柱芳烃合成及应用研究进展

doi:10.16085/j.issn.1000-6613.2015.09.010

摘要/Abstract

摘要： 柱芳烃是一类结构对称、由对苯二酚或对苯二酚醚通过亚甲基对位桥联的新型“柱”状大环低聚超分子主体化合物。本文主要回顾了烷氧基柱芳烃、水溶性柱芳烃、两亲性柱芳烃的合成发展过程,介绍了柱芳烃的结构与构象,柱芳烃及其衍生物的主客体化学,阐述了它们在构筑超分子自组装体系、医药、生物、相转移催化方面的应用研究进展。目前,柱[5,6]芳烃的合成方法已经比较成熟,而高阶柱芳烃的合成仍有待进一步改善,同时,随着研究的不断深入,柱芳烃及其衍生物将有望用于催化、生物模拟、石油化工等更广泛的领域。

关键词: 柱芳烃, 超分子, 合成, 分子识别, 自组装

Abstract: Pillararene is a kind of new “column” macrocyclic supramolecular polymer with symmetrical structure. It is formed by hydroquinone or hydroquinone ether para-bridged by methylene. In this paper,it is aimed to review progress in the synthesis of alkoxy,water-soluble and amphipathic pillararene,to introduce the structure and conformation of pillararene,the host-guest properties of pillararene and their derivatives,to elaborate the application progress of pillararenes in the field of supramolecular self-assembly,medicine,biology and phase transfer catalytic aspects. So far,the synthesis method of pillar[5,6]arene has been well established,while the high-level pillararene needs to improve. Meanwhile,with the deepening of research,pillararene and their derivatives are expected to be used in the areas of catalysis,biologic simulation,and petrochemistry.

Key words: pillararenes, supramolecular, synthesis, molecular recognition, self-assembly

中图分类号:

O641.3

卜婷婷, 崔娜, 朱丽君, 周玉路, 项玉芝, 夏道宏. 柱芳烃合成及应用研究进展[J]. 化工进展, 2015, 34(09): 3267-3278.

BU Tingting, CUI Na, ZHU Lijun, ZHOU Yulu, XIANG Yuzhi, XIA Daohong. Progress in the synthesis and application of pillar[n]arene[J]. Chemical Industry and Engineering Progree, 2015, 34(09): 3267-3278.

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