膦酸类金属-有机骨架材料对CO2的吸附性能研究进展

doi:10.16085/j.issn.1000-6613.2017.05.028

摘要/Abstract

摘要： 膦酸类金属-有机骨架（MOFs）材料作为众多MOFs材料家族中的一类，近年来受到了研究者的广泛关注。本文综述了膦酸类MOFs材料的发展过程及其对二氧化碳（CO₂）的吸附性能，并阐明了吸附过程机理，总结了结晶度、有效比表面积、孔隙率和水稳定性等因素对膦酸类MOFs材料CO₂吸附性能的影响。概述了含有N，N'-二（亚甲基膦酸）-哌嗪及其衍生物、膦酸单酯（PMEs）配体的新兴膦酸类MOFs材料的性质和特点，总结了哌嗪环、烷基基团、烷氧基及杂元素（硫、氟）对提高膦酸类MOFs材料CO₂吸附性能的研究概况。分析了甲基、乙基、烷氧基等对膦酸类MOFs材料孔道结构的调控机制。指出了较低的比表面积和孔隙率仍然是制约膦酸类MOFs材料CO₂吸附性能的重要因素，而开发核壳结构的MOFs材料可能是一种有效的解决途径。

关键词: 金属-有机骨架, 膦酸类金属-有机骨架, 二氧化碳, 吸附

Abstract: Phosphonate metal-organic framework (MOFs),one kind of the MOFs materials,has attracted much attention in recent years. In this work,the progress of phosphonate MOFs and its application in CO₂ adsorption were reviewed. Moreover,the adsorption mechanism was expounded. The effects of crystallinity,effective specific surface area,porosity and water stability on the CO₂ adsorption performance of phosphonate MOFs were discussed. In addition,the properties and characterization of new phosphonate MOFs containing N,N'-piperazinebis (methylenephosphonic acid) and its derivatives,phosphonate monoesters (PMEs) linkers were also reviewed. The effect of properties of piperazine ring,alkyl group,alkoxy group and hetero element (sulfur and fluorine) on CO₂ adsorption performance of the phosphonate MOFs was summarized. The adjusting mechanism of the methyl,ethyl and alkoxy group on the pore structure of phosphonate MOFs were analyzed. However,the low specific surface area and porosity are still important restriction factors for the CO₂ adsorption performance of phosphonate MOFs,while the core-shell structure of the MOFs material may give an effective solution.

Key words: MOFs, phosphonate metal-organic frameworks, carbon dioxide, adsorption

中图分类号:

O799
X-1

牛照栋, 关清卿, 陈秋玲, 宁平, 谷俊杰. 膦酸类金属-有机骨架材料对CO₂的吸附性能研究进展[J]. 化工进展, 2017, 36(05): 1782-1790.

NIU Zhaodong, GUAN Qingqing, CHEN Qiuling, NING Ping, GU Junjie. Progress of application for CO₂adsorption with phosphonate metal-organic frameworks[J]. Chemical Industry and Engineering Progress, 2017, 36(05): 1782-1790.

参考文献

[1] SUMIDA K,ROGOW D L,MASON J A,et al. Carbon dioxide capture in metal-organic frameworks[J]. Chemical Reviews,2012,12(2):724-81.
[2] 李立博,王勇,王小青,等. 柔性金属有机骨架材料(MOFs)用于气体吸附分离[J]. 化工进展,2016,35(6):1794-1803. LI L B,WANG Y,WANG X Q,et al. Selective gas adsorption and separation in flexible metal-organic frameworks[J]. Chemical Industry and Engineering Progress,2016,35(6):1794-1803.
[3] FURUKAWA H,CORDOVA K E,O' KEEFFE M,et al. The chemistry and applications of metal-organic frameworks[J]. Science,2013,341(6149):1230444-1230444.
[4] ZHAO Z,LI Z,LIN Y S. Adsorption and diffusion of carbon dioxide on metal-organic framework (MOF-5)[J]. Industrial & Engineering Chemistry Research,2009,48(22):10015-10020.
[5] BOTAS J A,CALLEJA G,SANCHEZSANCHEZ M,et al. Cobalt doping of the MOF-5 framework and its effect on gas-adsorption properties[J]. Langmuir the Acs Journal of Surfaces & Colloids,2010,26(8):5300-5303.
[6] 朱晨明,王保登,张中正,等. 金属-有机骨架复合材料的制备及其二氧化碳吸附性能[J]. 化工进展,2016,35(9):2875-2884. ZHU C M,WANG B D,ZHANG Z Z,et al. Preparation and CO₂adsorption performance of metal-organic framework composites[J]. Chemical Industry and Engineering Progress,2016,35(9):2875-2884.
[7] ZHANG Y B,FURUKAWA H,KO N,et al. Introduction of functionality,selection of topology,and enhancement of gas adsorption in multivariate metal-organic framework-177[J]. Journal of the American Chemical Society,2015,137(7):2641-2650.
[8] PARK H J,SUH M P. Mixed-ligand metal-organic frameworks with large pores:gas sorption properties and single-crystal-to-single- crystal transformation on guest exchange[J]. Chemistry,2008,14(29):8812-8821.
[9] 王天龙,张燕,王新红,等. 类沸石咪唑酯骨架材料(ZIFs)的研究进展[J]. 化工进展,2015,34(11):3959-3964. WANG T L,ZHANG Y,WANG X H,et al. Research progress in zeoliticimidazolate frameworks(ZIFs)[J]. Chemical Industry and Engineering Progress,2015,34(11):3959-3964.
[10] MORRIS W,LEUNG B,FURUKAWA H,et al. A combined experimental-computational investigation of carbon dioxide capture in a series of isoreticular zeolitic imidazolate frameworks[J]. Journal of the American Chemical Society,2010,132(32):11006-11008.
[11] COLOMBO V,GALLI S,CHOI H J,et al. High thermal and chemical stability in pyrazolate-bridged metal-organic frameworks with exposed metal sites[J]. Chemical Science,2011,2(7):1311-1319.
[12] CLEARFIELD A,DEMADIS K D. Metal phosphonate chemistry: from synthesis to applications[M]. London:Royal Society of Chemistry,2011.
[13] ROWSELL J L C,MILLWARD A R,PARK K S,et al. Hydrogen sorption in functionalized metal-organic frameworks[J]. Journal of the American Chemical Society,2004,126(18): 5666-5667.
[14] FEREY G,MELLOT-DRAZNIEKS C,SERRE C,et al. A chromium terephthalate-based solid with unusually large pore volumes and surface area[J]. Science,2005,309(5743):2040-2042.
[15] REN J,ROGERS D E C,SEGAKWENG T,et al. Thermal treatment induced transition from Zn₃(OH)₂(BDC)₂(MOF-69c) to Zn₄O(BDC)₃(MOF-5)[J]. International Journal of Materials Research,2014,105(1):89-93.
[16] BIDEAU J L,PAYEN C,PALVADEAU P,et al. Preparation,structure,and magnetic properties of copper(Ⅱ) phosphonates. beta.-cull(CH₃PO₃),an original three-dimensional structure with a channel-type arrangement[J]. Inorganic Chemistry,2002,33(22). DOI:10.1021/ic00100a011.
[17] MAEDA K,KIYOZUMI Y,MIZUKAMI F. Synthesis of the first microporous aluminum phosphonate with organic groups covalently bonded to the skeleton[J]. Angewandte Chemie International Edition,1994,33(22):2335-2337.
[18] MAEDA K,AKIMOTO J,KIYOZUMI Y,et al. AlMepO-α:a novel open-framework aluminum methylphosphonate with organo-lined unidimensional channels[J]. Angewandte Chemie International Edition in English,1995,34(11):1199-1201.
[19] MAEDA K,AKIMOTO J,KIYOZUMI Y,et al. Structure of aluminium methylphosphonate,AIMepO-β,with unidimensional channels formed from ladder-like organic-inorganic polymer chains[J]. Journal of the Chemical Society Chemical Communications,1995,10(10):1033-1034.
[20] HERDES C,VALENTE A,LIN Z,et al. Selective adsorption of volatile organic compounds in micropore aluminum methylphosphonate-alpha:a combined molecular simulation-experimental approach[J]. Langmuir,2007,23(13):7299-305.
[21] POOJARY D M,GROHOL D,CLEARFIELD A. Synthesis and X-ray powder structure of a novel porous uranyl phenylphosphonate containing unidimensional channels flanked by hydrophobic regions[J]. Angewandte Chemie International Edition,1995,34(1314):1508-1510.
[22] POOJARY D M,ZHANG B,CABEZA A,et al. Synthesis and crystal structures of two metal phosphonates,M(HO₃PC₆H₅)₂(M=Ba,Pb)[J]. Journal of Materials Chemistry,1996,6(4):639-644.
[23] YOON M,MOON D. New Zr (IV) based metal-organic framework comprising a sulfur-containing ligand:enhancement of CO₂ and H₂ storage capacity[J]. Microporous and Mesoporous Materials,2015,215:116-122.
[24] SOGHOMONIAN V,CHEN Q,HAUSHALTER R C,et al. Hydrothermal syntheses and structural characterization of layered oxovanadium phosphate solids incorporating organic cations:[H₂N(C₄H₈)NH₂][(VO)₄(OH)₄(PO₄)₂],[(NH₃C₃H₆)NH(C₂H₄)₂NH (C₃H₆NH₃)][(VO)₅(OH)₂(PO₄)₄].cntdot. 2H₂O,[HN(C₂H₄)₃NH]₂[(VO)₈(HPO₄)₃(PO₄)₄][J]. Inorganic Chemistry,1995,34(13). DOI:10.1021/ic00117a021.
[25] LADUCA R,ROSE D,DEBORD J R D,et al. Three-dimensional metal piperazinyldiphosphonate phases with ellipsoidal cavities defined by 44-membered rings:crystal structures of [M{O₃PCH₂NH(C₂H₄)₂NHCH₂PO₃]·H₂O,M = Mn and Co[J]. Journal of Solid State Chemistry,1996,123(2):408-412.
[26] SERRE Christian,GROVES John A, LIGHTFOOT Philip,et al. Synthesis,structure and properties of related microporous N,N'-piperazinebismethylenephosphonates of aluminum and titanium[J]. Chemistry of Materials,2006,18(60):1451-1457.
[27] LLEWELLYN P L,GARCIA-RATES M,GABEROVA L,et al. Structural origin of unusual CO₂ adsorption behavior of a small-pore aluminum bisphosphonate MOF[J]. The Journal of Physical Chemistry C,2015,119(8):4208-4216.
[28] BENOIT V,PILLAI R S,ORSI A,et al. MIL-91(Ti),a small pore metal-organic framework which fulfils several criteria:an upscaled green synthesis,excellent water stability,high CO₂ selectivity and fast CO₂ transport[J]. Journal of Materials Chemistry A,2016,4(4):1383-1389.
[29] GROVES J A,MILLER S R,WARRENDER S J,et al. The first route to large pore metal phosphonates[J]. Chemical Communications,2006,31(31):3305-3307.
[30] GAGNON K,PERRY H P,CLEARFIELD A. Conventional and unconventional metal-organic frameworks based on phosphonate ligands:MOFs and UMOFs[J]. Chemical Reviews,2011,112(2):1034-1054.
[31] MILLER S R,PEARCE G M,WRIGHT P A,et al. Structural transformations and adsorption of fuel-related gases of a structurally responsive nickel phosphonate metal-organic framework,Ni-STA-12[J]. Journal of the American Chemical Society,2008,130(47):15967-15981.
[32] LI C P,DU M. ChemInform abstract:role of solvents in coordination supramolecular systems[J]. Chemical Communications,2011,42(40):5958-5972.
[33] MOWAT J P S,GROVES J A,WHARMBY M T,et al. Lanthanide N,N'-piperazine-bis(methylenephosphonates)(Ln =La,Ce,Nd)that display flexible frameworks,reversible hydration and cation exchange[J]. Journal of Solid State Chemistry,2009,182(10):2769-2778.
[34] DU Z Y,XU H B,MAO J G. Rational design of 0D,1D,and 3D open frameworks based on tetranuclear lanthanide(Ⅲ) sulfonate-phosphonate clusters[J]. Inorganic Chemistry,2006,45(24):9780-9788.
[35] WHARMBY M T,MILLER S R,GROVES J A,et al. Yttrium bisphosphonate STA-13:a racemic phosphonate metal organic framework with permanent microporosity[J]. Dalton Transactions,2010,39(28):6389-6391.
[36] WHARMBY M T,MOWAT J P S,THOMPSON S P,et al. Extending the pore size of crystalline metal phosphonates toward the mesoporous regime by isoreticular synthesis[J]. Journal of the American Chemical Society,2011,133(5):1266-1269.
[37] PATZSCHKE C,FORSYTH C M,BATTEN S R,et al. Formation of a non-porous cobalt-phosphonate framework by small pH change in the preparation of the microporous STA-16 (Co)[J]. Crystengcomm,2014,16(28):6296-6299.
[38] PATZSCHKE C,MARSHALL M,CHAFFEE A L. An adsorption study on STA-16(Co)[J]. Microporous and Mesoporous Materials,2016,222:169-177.
[39] YAZAYDIN A Ö,SNURR R Q,PARK T H,et al. Screening of metal-organic frameworks for carbon dioxide capture from flue gas using a combined experimental and modeling approach[J]. Journal of the American Chemical Society,2009,131(51):18198-18199.
[40] TADDEI M,COSTANTINO F,VIVANI R. Synthesis and crystal structure from X-ray powder diffraction data of two zirconium diphosphonates containing piperazine groups[J]. Inorganic Chemistry,2010,49(20):9664-9670.
[41] MAH R K,GELFAND B S,TAYLOR J M,et al. Reconciling order,stability,and porosity in phosphonate metal-organic frameworks via HF-mediated synthesis[J]. Inorganic Chemistry Frontiers,2015,2(3):273-277.
[42] IREMONGER S S,LIANG J,VAIDHYANATHAN R,et al. Phosphonate monoesters as carboxylate-like 1inkers for metal organic frameworks[J]. Journal of the American Chemical Society,2011,133(50):20048-20051.
[43] TAYLOR J M,VAIDHYANATHAN R,IREMONGER S S,et al. Enhancing water stability of metal-organic frameworks via phosphonate monoester linkers[J]. Journal of the American Chemical Society,2012,134(35):14338-14340.
[44] LIN J B,SHIMIZU G K H. Pyridinium linkers and mixed anions in cationic metal-organic frameworks[J]. Inorg. Chem. Front.,2014,1(1):302-305.
[45] GELFAND B S,LIN J B,SHIMIZU G K. Design of a humidity-stable metal-organic framework using a phosphonate monoester ligand[J]. Inorganic Chemistry,2015,54(4):1185-1187.

膦酸类金属-有机骨架材料对CO₂的吸附性能研究进展

Progress of application for CO₂adsorption with phosphonate metal-organic frameworks

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	时永兴, 林刚, 孙晓航, 蒋韦庚, 乔大伟, 颜彬航. 二氧化碳加氢制甲醇过程中铜基催化剂活性位点研究进展[J]. 化工进展, 2023, 42(S1): 287-298.
[2]	郑谦, 官修帅, 靳山彪, 张长明, 张小超. 铈锆固溶体Ce_0.25Zr_0.75O₂光热协同催化CO₂与甲醇合成DMC[J]. 化工进展, 2023, 42(S1): 319-327.
[3]	戴欢涛, 曹苓玉, 游新秀, 徐浩亮, 汪涛, 项玮, 张学杨. 木质素浸渍柚子皮生物炭吸附CO₂特性[J]. 化工进展, 2023, 42(S1): 356-363.
[4]	崔守成, 徐洪波, 彭楠. 两种MOFs材料用于O₂/He吸附分离的模拟分析[J]. 化工进展, 2023, 42(S1): 382-390.
[5]	陈崇明, 陈秋, 宫云茜, 车凯, 郁金星, 孙楠楠. 分子筛基CO₂吸附剂研究进展[J]. 化工进展, 2023, 42(S1): 411-419.
[6]	许春树, 姚庆达, 梁永贤, 周华龙. 共价有机框架材料功能化策略及其对Hg(Ⅱ)和Cr(Ⅵ)的吸附性能研究进展[J]. 化工进展, 2023, 42(S1): 461-478.
[7]	顾永正, 张永生. HBr改性飞灰对Hg⁰的动态吸附及动力学模型[J]. 化工进展, 2023, 42(S1): 498-509.
[8]	孙玉玉, 蔡鑫磊, 汤吉海, 黄晶晶, 黄益平, 刘杰. 反应精馏合成甲基丙烯酸甲酯工艺优化及节能[J]. 化工进展, 2023, 42(S1): 56-63.
[9]	郭强, 赵文凯, 肖永厚. 增强流体扰动强化变压吸附甲硫醚/氮气分离的数值模拟[J]. 化工进展, 2023, 42(S1): 64-72.
[10]	杨寒月, 孔令真, 陈家庆, 孙欢, 宋家恺, 王思诚, 孔标. 微气泡型下向流管式气液接触器脱碳性能[J]. 化工进展, 2023, 42(S1): 197-204.
[11]	王胜岩, 邓帅, 赵睿恺. 变电吸附二氧化碳捕集技术研究进展[J]. 化工进展, 2023, 42(S1): 233-245.
[12]	葛亚粉, 孙宇, 肖鹏, 刘琦, 刘波, 孙成蓥, 巩雁军. 分子筛去除VOCs的研究进展[J]. 化工进展, 2023, 42(9): 4716-4730.
[13]	杨莹, 侯豪杰, 黄瑞, 崔煜, 王兵, 刘健, 鲍卫仁, 常丽萍, 王建成, 韩丽娜. 利用煤焦油中酚类物质Stöber法制备碳纳米球用于CO₂吸附[J]. 化工进展, 2023, 42(9): 5011-5018.
[14]	张振, 李丹, 陈辰, 吴菁岚, 应汉杰, 乔浩. 吸附树脂对唾液酸的分离纯化[J]. 化工进展, 2023, 42(8): 4153-4158.
[15]	王耀刚, 韩子姗, 高嘉辰, 王新宇, 李思琪, 杨全红, 翁哲. 铜基催化剂电还原二氧化碳选择性的调控策略[J]. 化工进展, 2023, 42(8): 4043-4057.