聚乙烯醇水凝胶自修复性能

doi:10.16085/j.issn.1000-6613.2016.08.31

化工进展 ›› 2016, Vol. 35 ›› Issue (08): 2507-2512.DOI: 10.16085/j.issn.1000-6613.2016.08.31

聚乙烯醇水凝胶自修复性能

龚桂胜, 刘景勃, 钟玉鹏, 林强, 张发爱

桂林理工大学材料科学与工程学院, 广西桂林 541004

收稿日期:2015-11-12 修回日期:2015-12-29 出版日期:2016-08-05 发布日期:2016-08-05
通讯作者: 张发爱,教授,博士生导师,主要从事聚合物纳米复合材料、天然产物化学、自愈合聚合物的研究。E-mail:zhangfaai@163.com。
作者简介:龚桂胜(1990—),男,硕士研究生。
基金资助:
国家自然科学基金项目（51263004）。

Self-healing performance of poly(vinyl alcohol) hydrogel

GONG Guisheng, LIU Jingbo, ZHONG Yupeng, LIN Qiang, ZHANG Faai

College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, Guangxi, China

Received:2015-11-12 Revised:2015-12-29 Online:2016-08-05 Published:2016-08-05

摘要/Abstract

摘要： 高浓度聚乙烯醇（PVA）水凝胶具有一定的修复功能，但其自修复机理及制备工艺参数对其修复性能的影响缺乏研究。本文采用冷冻-解冻法制备了高浓度自修复PVA水凝胶，通过调整PVA水凝胶制备工艺参数（PVA分子量、PVA浓度、冷冻时间、解冻时间、冷冻-解冻次数、修复时间、冷冻温度等）得到了最佳工艺条件，分析了水凝胶自修复机理，并研究了PVA水凝胶的多次自修复性能。研究结果表明：相对分子质量大的PVA制备的水凝胶自修复性能好；其中冷冻时间为2h，解冻时间为1h，一次冷冻-解冻循环制备得到的水凝胶自修复性能最好，最佳修复时间为12h，能较好地进行反复自修复。指出水凝胶自修复性能主要是由其内部可逆氢键的相互作用形成的，其主要影响源于冷冻-解冻处理后水凝胶内部羟基含量及PVA分子的流动性。

关键词: 聚乙烯醇, 自修复, 水凝胶, 制备, 机理

Abstract: The high concentration of poly(vinyl alcohol) hydrogels possesses self-healing property. However,its self-healing mechanism and the effects of the preparation conditions on the self-healing property of the hydrogel were rarely studied. In this paper,the high concentration PVA hydrogel was prepared by the freezing and thawing method. The optimum conditions were obtained by changing the preparation conditions(the PVA molecular weight,PVA concentration,freezing time,thawing time,numbers of freezing and thawing cycles,healing time,freezing temperature,etc.) and the self-healing mechanism was analyzed. The multiple self-healing performance of the hydrogel was also investigated. The results showed that the larger the molecular weight of the PVA,the better the self-healing performance of the hydrogels. The hydrogels prepared under 2h freezing and 1h thawing in only one cycle showed the best self-healing performance,and the best healing time was 12h. The PVA hydrogel could self-heal for many times. The self-healing property of the hydrogel was due to the interaction of reversible hydrogen bond,which was mainly influenced by the content of hydroxyl group and the mobility of the PVA molecules in the hydrogel.

Key words: poly(vingl alcohol)(PVA), self-healing, hydrogels, preparation, mechanism

中图分类号:

O643

龚桂胜, 刘景勃, 钟玉鹏, 林强, 张发爱. 聚乙烯醇水凝胶自修复性能[J]. 化工进展, 2016, 35(08): 2507-2512.

GONG Guisheng, LIU Jingbo, ZHONG Yupeng, LIN Qiang, ZHANG Faai. Self-healing performance of poly(vinyl alcohol) hydrogel[J]. Chemical Industry and Engineering Progree, 2016, 35(08): 2507-2512.

参考文献

[1] 李思超,韩朋,许华平.自修复高分子材料[J].化学进展,2012,24(7):1346-1352.
[2] 董坤,魏钊,志懋,等.自愈合凝胶:结构、性能及展望[J].中国科学(化学),2012,42(6):741-756.
[3] CAI Z,ZHANG J T,XUE F,et al.2D photonic crystal protein hydrogel coulometer for sensing serum albumin ligand binding[J].Analytical Chemistry,2014,86(10):4840-4847.
[4] ZHANG L,WU J T,SUN N,et al.A novel self-healing poly(amic acid) ammonium salt hydrogel with temperature-responsivity and robust mechanical properties[J].Journal of Materials Chemistry A,2014,2(21):7666-7668.
[5] CAI Z,KWAK D H,PUNIHAOLE D,et al.A photonic crystal protein hydrogel sensor for candida albicans[J].Angewandte Chemie International Edition,2015,54(44):13036-13040.
[6] 李海燕,张丽冰,李杰,等.外援型自修复聚合物材料研究进展[J].化工进展,2014,33(1):133-139,164.
[7] 雷鑫宇,李小可,于小荣,等.固井自修复水泥性能评价方法研究[J].精细石油化工进展,2015(2):9-11.
[8] PEPPAS N A,STAUFFER S R.Reinforced uncrosslinked poly(vinyl alcohol)gels produced by cyclic freezing-thawing processes:a short review[J].Journal of Controlled Release,1991,16(3):305-310.
[9] LOZINSKY V I,DOMOTENKO L V,ZUBOV A L,et al.Study of cryostructuration of polymer systems. Ⅻ. Poly(vinyl alcohol) cryogels:influence of low-molecular electrolytes[J].Journal of Applied Polymer Science,1996,61(11),1991-1998.
[10] YOKOYAMA F,MASADA I,SHIMAMURA K,et al.Morphology and structure of highly elastic poly(vinyl alcohol) hydrogel prepared by repeated freezing and melting[J].Colloid and Polymer Science,1986,264(7):595-601.
[11] 李钒,张金龙,尹玉姬.生物医用高强度水凝胶的研究进展[J].化工进展,2012,31(11):2511-2519,2534.
[12] LI Xinming,CUI Yingde. Sudy on synthesis and chloramphenicol release of poly(2-hydoxyethylmeth acrylate-co-acrylamide)hydrogels. [J].Chinese Journal of Chemical Engineering,2008,16(4):640-645.
[13] LOZINSKY V I,PLIEVA F M.Poly(vinyl alcohol) cryogels employed as matrices for cell immobilization.3.Overview of recent research and developments[J].Enzyme and Microbial Technology,1998,23(3/4),227-242.
[14] ZHOU L,HE B,ZHANG F.Facile one-pot synthesis of iron oxide nanoparticles cross-linked magnetic poly(vinyl alcohol) gel beads for drug delivery[J].ACS Applied Materials & Interfaces,2011,4(1):192-199.
[15] ZHANG H J,XIA H S,ZHAO Y.Poly(vinyl alcohol) hydrogel can autonomously self-heal[J].ACS Macro Letters,2012,1(11):1233-1236.
[16] GONZALEZ J S,HOPPE C E,MURACA D,et al.Synthesis and characterization of PVA ferrogels obtained through a one-pot freezing-thawing procedure[J].Colloid and Polymer Science,2011,289(17/18):1839-1846.
[17] 黄梅.冷冻解冻法聚乙烯醇凝胶体系研究[D]. 苏州:苏州大学,2012.
[18] 潘育松,熊党生,陈晓林.聚乙烯醇水凝胶的制备及性能[J].高分子材料科学与工程,2007(6):228-231.
[19] 陈立奇,张德坤,张劲松,等.冷冻温度对聚乙烯醇水凝胶性能的影响[J].中国组织工程研究与临床康复,2007,11(48):9679-9682.

聚乙烯醇水凝胶自修复性能

Self-healing performance of poly(vinyl alcohol) hydrogel

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	李梦圆, 郭凡, 李群生. 聚乙烯醇生产中回收工段第三、第四精馏塔的模拟与优化[J]. 化工进展, 2023, 42(S1): 113-123.
[2]	王乐乐, 杨万荣, 姚燕, 刘涛, 何川, 刘逍, 苏胜, 孔凡海, 朱仓海, 向军. SCR脱硝催化剂掺废特性及性能影响[J]. 化工进展, 2023, 42(S1): 489-497.
[3]	王谨航, 何勇, 史伶俐, 龙臻, 梁德青. 气体水合物阻聚剂研究进展[J]. 化工进展, 2023, 42(9): 4587-4602.
[4]	高彦静. 单原子催化技术国际研究态势分析[J]. 化工进展, 2023, 42(9): 4667-4676.
[5]	王少凡, 周颖, 郝康安, 黄安荣, 张如菊, 吴翀, 左晓玲. 具有pH响应性的自愈合蓝光水凝胶[J]. 化工进展, 2023, 42(9): 4837-4846.
[6]	宋伟涛, 宋慧平, 范朕连, 樊飙, 薛芳斌. 粉煤灰在防腐涂料中的研究进展[J]. 化工进展, 2023, 42(9): 4894-4904.
[7]	李润蕾, 王子彦, 王志苗, 李芳, 薛伟, 赵新强, 王延吉. CuO-CeO₂/TiO ₂ 高效催化CO低温氧化反应性能[J]. 化工进展, 2023, 42(8): 4264-4274.
[8]	吴亚, 赵丹, 方荣苗, 李婧瑶, 常娜娜, 杜春保, 王文珍, 史俊. 用于复杂原油乳液的高效破乳剂开发及应用研究进展[J]. 化工进展, 2023, 42(8): 4398-4413.
[9]	吴海波, 王希仑, 方岩雄, 纪红兵. 3D打印催化材料开发与应用进展[J]. 化工进展, 2023, 42(8): 3956-3964.
[10]	俞俊楠, 俞建峰, 程洋, 齐一搏, 化春键, 蒋毅. 基于深度学习的变宽度浓度梯度芯片性能预测[J]. 化工进展, 2023, 42(7): 3383-3393.
[11]	储甜甜, 刘润竹, 杜高华, 马嘉浩, 张孝阿, 王成忠, 张军营. 有机胍催化脱氢型RTV硅橡胶的制备和可降解性能[J]. 化工进展, 2023, 42(7): 3664-3673.
[12]	欧阳素芳, 周道伟, 黄伟, 贾凤. 新型耐迁移橡胶防老剂的研究进展[J]. 化工进展, 2023, 42(7): 3708-3719.
[13]	冯琬淇, 哈尼夏·巴合提null, 葛雨璇, 赵俭波. 磁性PASP/PAM半互穿水凝胶的制备及性能[J]. 化工进展, 2023, 42(6): 3130-3137.
[14]	于丁一, 李圆圆, 王晨钰, 纪永升. pH响应性木质素水凝胶的制备及药物控释[J]. 化工进展, 2023, 42(6): 3138-3146.
[15]	杨家添, 唐金铭, 梁恣荣, 黎胤宏, 胡华宇, 陈渊. 新型淀粉基高吸水树脂抑尘剂的制备及其应用[J]. 化工进展, 2023, 42(6): 3187-3196.