脱氧胆酸修饰的银纳米粒子比色法检测H2PO4-

doi:10.16085/j.issn.1000-6613.2017.01.036

化工进展 ›› 2017, Vol. 36 ›› Issue (01): 289-293.DOI: 10.16085/j.issn.1000-6613.2017.01.036

脱氧胆酸修饰的银纳米粒子比色法检测H₂PO₄^-

展军颜, 崔建国, 黄燕敏, 甘春芳, 刘志平

广西师范学院化学与材料科学学院, 广西南宁 530001

收稿日期:2016-04-06 修回日期:2016-08-12 出版日期:2017-01-05 发布日期:2017-01-05
通讯作者: 展军颜(1982-),女,副教授,主要从事功能界面材料研究。E-mail:zhanjunyan@126.com。
作者简介:展军颜(1982-),女,副教授,主要从事功能界面材料研究。E-mail:zhanjunyan@126.com。
基金资助:
广西自然科学基金青年基金（2013GXNSFBA019027）、广西高校科学技术研究项目一般项目（2013YB150）及有机化学广西高校重点学科资助项目。

Colorimetric detection of dihydrogen phosphate based on deoxycholic acid modified silver nanoparticles

ZHAN Junyan, CUI Jianguo, HUANG Yanmin, GAN Chunfang, LIU Zhiping

School of Chemistry and Materials Science, Guangxi Teachers Education University, Nanning 530001, Guangxi, China

Received:2016-04-06 Revised:2016-08-12 Online:2017-01-05 Published:2017-01-05

摘要/Abstract

摘要： 阴离子在生命科学和环境科学等领域发挥重要的作用，建立快速、高效的阴离子检测方法越来越被关注。本文基于脱氧胆酸修饰的银纳米探针建立一种简便快速检测H₂PO₄^-的比色方法。采用硼氢化钠还原法合成脱氧胆酸修饰的银纳米粒，将该银纳米粒用于对阴离子的比色检测。结果表明，通过银纳米粒表面的配体脱氧胆酸与H₂PO₄^-之间较强的氢键作用，H₂PO₄^-诱导银纳米粒颜色的改变，HPO₄^2-等其他阴离子并未发生明显变化，从而实现对H₂PO₄^-高选择性的比色识别。该脱氧胆酸修饰的银纳米粒探针检测H₂PO₄^-的线性范围为6×10^-7~6×10^-6mol/L，比色检测限为7×10^-7mol/L，可以在水溶液中实现对H₂PO₄^-的检测。

关键词: 纳米粒子, 脱氧胆酸, 比色检测, 银, 选择性

Abstract: It is of extensive interest in developing a simple,selective,sensitive and rapid approach for anions sensing,as anions play a significant role in biological systems and environment. A simple and sensitive detection method based on the deoxycholic acid modified silver nanoparticles has been developed for the determination of H₂PO₄^- in aqueous solution. The deoxycholic acid modified silver nanoparticles were synthesized by reduction method with sodium borohydride. The research indicates that those Ag NPs allowH₂PO₄^- to be visually detected with high selectivity because of the hydrogen bonding interaction between H₂PO₄^- and the ligand. Moreover,the assay method showed a linear response range of 6×10^-7-6×10^-6mol/L for H₂PO₄^- with colorimetric detection limit being 7×10^-7 mol/L,which allows the method to be applied for the colorimetric detection of H₂PO₄^-.

Key words: nanoparticles, deoxycholic acid, colorimetric detection, silver, selectivity

中图分类号:

O648

展军颜, 崔建国, 黄燕敏, 甘春芳, 刘志平. 脱氧胆酸修饰的银纳米粒子比色法检测H₂PO₄^-[J]. 化工进展, 2017, 36(01): 289-293.

ZHAN Junyan, CUI Jianguo, HUANG Yanmin, GAN Chunfang, LIU Zhiping. Colorimetric detection of dihydrogen phosphate based on deoxycholic acid modified silver nanoparticles[J]. Chemical Industry and Engineering Progree, 2017, 36(01): 289-293.

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脱氧胆酸修饰的银纳米粒子比色法检测H₂PO₄^-

Colorimetric detection of dihydrogen phosphate based on deoxycholic acid modified silver nanoparticles

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