acta Scientiae Circumstantiae, 2013, 33(11):2935-3940.
[27] 刘佳露, 卢伟, 张凤君, 等. 活化过硫酸盐氧化地下水中苯酚的动力学研究[J]. 中国环境科学, 2015, 35(9):2677-2681. LIU J L, LU W, ZHANG F J, et al. Kinetics study of activated persulfate oxidation of phenol in ground water[J]. China Environmental Science, 2015, 35(9):2677-2681.
[28] NADIM F, HUANG K C, DAHMANI A M. Remediation of soil and ground water contaminated with PAH using heat and Fe(Ⅱ)-EDTA catalyzed persulfate oxidation[J]. Water, Air, & Soil Pollution Focus, 2006, 6:227-232.
[29] FERRARESE E, ANDREOTTOLA G, OPREA I A. Remediation of PAH-contaminated sediments by chemical oxidation[J]. Journal of Hazardous Materials, 2008, 152:128-139.
[30] 陈垚, 张凤娥, 董良飞. 活化过硫酸钠氧化修复有机氯农药污染土壤[J]. 环境工程学报, 2017, 11(10):5715-5721. CHEN Y, ZHANG F E, DONG L F. Remediation of organochlorine pesticides-contaminated soils by activatal persulfate[J]. Chinese Journal of Environmental Engineering, 2017, 11(10):5715-5721.
[31] 蔡信德, 吴嘉怡, 杜文婷, 等. 过硫酸钠对砂壤土中三氯乙烯的氧化研究[J]. 中国环境科学, 2012, 32(7):1263-1267. CAI X D, WU J Y, DU W T, et al. Removal efficiency of trichloroethylene from the contaminated sandy loam soil using sodium persulfate[J]. China Environmental Science, 2012, 32(7):1263-1267.
[32] KILLIAN P F, BRUELL C J, LIANG C, et al. Iron (Ⅱ) activated persulfate oxidation of MGP contaminated soil[J]. Soil Sediment Contam, 2007, 16(6):523-537.
[33] DRZEWICZ P, PEREZ E L, ALPATOVAl A, et al. Impact of peroxydisulfate in the presence of zero valent iron on the oxidation of cyclohexanoic acid and naphthenic acids from oil sands process-affected water[J]. Environmental Science & Technology, 2012, 46:8984-8991.
[34] MOHAMMED M, THOMSON N. Treatment of organic compounds by activated persulfate using nanoscale zerovalent iron[J]. Industrial & Engineering Chemistry Research, 2013, 52:13564-13571.
[35] 文勤亮, 张瀚文, 许海波, 等. 零价铁还原-过硫酸盐氧化联合降解土壤中对硝基氯苯的研究[J]. 南京农业大学学报, 2014, 37(6):111-118. WEN Q L, ZHANG H W, XU H B, et al. Degradation of p-nitrochlorobenzene in soil by zero-valent iron activated persulfate[J]. Journal of Nanjing Agricultural University, 2016, 37(6):111-118.
[36] PARDO F, ROSAS J M, SANTOS A, et al. Remediation of a biodiesel blend-contaminated soil with activated persulfate by different sources of iron[J]. Water, Air & Soil Pollution, 2015, 226(2):1-12.
[37] 吴非, 陈谷汎, 林伟翰, 等. 包覆型纳米零价铁活化过硫酸处理柴油污染土壤[J]. 环境科学学报, 2016, 36(7):2589-2595. WU F, CHEN G F, LIN W H, et al. Remediation of diesel-contaminated soil using coated nano zero valent iron/sodium peroxydisulfate system[J]. Acta Scientiae Circumstantiae, 2016, 36(7):2589-2595.
[38] 吴文慧, 朱长银, 施维林, 等. 微纳铁活化过硫酸钠降解污染土壤中DDTs的效果研究[J]. 土壤, 2017, 49(3):460-466. WU W H, ZHU C Y, SHI W L, et al. Efficient degradation of DDTs by persulfate activated with micro/nano-Fe⁰ particles in soil[J]. Soils, 2017, 49(3):460-466.
[39] BLOCK P A, BROWN R A, ROBINSON D. Novel activation technologies for sodium persulfate in situ chemical oxidation[C]//Proceedings of the Fourth International Conference on the Remediation of Chlorinated and Recalcitrant Compounds, Monterey, 2004.
[40] GOI A, TRAPIDO M. Chlorophenols contaminated soil remediation by peroxidation[J]. J. Adv. Oxid. Technol., 2010, 13:50-58.
[41] CRIMI M L, TAYLOR J. Experimental evaluation of catalyzed hydrogen peroxide and sodium persulfate for destruction of BTEX contaminants[J]. Soil & Sediment Contamination, 2007, 16(1):29-45.
[42] 施维林, 沈秋悦, 王儒, 等. 不同化学氧化剂对多环芳烃污染土壤修复效果研究[J]. 苏州科技大学学报(自然科学版), 2017, 34(1):61-66. SHI W L, SHEN Q Y, WANG R, et al. Remediation effects of different oxidants on soil contaminated by polycyclic aromatic hydrocarbons[J]. Journal of Suzhou Universiry of Science and Technology(Natural Science), 2017, 34(1):61-66.
[43] 吴昊, 孙丽娜, 李玉双, 等. 活化过硫酸钠去除长期污染土壤中的TPH[J]. 环境工程学报, 2016, 10(9):5231-5237. WU H, SUN L N, LI Y S, et al. Application of persulfate to remediatiate long-term TPH contaminated soils[J]. Chinese Journal of Environmental Engineering, 2016, 10(9):5231-5237.
[44] 占升, 郑义, 李森, 等. 不同氧化剂活化过硫酸钠对土壤中多环芳烃降解的影响[J]. 浙江农业学报, 2017, 29(1):129-136. ZHAN S, ZHENG Y, LI S, et al. Degradation of PAHs in soil by different oxidants activated sodium persulfate[J]. Acta Agriculturae Zhejiangensis, 2017, 29(1):129-136.
[45] 吴昊, 孙丽娜, 王辉, 等. CaO₂/Fe²⁺活化过硫酸钠对石油类污染土壤的修复效果[J]. 环境化学, 2016, 35(4):623-628. WU Hao, SUN Lina, WANG Hui, et al. Remediation of petroleum hydrocarbon-contaminated soils by CaO₂/Fe²⁺ activatal persulfate[J]. Environmental Chemistry, 2016, 35(4):623-628.
[46] OLHA S F, AMY L T, WATTS R J. Mechanism of base activation of persulfate[J]. Environ. Sci. Technol., 2010, 44(16):6423-6428.
[47] HUANG K C, ZHAO Z, HONG G E, et al. Degradation of volatile organic compounds with thermally activated persulfate oxidation[J]. Chemosphere, 2005, 61(4):551-560.
[48] 樊广萍, 仓龙, 刘德宏, 等. 电动强化过硫酸钠修复多氯联苯污染土壤的研究[J]. 农业环境科学学报, 2015, 34(5):859-865. FAN G P, CANG L, LIU D H, et al. Electrokinetically enhanced persulfate remediation of PCBs polluted soil[J]. Journal of Agro-Environment Science, 2015, 34(5):859-865.
[49] TAN C, GAO N, DENG Y, et al. Heat-activated persulfate oxidation of diuron in water[J]. Chemical Engineering Journal, 2012, 203(5):294-300.
[50] YUKSELEN A Y, REDDY K R. Effect of soil composition on electrokinetically enhanced persulfate oxidation of polychlorobiphenyls[J]. Electrochimica Acta, 2012, 86:164-169.
[51] 顾小钢, 吕树光, 邱兆富, 等. 热活化过硫酸钠处理水溶液及泥浆系统中1,1,1-三氯乙烷的研究[J]. 环境科学学报, 2012, 32(6):1374-1380. GU X G, LÜ S G, QIU Z F, et al. Oxidation of 1,1,1-trichloroethane in aqueous and slurry systems by thermally activated persulfate[J]. Acta Scientiae Circumstantiae, 2012, 32(6):1374-1380.
[52] 李永涛, 罗进, 岳东. 热活化过硫酸盐氧化修复柴油污染土壤[J]. 环境污染与防治, 2017, 39(10):1143-1146. LI Y T, LUO J, YUE D. Thermo activated persulfate oxidation for remediation of diesel oil contaminated soil[J]. Environmental Pollution and Control, 2017, 39(10):1143-1146.
[53] 葛斐, 刘国强, 舒茂, 等. 利用热活化过硫酸钠降解土壤中硝基苯的研究[J]. 环境工程, 2017, 35(s2):461-464. GE F, LIU G Q, SHU M, et al. Degradation of nitrobenzene in soil with heat-activated sodium persulfate system[J]. Environmental Engineering, 2017, 35(s2):461-464.
[54] 徐开泰, 林匡飞, 陆强, 等. 热活化过硫酸钠降解土壤体系中的菲[J]. 环境工程, 2018, 36(1):188-194. XU K T, LIN K F, LU Q, et al. Degradation of phenanthrene in soil via thermally activated sodium persulfate[J]. Environmental Engineering, 2018, 36(1):188-194.
[55] 周颖, 谢海燕, 赵晨曦, 等. 活化过硫酸盐处置石油污染土壤技术研究[J]. 新疆环境保护, 2016, 38(2):12-17. ZHOU Y, XIE H Y, ZHAO C X, et al. Study on the technology of petroleum contaminated soil treatment with activated sulfate[J]. Environmental Protection of Xinjiang, 2016, 38(2):12-17.
[56] 龙安华, 雷洋, 张晖. 活化过硫酸盐原位化学氧化修复有机污染土壤和地下水[J]. 化学进展, 2014, 26(5):898-908. LONG A H, LEI Y, ZHANG H. In situ chemical oxidation of organic contaminated soil and groundwater using activated persulfate process[J]. Progress in Chemistry, 2014, 26(5):898-908.
[57] 陈垚, 董良飞, 张凤娥. 超声波-热联合活化过硫酸盐氧化修复有机氯农药污染土壤[J]. 常州大学学报(自然科学版), 2017, 29(1):35-40. CHEN Y, DONG L F, ZHANG F E. Degradation of organochlorine pesticides by ultrasonic-thermally co-activated persulfate in soil system[J]. Journal of Changzhou Unicersity(Natural Science Edition), 2017, 29(1):35-40.
[58] 朱杰, 罗启仕, 郭琳, 等. 碱热活化过硫酸盐氧化水中氯苯的试验[J]. 环境化学, 2013, 32(12):2256-2262. ZHU J, LUO Q S, GUO L, et al. Remediation of chlorobenzene-contaminated waste water using a combination of thermal-and alkaline-activated persulfate[J]. Environmental Chemistry, 2013, 32(12):2256-2262.
[59] 李社锋, 王文坦, 邵雁, 等. 活化过硫酸盐高级氧化技术的研究进展及工程应用[J]. 环境工程, 2016, 34(9):171-174. LI S F, WANG W T, SHAO Y, et al. Progress in advanced oxidation technology of activated persulfate and its engineering application[J]. Environmental Engineering, 2016, 34(9):171-174.
[60] 吴玉婷, 马福俊, 谷庆宝, 等. 过硫酸钾氧化去除水和土壤中的苯胺[J]. 环境工程技术学报, 2015, 5(4):259-264. WU Y T, MA F J, GU Q B, et al. Aniline degradation in water and soils by potassium persulfate[J]. Journal of Environmental Engineering Technology, 2015, 5(4):259-264.
[61] 陈辉, 肖杰, 万正茂, 等. Fe²⁺活化过硫酸盐氧化降解水和泥浆中PAHs(芘)的研究[J]. 工业安全与环保, 2017, 43(2):1-4, 10. CHEN H, XIAO J, WAN Z M, et al. Study on degradation of PAHs(pyrene) in the water and mud by persulfate activated with Fe²⁺[J]. Industrial Safety and Environmental Protection, 2017, 43(2):1-4, 10.
[62] 邸莎, 张超艳, 颜增光, 等. 过硫酸钠对我国典型土壤中多环芳烃氧化降解效果的影响[J]. 环境科学研究, 2018, 31(1):95-101. DI S, ZHANG C Y, YAN Z G, et al. Oxidative degradation effect of sodium persulfate on polycyclic aromatic hydrocarbons in typical Chinese soils[J]. Research of Environmental Sciences, 2018, 31(1):95-101.
[63] ISOSAARI P, PISKONENI R, OJALA P, et al. Integration of electrokinetics and chemical oxidation for the remediation of creosote-contaminated clay[J]. Journal of Hazardous Materials, 2007, 144(1):538-548.
[64] YANG G C, YEH C F. Enhanced nano-Fe₃O₄/S₂O₈^2- oxidation of trichloroethylene in a clayey soil by electrokinetics[J]. Separation and Purification Technology, 2011, 79(2):264-271.
[65] CANG L, FAN G P, ZHOU D M, et al. Enhanced-electrokinetic remediation of copper-pyrene co-contaminated soil with different oxidants and pH control[J]. Chemosphere, 2013, 90(8):2326-2331.
[66] 宋萌萌, 罗泽娇, 秦佳. 电动力学-过硫酸钠氧化联用修复二氯苯污染土壤的研究[J]. 环境工程, 2016, 34(7):176-180. SONG M M, LUO Z J, QIN J. Study on electrokinetics combined with persulfate oxidation for remediation of dichlorobenzene contaminated soil[J]. Environmental Engineering, 2016, 34(7):176-180.
[67] 肖鹏飞, 宋玉珍, 王剑桥. 表面活性剂对东北黑土中苯并[a]芘的增溶洗脱作用. 土壤通报, 2014, 45(3):743-748. XIAO P F, SONG Y Z, WANG J Q. The solubilization and elution of benzo[a]yrene from black soils of Northeast China by surfactants[J]. Chinese Journal of Soil Science, 2014, 45(3):743-748.
[68] 肖鹏飞, 孙丽军. Tween60对黑龙江黑土中有机氯农药的洗脱及影响因素[J]. 土壤通报, 2016, 47(4):980-985. XIAO P F, SUN L J. Elution of chlorinated cyclodiene pesticides from black soils in Heilongjiang province by Tween60 and its effect factors[J]. Chinese Journal of Soil Science, 2016, 47(4):980-985.
[69] 罗怡雯, 金泽鑫, 石晓童, 等. 芘污染黑土的表面活性剂洗脱修复研究[J]. 环境科学与技术, 2016, 39(6):39-44. LUO Y W, JIN Z X, SHI X T, et al. Remediation of pyrene contaminated black soil by surfactants eluting method[J]. Environmental Science and Technology, 2016, 39(6):39-44.
[70] GOI A, VⅡSIMAA M, KARPENKO O. DDT-contaminated soil treatment with persulfate and hydrogen peroxide utilizing different activation aids and the chemicals combination with biosurfactant[J]. Journal of Advanced Oxidation Technologies, 2012, 15(1):41-52.
[71] 朱长银, 方国东, 司友斌, 等. 洗脱-过硫酸钠氧化联合去除土壤中PCBs的研究[J]. 土壤, 2015, 47(6):1125-1131. ZHU C Y, FANG G D, SI Y B, et al. Combination of elution and persulfateoxidation for the removal of PCBs from soils[J]. Soils, 2015, 47(6):1125-1131.
[72] 吉红军, 龙涛, 陈墙, 等. Tween80强化-活化过硫酸钠氧化修复多环芳烃污染土壤[J]. 化工学报, 2016, 67(9):3879-3887. JI H J, LONG T, CHEN Q, et al. Tween80 enhanced-activated sodium persulfate oxidation of PAHs contaminated soil[J]. CIESC Journal, 2016, 67(9):3879-3887.
[73] HRAPOVIC L, SLEEP B E, MAJOR D J, et al. Laboratory study of treatment of trichloroethene by chemical oxidation followed by bioremediation[J]. Environ. Sci. Technol., 2005, 39:2888-2897.
[74] SAHL J W, MUNAKATA M J, CRIMI M L, et al. Coupling permanganate oxidation with microbial dechlorination of tetrachloroethene[J]. Water Environ. Res., 2007, 79:5-12.
[75] STOCKINGER H, HEINZLE E, KUT O M. Removal of chloro and nitro aromatic wastewater pollutants by ozonation and biotreatment[J]. Environ. Sci. Technol., 1995(29):2016-2022.
[76] 张晓慧, 葛芳州, 董玉婧, 等. 过硫酸盐强化微生物处理石油污染土壤的研究[J]. 应用化工, 2015, 44(10):1811-1815. ZHANG X H, GE F Z, DONG Y J, et al. Study on application of persulfate to enhance microbiological remediation for petroleum contaminated soil[J]. Applied Chemical Industry, 2015, 44(10):1811-1815.
[77] SORA I, PELOSATO R, BOTTA D, et al. Chemistry and microstructure of cement pastes admixed with organic liquids[J]. Journal of the European Ceramic Society, 2002, 22(9/10):1463-1473.
[78] RHO H, ARAFAT H, KOUNTZ B, et al. Decomposition of hazardous organic materials in the solidification/stabilization process using catalytic-activated carbon[J]. Waste Management, 2001, 21(4):343-356.
[79] 马福俊, 李方, 张倩, 等. 过硫酸盐氧化与水泥固化稳定化协同修复苯胺污染土壤[J]. 环境科学研究, 2016, 29(5):731-736. MA F J, LI F, ZHANG Q, et al. Oxidation of aniline in cement-based solidified/stabilized contaminated soil using persulfate[J]. Researtch Environmental Sciences, 2016, 29(5):731-736.
[80] LIANG C J, HUANG C F, CHEN Y J. Potential for activated persulfate degradation of BTEX contamination[J]. Water Research, 2008, 42:4091-4100.
[81] 曾嘉强, 文勤亮, 吴文成, 等. 零价铁和氧化剂复合添加对土壤中硝基氯苯降解的影响研究[J]. 黑龙江大学自然科学学报, 2015, 32(5):667-672. ZENG J Q, WEN Q L, WU W C, et al. Degradation of nitrochlorobenzenes in soil by Fe(0) combined with oxidants[J]. Journal of Natural Science of Heilongjiang University, 2015, 32(5):667-672.