含磺酸基团的环氧琥珀酸类共聚物的合成及性能比较

doi:10.16085/j.issn.1000-6613.2017.04.044

化工进展 ›› 2017, Vol. 36 ›› Issue (04): 1491-1498.DOI: 10.16085/j.issn.1000-6613.2017.04.044

含磺酸基团的环氧琥珀酸类共聚物的合成及性能比较

李海花^1,2, 高美玲³, 张利辉^1,2, 高玉华^1,2, 刘振法^1,2

1 河北省科学院能源研究所, 河北石家庄 050081;
2 河北省工业节水工程技术研究中心, 河北石家庄 050081;
3 河北工业大学化工学院, 天津 300130

收稿日期:2016-07-12 修回日期:2016-11-28 出版日期:2017-04-05 发布日期:2017-04-05
通讯作者: 刘振法,博士,研究员,主要从事工业水处理及污水资源化研究。E-mail:lzf63@sohu.com。
作者简介:李海花(1979-),女,博士,助理研究员,主要从事绿色水处理剂及水处理工艺开发。E-mail:873756647@qq.com。
基金资助:
国家自然科学基金（21376062）及河北省自然科学基金（B2015302008）项目。

Synthesis of ESA-polymers containing sulfonic acid groups and their performance comparison

LI Haihua^1,2, GAO Meiling³, ZHANG Lihui^1,2, GAO Yuhua^1,2, LIU Zhenfa^1,2

1 Institute of Energy Resources, Hebei Academy of Science, Shijiazhuang 050081, Hebei, China;
2 Hebei Engineering Research Center for Water Saving in Industry, Shijiazhuang 050081, Hebei, China;
3 College of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China

Received:2016-07-12 Revised:2016-11-28 Online:2017-04-05 Published:2017-04-05

摘要/Abstract

摘要： 选用烯丙基磺酸钠（SAS）、苯乙烯磺酸钠（SS）、2-丙烯酰胺基-2-甲基丙磺酸（AMPS）和衣康酸（IA）为单体，与环氧琥珀酸（ESA）分别合成了ESA/SAS、ESA/SS、ESA/AMPS和ESA/IA/AMPS四种含磺酸基团的环氧琥珀酸类共聚物，利用FTIR对共聚物的结构进行了表征，利用SEM对使用不同共聚物时生成的碳酸钙晶型进行了观察。对各种共聚物的阻垢分散性能进行了研究，并与聚环氧琥珀酸（PESA）进行了比较。实验结果表明，4种共聚物中，ESA/IA/AMPS具有全面的水处理性能，在高硬度和高碱度水质条件下表现出优异的阻碳酸钙垢和阻磷酸钙垢性能。当其加药量为40mg/L时，对CaCO₃的阻垢率为82.7%，比PESA提高了10.4%。当加药量为30mg/L时，对Ca₃（PO₄）₂的阻垢率可达100%。同时，ESA/IA/AMPS易于生物降解，14天后可以降解72.7%。电镜分析结果表明，加入共聚物后，垢样中出现了球霰石型碳酸钙，这说明共聚物可以使不稳定相稳定存在，增加了碳酸钙在水中的溶解性和分散性。

关键词: 聚合物, 环氧琥珀酸, 磺酸基团, 阻垢分散, 降解

Abstract: Four ESA-polymers containing sulfonic acid groups were synthesized by copolymerization of monomers of epoxysuccinic acid(ESA) and sodium allyl sulfonate(SAS),sodium styrene sulfonate(SS),2-acrylamido-2-methylpropanesulfonic acid(AMPS) and itaconic acid(IA). Their molecule structures were characterized by FTIR spectrum,and the crystalline shapes of the CaCO₃ formed from different polymers were observed by SEM. The scale inhibition and dispersion performances of the polymers were studied and compared with those of PESA. The results showed that the polymer of ESA/IA/AMPS had comprehensive water treatment performances,which showed excellent scale inhibition performances to CaCO₃ and Ca₃(PO₄)₂ in the water of high hardness and alkalinity. When the dosage was 40mg/L,the inhibition rate to CaCO₃ scales was 82.7%,10.4% higher than that of PESA. When the dosage was 30mg/L,the scale inhibition rate to Ca₃(PO₄)₂reached 100%. Moreover,ESA/IA/AMPS was easy to be biodegraded,and its biodegradation percentage reached 72.7% after 14d.The results of SEM showed that there were vaterite type CaCO₃in the scales formed in the water samples with the addition of the polymers. This indicated that the polymers could stabilize the unstable phase,and thus enhance the solubility and dispersion of CaCO₃ in water.

Key words: polymers, epoxysuccinic acid, sulfonic acid group, scale inhibition and dispersion, degradation

中图分类号:

TQ085⁺.4

李海花, 高美玲, 张利辉, 高玉华, 刘振法. 含磺酸基团的环氧琥珀酸类共聚物的合成及性能比较[J]. 化工进展, 2017, 36(04): 1491-1498.

LI Haihua, GAO Meiling, ZHANG Lihui, GAO Yuhua, LIU Zhenfa. Synthesis of ESA-polymers containing sulfonic acid groups and their performance comparison[J]. Chemical Industry and Engineering Progress, 2017, 36(04): 1491-1498.

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含磺酸基团的环氧琥珀酸类共聚物的合成及性能比较

Synthesis of ESA-polymers containing sulfonic acid groups and their performance comparison

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