单分散磁性Fe3O4纳米粒子的研究进展

doi:10.16085/j.issn.1000-6613.2016.s1.039

化工进展 ›› 2016, Vol. 35 ›› Issue (S1): 242-247.DOI: 10.16085/j.issn.1000-6613.2016.s1.039

单分散磁性Fe₃O₄纳米粒子的研究进展

汪彩虹, 陈硕然, 叶常青, 王筱梅

苏州科技大学江苏省环境功能材料重点实验室, 绿色印刷纳米光子工程技术研究中心, 江苏苏州 215009

收稿日期:2015-12-17 修回日期:2016-01-21 出版日期:2016-06-30 发布日期:2016-07-08
通讯作者: 叶常青,副教授,研究方向为光子晶体,有机光电材料。E-mail yechangqing@mail.usts.edu.cn。
作者简介:汪彩虹(1992-),女,硕士研究生。
基金资助:
国家自然科学基金(51303122)、江苏省自然科学基金(BK20130262)及江苏省环境功能材料重点实验室开放基金(SJHG1311)项目。

Research progress on monodisperse Fe₃O₄ magnetic nanoparticles

WANG Caihong, CHEN Shuoran, YE Changqing, WANG Xiaomei

Research Center for Green Printing of Nano Photonic Engineering, Jiangsu Key Laboratory for Environment Function Materials, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu, China

Received:2015-12-17 Revised:2016-01-21 Online:2016-06-30 Published:2016-07-08

摘要/Abstract

摘要： 具有良好的化学稳定性、生物相容性、磁响应性的单分散磁性Fe₃O₄纳米粒子,在药学、催化化学、医学和光电磁记录材料等方面都有很大的使用前景;而具有自组装光子晶体现象的Fe₃O₄磁性纳米粒子在包装、印刷、防伪等领域的应用中更展现出巨大的潜力。本文在对单分散磁性Fe₃O₄纳米粒子的制备方法进行了总结回顾,并对单分散磁性Fe₃O₄纳米粒子的光学应用领域做了简略的介绍,并对单分散磁性Fe₃O₄纳米粒子的发展趋向进行了展望,并总结分析现阶段大多数Fe₃O₄纳米粒子的合成方法在非极性溶液中分散性差,使其在实际应用中受到很大的限制,未来Fe₃O₄纳米粒子表面进行修饰将成为该领域的研究热点之一。

关键词: 四氧化三铁, 纳米粒子, 单分散, 制备方法, 进展

Abstract: The monodisperse Fe₃O₄ magnetic nanoparticles have drawn more and more attention for their unique properties, such as good chemical stability, biocompatibility, magnetic response and so on, which show great pratical potential in the fields of pharmacy, and optical/magnetic recording materials.Particularly, The monodisperse Fe₃O₄ magnetic nanoparticles can also be directly employed for constructing colloidal photonic crystals with highly tunable stop bands which can be moved across the entire visible spectral region.In this paper, several preparation methods of monodisperse Fe₃O₄ magnetic nanoparticles were summarized, the applications fields were briefly introduced and the development trends of monodisperse Fe₃O₄ magnetic nanoparticles were discussed.It was pointed out that the applications of Fe₃O₄ nanoparticles are limited due to poor dispersion in non-polar solution.Therefore, the surface modification of Fe₃O₄ nanoparticles will be the focus study in this area.

Key words: ferriferrous oxide, nanoparticles, monodisperse, preparation methods, progress

中图分类号:

O734

汪彩虹, 陈硕然, 叶常青, 王筱梅. 单分散磁性Fe₃O₄纳米粒子的研究进展[J]. 化工进展, 2016, 35(S1): 242-247.

WANG Caihong, CHEN Shuoran, YE Changqing, WANG Xiaomei. Research progress on monodisperse Fe₃O₄ magnetic nanoparticles[J]. Chemical Industry and Engineering Progree, 2016, 35(S1): 242-247.

参考文献

[1] WU W,HE Q G, JIANG C Z.Magnetic iron oxide nanoparticles:synthesis and surface functionalization strategies[J].Nanoscale Res.Lett.,2008,3(11):397-415.
[2] GUPTA A K and GUPTA M.Synthesis and surface engineering of iron oxide nanoparticles for biomedical applications[J]. Biomater.,2005,26(18):3995-4021.
[3] GILCHRIST R,MEDAL R,SHOREY W D,et al.Selective inductive heating of lymph nodes[J].Ann.Surg.,1957,146(4):596-606.
[4] LIONG M,LU J,KOVOCHICH M,et al.Multifunctionl inorganic nanoparticles for imaging,targeting,and drug delivery[J].ACS Nano.,2008,2(5):889-896.
[5] LAURENT S,FORGE D,PORT M,et al.Magnetic iron oxide nanoparticles:synthesis,stabilization,vectorization physicochemical characterizations and biological applications[J].Chem.Rev.,2008,108(6):2064-2110.
[6] BAO J,CHEN W,LIU T,et al.Bifunctional Au-Fe₃O₄ nanoparticles for protein separation[J].ACS Nano,2007,1(4):293-298.
[7] SAHOO S K,VINOD L.Nanotech approaches to drug delivery and imaging[J]. Drug Discovery Today,2003,8(24):1112-1120.
[8] JORDAN A,SCHOLZ R,WUST P,et al.Magnetic fluid hyperthermia (MFH):cancer treatment with AC magnetic field induced excitation of biocompatible superparamagnetic nanoparticles[J].Journal of Magnetism and Magnetic Materials,1999,201(1/2/3):413-419.
[9] YABLONOVITCH E.Inhibited spontaneous emission in soild-state physics and elect ronics[J].Phys.Rev.Lett.,1987,58(20):2059-2061.
[10] JOHN S.Strong localization of photons in certain disordered dielectric superlattices[J]. Phys.Rev.Lett.,1987,58(23):2486-2489.
[11] 薛群基,徐康.纳米化学[J].化学进展,2000,2(4):431-442.
[12] 徐如人,庞文琴.无机合成与制备化学[M].北京:高等教育出版社,2001:523-542.
[13] 宋孟杰.单分散Fe₃O₄纳米颗粒的形貌调控及其PEG化研究[D].南京:东南大学,2012.
[14] 宋丽贤,卢忠远,刘德春,等.分解沉淀法制备磁性纳米Fe₃O₄的研究及表征[J].化工进展,2006,25(l):54-57.
[15] 付云芝,牟敏仁,向伟,等.共沉淀法合成小粒径单分散Fe₃O₄纳米颗粒[J].广东化工,2009,36(9):2-3,47.
[16] 丁永玲,刘福田,程传兵,等.盐酸对共沉淀法合成单分散性纳米四氧化三铁的改性研[J].人工晶体学报,2012,41(2):468-473.
[17] XU X,FRIEDMAN G,HUMFELD K D,et al. Superparamagnetic photonic crystals[J]. Adv.Mater.,2001,13(20):1681-1684.
[18] XU X,FRIEDMAN G,HUMFELD K D,et al.Synthesis and utilization of monodisperse superparamagnetic colloidal particles for magnetically controllable photonic crystals[J]. Chem.Mater.,2002,14(3):1249-1256.
[19] KANG Y S,RISBUD S,RABOLT J F,et al.Synthesis and characterization of nanometer-size Fe₃O₄ and γ-Fe₂O₃ particles[J].Chem.Mater.,1996,8(9):2209-2211.
[20] SAUZEDDE F,ELAISSARI A,PICHOT C.Hydrophilic magnetic polymer latexes.1.Adsorption of magnetic iron oxide nanoparticles onto various cationic latexes[J].Colloid Polym.Sci.,1999,277(277):846-855.
[21] LIZ L,QUINTELA M A L,MIRA J,et al.Preparation of colloidal Fe₃O₄ ultrafine particles in microemulsions[J]. J.Mater.Sci.,1994,29(14):3797-3801.
[22] PEREZ J A, QUINTELA M A L,MIRA J,et al.Advances in the preparation of magnetic nanoparticles by the microemulsion method[J].J.Phys.Chem.B,1997,101(41):8045-8047.
[23] LEE J,ISOBE T,SENNA M.Preparation of ultrafine Fe₃O₄ particles by precipitation in the presence of PVA at high pH[J]. J.Colloid Interface Sci.,1996,177(2):490-494.
[24] YANASE N,NOGUCHI H,ASAKURA H,et al.Preparation of magnetic latex particles by emulsion polymerization of styrene in the presence of a ferrofluid[J].J.Appl.Polym.Sci.,1993,50(5):765-776.
[25] BRINKER C J,SCHERER G W.Soe-gel science:the physics and chemistry of sol-cel processing[M].San Diego:Academic Press,1990.
[26] 周洁,马明.不同尺寸Fe₃O₄磁性颗粒的制备和表征[J].东南大学学报(自然科学版),2005,35(4):615-618.
[27] 李志慧,付乌有,许静,等.单分散性Fe₃O₄纳米颗粒的制备及其表征[J].人工晶体学报,2008,37(4):977-980.
[28] 杨思源,戴伟,傅吉全,等.微乳液法制备纳米催化剂及其在加氢反应中应用的研究进展[J].石油化工,2012,41(4):471-476.
[29] 柴波.微乳法制备Fe₃O₄磁性纳米粒子的研究[J].武汉工业学院学报,2006,25(l):65-67.
[30] 宋丽贤,卢忠远,廖其龙.双微乳液法制备纳米磁性Fe₃O₄粉体的研究[J].功能材料,2005,36(11):1762-1764.
[31] SUN S H,ZENG H,ROBINSON D B,et al.Monodisperse MFe₂O₄ (M=Fe,Co,Mn)nano-particles[J]. J.Am.Soc.,2004,126(1):273-279.
[32] 窦永华,张玲,古宏晨.单分散Fe₃O₄纳米粒子的合成、表征及其自组装[J].功能材料,2007,38(1):119-122.
[33] GE J P,HU Y X,MAURIZIO B,et al.Superparamagnetic magnetite colloidal nanocrystal clusters[J]. Angew. Chem.Int.Ed.,2007,46(23):4342-4345.
[34] GE J P,HU Y X, YIN Y D.Highly tunable superparamagnetic colloidal photonic crystals[J].Angew.Chem.Int.Ed.,2007,46(39):7572-7575.
[35] 冯守华.水热与溶剂热合成化学[J].吉林师范大学学报,2008,29(3):7-11.
[36] 杨华,黄可龙.水热法制备的Fe₃O₄磁流体[J].磁性材料及器件,2003,34(2):4-6,15.
[37] 付佳,许启明,张文彦,等.单分散磁性Fe₃O₄纳米颗粒溶剂热合成及性能[J].化工进展,2008,27(3):457-459,471.
[38] WANG H,SUN Y B,CHEN Q W,et al.Synthesis of carbon-encapsulated superparamagnetic colloidal nanoparticles with magnetic-responsive photonic crystal property[J]. Dalton Trans.,2010,39(40):9565-9569.
[39] WANG H,CHEN Q W,YU Y F,et al.size- and solvent-dependent magnetically responsive optical diffraction of carbon-encapsulated superparamagnetic colloidal photonic crystals[J]. J. Phys.Chem.C,2011,115(23):11427-11434.
[40] HU H B,CHEN C L,CHEN Q W.Magnetically controllable colloidal photonic crystals:unique features and intriguing applications[J]. J.Mater.Chem.C,2013,1(38):6013-6030.
[41] GAO J N,RAN X Z,SHI C M,et al.One-step solvothermal synthesis of highly water-soluble,negatively charged superparamagnetic Fe₃O₄ colloidal nanocrystal clusters[J]. Nanoscale,2013,5(15):7026-7033.
[42] LUO W,MA H R,MOU F Z,et al.Steric-repulsion-based magnetically responsive photonic crystals[J].Adv.Mater.,2014,26(7):1058-1064.
[43] 蒋秉植,杨健美.磁性液体材料的应用[J].化工新型材料,1994(4):1-5.
[44] 毕玉水,张晓晓.磁性氧化铁纳米微粒的制备与应用[J].材料导报:纳米与新材料专辑,2014(1):50-52.

单分散磁性Fe₃O₄纳米粒子的研究进展

Research progress on monodisperse Fe₃O₄ magnetic nanoparticles

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