类沸石咪唑酯骨架材料(ZIFs)的研究进展

doi:10.16085/j.issn.1000-6613.2015.11.020

摘要/Abstract

摘要： 类沸石咪唑酯骨架化合物(zeolitic imidazolate frameworks,ZIFs)是一种新型的MOFs材料,ZIFs是将咪唑环上的N原子络合到二价过渡金属离子上而形成的一种具有沸石拓扑结构的多孔晶体材料,通过调变配体或配体间的相互作用就可以形成不同结构的ZIFs。ZIFs的合成方法包括溶剂热法、水热法、液相扩散法、胶体化学法、微波合成法和超声法等,本文综述了ZIFs材料的多种优异性能,介绍了近些年来ZIFs材料在选择性气体吸附/分离、催化反应、光学、磁性材料及其他方面的应用。最后对合成新型的ZIFs材料,并将该ZIFs材料应用在电子设备、能源利用以及环境保护等方面进行了展望。

关键词: 类沸石咪唑酯骨架材料, 合成, 气体选择性吸附, 催化

Abstract: Zeoliticimidazolate frameworks (ZIFs) are a new class of MOFs materials, characterized by porous crystalline and topology structure which is formed through the complexation of N atom in imidazole ring with divalent transition metal ions. Different ZIFs structures could be obtained through the modulation of the interaction between the ligands. The synthesis methods include solvothermal method, hydrothermal method, liquid phase diffusion method, colloid chemical method, microwave synthesis method, and ultrasonic method, etc. Recent studies on the excellent performances and the applications of ZIFs materials were reviewed in this paper. Specially, their applications, such as selective adsorption/separation of gas, catalytic reaction, optics, magnetic materials and other areas, were introduced in detail. In the end, the synthesis of novel ZIFs materials as well as their potential applications in electronic equipment, energy utilization and environment protection in the future is prospected.

Key words: zeoliticimidazolate frameworks, synthesis, selective adsorption of gas, catalysis

中图分类号:

O63
TB383

王天龙, 张燕, 王新红, 冯钠, 曲敏杰. 类沸石咪唑酯骨架材料(ZIFs)的研究进展[J]. 化工进展, 2015, 34(11): 3959-3964,3978.

WANG Tianlong, ZHANG Yan, WANG Xinhong, FENG Na, QU Minjie. Research progress in zeoliticimidazolate frameworks(ZIFs)[J]. Chemical Industry and Engineering Progree, 2015, 34(11): 3959-3964,3978.

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