ZnO负载SnO2复合材料的制备及其气敏性能

doi:10.16085/j.issn.1000-6613.2017-0907

化工进展 ›› 2018, Vol. 37 ›› Issue (02): 651-657.DOI: 10.16085/j.issn.1000-6613.2017-0907

ZnO负载SnO₂复合材料的制备及其气敏性能

魏莹^1,2, 仪桂云^1,2, 王晓冬^1,2, 许亚威^1,2, 周利星^1,2

1 河南理工大学材料科学与工程学院, 河南焦作 454000;
2 河南理工大学环境友好型无机材料河南省高校重点实验室培育基地, 河南焦作 454000

收稿日期:2017-05-16 修回日期:2017-07-26 出版日期:2018-02-05 发布日期:2018-02-05
通讯作者: 仪桂云,讲师,研究方向为碳材料的制备与应用。
作者简介:魏莹(1989-),女,硕士研究生。
基金资助:
国家自然科学基金（51404097，61474038，51404097）、河南省科技攻关项目（132102210251）及河南省高等学校重点科研项目计划（15A430027）。

Preparation and sensing properties of ZnO supporting SnO₂ nanocomposites

WEI Ying^1,2, YI Guiyun^1,2, WANG Xiaodong^1,2, XU Yawei^1,2, ZHOU Lixing^1,2

1 Institute of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, Henan, China;
2 Key Laboratory Cultivation Base of Environment-Friendly Inorganic Materials in Henan Province, Henan Polytechnic University, Jiaozuo 454000, Henan, China

Received:2017-05-16 Revised:2017-07-26 Online:2018-02-05 Published:2018-02-05

摘要/Abstract

摘要： 以五水四氯化锡（SnCl₄·5H₂O）和乙酸锌[Zn （AC）₂·2H₂O]为原料，氢氧化钠（NaOH）为沉淀剂，采用简单的水热法，使二氧化锡（SnO₂）纳米颗粒锚定在蚕蛹状氧化锌（ZnO）表面，一步成功合成了二氧化锡/氧化锌（SnO₂/ZnO）复合材料。采用X射线衍射仪（XRD）、透射电镜（TEM）、高分辨透射电镜（HRTEM）和氮气吸附脱附仪（BET）对材料的结构和形貌进行了表征，研究并讨论了温度、乙醇浓度等因素对SnO₂、ZnO及SnO₂/ZnO复合材料气敏性能的影响。结果表明，所得样品为SnO₂纳米颗粒与蚕蛹状ZnO的复合物，SnO₂纳米颗粒较均匀地负载在ZnO表面。SnO₂/ZnO复合材料气敏元件在最佳工作温度为240℃时，对200μL/L乙醇的灵敏度达到39.68，与SnO₂（24.53）及ZnO （17.8）相比，气敏性能得到了很大的提高。

关键词: 二氧化锡/氧化锌, 粒子, 水热, 复合材料, 气敏性能, 选择性

Abstract: SnO₂/ZnO composites were synthesized by a facile hydrothermal method using SnCl₄·5H₂O and Zn(AC)₂·2H₂O as the raw material and NaOH as the precipitant, which makes SnO₂ nanoparticles adhere to the surface of silkworm chrysalis-like ZnO. The structure and morphology of the obtained materials were characterized by XRD, TEM, HRTEM and BET. And the effects of temperature, ethanol concentration and other factors on the sensitivity were inverstigated. The results confirmed that the composite materials were SnO₂ nanoparticles and silkworm chrysalis-like ZnO. The SnO₂ nanoparticles were distributed on the surface of ZnO. The SnO₂/ZnO composite exhibited good gas-sensing properties, and the sensitivity of the sensor to 200μL/L ethanol was 39.68 at the optimum operating temperature (240℃), which were almost double of that of the individual SnO₂(24.53) and ZnO sensor(17.8).

Key words: SnO₂/ZnO, particles, hydrothermal, composites, gas-sensing properties, selectivity

中图分类号:

TQ17

魏莹, 仪桂云, 王晓冬, 许亚威, 周利星. ZnO负载SnO₂复合材料的制备及其气敏性能[J]. 化工进展, 2018, 37(02): 651-657.

WEI Ying, YI Guiyun, WANG Xiaodong, XU Yawei, ZHOU Lixing. Preparation and sensing properties of ZnO supporting SnO₂ nanocomposites[J]. Chemical Industry and Engineering Progress, 2018, 37(02): 651-657.

参考文献

[1] MIRZAEI A, PARK S, SUN G J, et al. Fe₂O₃/Co₃O₄ composite nanoparticle ethanol sensor[J]. Journal of the Korean Physical Society, 2016, 69(3):373-380.
[2] XIAO Y, YANG Q Y, WANG Z Y, et al. Improvement of NO₂ gas sensing performance based on discoid tin oxide modified by reduced graphene oxide[J]. Sensors & Actuators B:Chemical, 2016, 227:419-426.
[3] 李振昊, 李文乐, 孔繁华, 等. 掺杂二氧化锡的应用研究进展[J]. 化工进展, 2010, 29(12):2324-2329. LI Zhenhao, LI Wenle, KONG Fanhua, et al. Advances in applied research of doped SnO₂[J]. Chemical Industry and Engineering Progress, 2010, 29(12):2324-2329.
[4] ZHANG D Z, CHANG H H, LI P. Characterization of nickel oxide decorated-reduced graphene oxide nanocomposite and its sensing properties toward methane gas detection[J]. Journal of Materials Science:Materials in Electronics, 2016, 27(4):3723-3730.
[5] 娄向东,刘淑萍,师东阳,等. H₂S气敏材料研究进展[J].化工进展, 2006, 25(1):43-46. LOU Xiangdong, LIU Shuping, SHI Dongyang, et al. Research progress on H₂S-sensing materials[J].Chemical Industry and Engineering Progress, 2006, 25(1):43-46.
[6] SHAALAN N M, RASHAD M, MOHARRAM A H, et al. Promising methane gas sensor synthesized by microwave-assisted Co₃O₄ nanoparticles[J]. Materials Science in Semiconductor Processing, 2016, 46:1-5.
[7] 熊静芳,肖佩,吴强,等.氧化锌多孔微米花的制备及其气敏性能研究[J].化学学报, 2014, 72(4):433-439. XIONG Jingfang, XIAO Pei, WU Qiang, et al. Synthesis and gas-sensing properties of ZnO porous microflowers[J]. Acta Chimica Sinica, 2014, 72(4):433-439.
[8] 柴丽雅,刘松莹,杨颖,等.氧化石墨烯与氧化锌复合材料的制备及室温NO_x气敏性能研究[J].人工晶体学报, 2013, 42(8):1611-1615. CAI Liya, LIU Songying, YANG Ying, et al.Synthesis and NO_x gas sensitivity at room temperature of graphene oxide and ZnO composites[J]. Journal of Synthetic Crystals, 2013, 42(8):1611-1615.
[9] PATIL S B, PATIL P P, MORE M A.Acetone vapour sensing characteristics of cobalt-doped SnO₂ thin films[J].Sensors & Actuators B:Chemical, 2007, 125(1):126-130.
[10] SHI Y J. Effects of gas diffusivity and reactivity on sensing properties of thick film SnO₂-based sensors[J].Sensors & Actuators B:Chemical, 1998, 46(3):163-168.
[11] 左霞,韦永德,吴谊群.高灵敏度高选择性气敏材料——金属酞菁配合物[J].化工进展, 2004, 23(1):69-76. ZUO Xia, WEI Yongde, WU Yiqun. High sensitive and selective gas sensing materials——metallophthalocyanines[J]. Chemical Industry and Engineering Progress, 2004, 23(1):69-76.
[12] SILVA L F D, M'PEKO J C, CATTO A C, et al. UV-enhanced ozone gas sensing response of ZnO-SnO₂ heterojunctions at room temperature[J]. Sensors & Actuators B Chemical,2017,40:573-579.
[13] WANG L W, LI J T, WANG Y H, et al. Construction of 1D SnO₂-coated ZnO nanowire heterojunction for their improved n-butylamine sensing performances[J]. Sci. Rep., 2016, 6:35079.
[14] HEMMATI S, FIROOZ A A, KHODADADI A A, et al.Nanostructured SnO₂-ZnO sensors:highly sensitive and selective to ethanol[J]. Sensors & Actuators B Chemical, 2011, 160(1):1298-1303.
[15] ZHANG B, FU W, LI H, et al.Actinomorphic ZnO/SnO₂ core-shell nanorods:two-step synthesis and enhanced ethanol sensing propertied[J]. Materials Letters, 2015, 160:227-230.
[16] 王莹,王晓冬,许亚威,等.贯通有序大孔SnO₂气敏材料的制备及气敏性能[J].化工进展, 2016, 35(11):3570-3575. WANG Ying, WANG Xiaodong, XU Yawei, et al. Preparation of interconnected ordered macroporous SnO₂ gas-sensing material with enhanced gas-sensing properties[J].Chemical Industry and Engineering Progress, 2016, 35(11):3570-3575.
[17] LU G, XU J, SUN J, et al. UV-enhanced room temperature NO₂ sensor using ZnO nanorods modified with SnO₂ nanoparticles[J]. Sensors & Actuators B:Chemical, 2012, 162(6):82-88.
[18] WANG Y, WANG X D, YI G Y, et al. Synthesis of layered hierarchical porous SnO₂ for enhancing gas sensing performance[J]. Journal of Porous Materials, 2016, 23(6):1-8.

ZnO负载SnO₂复合材料的制备及其气敏性能

Preparation and sensing properties of ZnO supporting SnO₂ nanocomposites

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