SiO2 Opal光子晶体结构周期数对TiO2染料敏化太阳能电池光电性能的影响

doi:10.16085/j.issn.1000-6613.2017.03.015

化工进展 ›› 2017, Vol. 36 ›› Issue (03): 881-886.DOI: 10.16085/j.issn.1000-6613.2017.03.015

SiO₂ Opal光子晶体结构周期数对TiO₂染料敏化太阳能电池光电性能的影响

李萍^1,2, 徐交¹, 陈胜利², 王爱军², 朱慧丽², 王媛²

1 武汉工程大学化工与制药学院, 绿色化工过程省部共建教育部重点实验室, 湖北省新型反应器与绿色化学工艺重点实验室, 湖北武汉 430205;
2 中国石油大学(北京)化学工程学院, 重质油国家重点实验室, 北京 102249

收稿日期:2016-08-19 修回日期:2016-11-09 出版日期:2017-03-05 发布日期:2017-03-05
通讯作者: 李萍(1977-),女,博士,讲师,研究方向为化工新材料。
作者简介:李萍(1977-),女,博士,讲师,研究方向为化工新材料。E-mail:pingli@wit.edu.cn。
基金资助:
湖北省教育厅科学研究计划中青年人才项目（Q20151501）。

The effect of SiO₂ Opal periodicity on the photoelectric performance of TiO₂ dye-sensitized solar cell

LI Ping^1,2, XU Jiao¹, CHEN Shengli², WANG Aijun², ZHU Huili², WANG Yuan²

1 School of chemical Engineering and pharmacy, Wuhan Institute of Technology, Key Laboratory for Green Chemical Process of Ministry of Education, The Hubei Key Laboratory of New-Type Reactors and Green Chemical Technology, Wuhan 430073, Hubei, China;
2 State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum, Beijing 102249, China

Received:2016-08-19 Revised:2016-11-09 Online:2017-03-05 Published:2017-03-05

摘要/Abstract

摘要：

通过在N719敏化的纳米晶二氧化钛膜上耦合SiO₂ Opal光子晶体，以此复合膜为光阳极，以敏化二氧化钛与无序SiO₂的复合膜为参比膜，考察了SiO₂ Opal光子晶体结构周期数对电池光电性能的影响。SiO₂ Opal光子晶体的结构周期数由制备光子晶体时的沉积液浓度控制。实验结果表明复合光子晶体后，电池的短路电流密度I_SC和能量转化效率Eff明显提高，且光子晶体周期数越多，提高率越大，当SiO₂ Opal结构周期数增加至20层时，I_SC和Eff与参比膜相比分别增加了91%和164%。IPCE分析表明光电性能提高的原因在于当光子晶体带隙与N719吸收峰重合时，利用光子带隙反射与光局域效应可提高N719对波长530nm光的吸收率。即光子晶体可有效提高吸光材料在光子带隙处的吸光率，且随着光子周期数增加，提升效果越显著。

关键词: 二氧化硅, 太阳能, 纳米材料, SiO₂ Opal光子晶体, 结构周期数, 纳米晶TiO₂, 染料敏化电池

Abstract:

The effect of photonic-crystals (PC) periodicity on the photoelectric performance of dye-sensitized solar cells was studied. The anodes of solar cells was the N719 dye-sensitized nanocrystalline TiO₂ film which was coupled with one layer of SiO₂ Opal PC with different periodicity. The periodicity of SiO₂ PC was controlled by the concentration of silica suspension in vertical deposition. It was shown that the Short circuit current density(I_SC) and the energy conversion efficiency(Eff) of the DSSC increased with the SiO₂ PCs periodicity. When the SiO₂ Opal increased to 20 layers,compared with reference film,I_SC and Eff increased by 91% and 164%,respectively. The results of IPCE analysis indicated that the improved performance of DSSCs was mainly attributed to the enhanced light-harvest of the N719 dye near 530nm by the light reflection at photonic band gap and photon localization of SiO₂ Opal. The Photonic crystal can effectively improve the light-harvest at the photonic band gap. The more the periodicity of the PC is,the stronger the effect of its photon localization is.

Key words: silica, solar energy, nanomaterials, SiO₂ Opal photonic crystals, periodicity, nanocrystalline TiO₂, dye-sensitized solar cells

中图分类号:

O6-1

李萍, 徐交, 陈胜利, 王爱军, 朱慧丽, 王媛. SiO₂ Opal光子晶体结构周期数对TiO₂染料敏化太阳能电池光电性能的影响[J]. 化工进展, 2017, 36(03): 881-886.

LI Ping, XU Jiao, CHEN Shengli, WANG Aijun, ZHU Huili, WANG Yuan. The effect of SiO₂ Opal periodicity on the photoelectric performance of TiO₂ dye-sensitized solar cell[J]. Chemical Industry and Engineering Progress, 2017, 36(03): 881-886.

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SiO₂ Opal光子晶体结构周期数对TiO₂染料敏化太阳能电池光电性能的影响

The effect of SiO₂ Opal periodicity on the photoelectric performance of TiO₂ dye-sensitized solar cell

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