表面增强拉曼散射基底的研究进展

doi:10.16085/j.issn.1000-6613.2015.05.023

摘要/Abstract

摘要： 表面增强拉曼光谱(SERS)由于其高的灵敏度、抗干扰能力强等优点,被广泛应用在表面科学、分析化学、物理学等领域,是研究表面和界面过程的重要工具,是定性鉴定化学组成相近化合物的有力手段.因此,高品质、高活性的SERS基底一直是科研工作者们追求和研究的重点.本文对SERS活性基底的发展进行了介绍,从金、银金属纳米粒子作为基底的拉曼效应的科学研究,又进一步总结了非金属纳米粒子ZnO、TiO₂、ZnS、Cu₂O、CdTe、CdS等SERS基底.今后,将贵金属与半导体纳米材料复合将是SERS基底的研究热点.SERS光谱目前可以在液相色谱分析的检测器、医学检测仪器、刑侦分析检测等众多领域得到应用.

关键词: 表面增强拉曼光谱, 纳米材料, 金属基底, 非金属基底

Abstract: Due to its high sensitivity and strong anti-jamming ability,surface-enhanced Raman spectroscopy (SERS) is widely used in surface science,analytical chemistry,physics and other fields,and is a powerful tool for qualitative identification of compounds with similar chemical composition. Therefore,SERS substrates with high-quality and high-activity have always been a focus of researchers. Gold and silver metallic nano-particles based on the Raman effect were first introduced; and non-metallic nanoparticle,ZnO,TiO₂,ZnS,Cu₂O,CdTe,CdS etc,as surface-enhanced Raman substrate were then summarized in terms of the SERS signal enhancement. Surface-enhanced Roman spectroscopic is currently applied in the liquid phase chromatographic detectors,medical instrumentation,forensic analysis and testing,and many other fields. In the future,the substrates of the complex of metal/semiconductor materials shall be focused on.

Key words: surface enhanced raman spectroscopy, nanomaterials, metal substrates, non-metal substrates

中图分类号:

薛向欣, 许东铎, 常立民. 表面增强拉曼散射基底的研究进展[J]. 化工进展, 2015, 34(05): 1317-1322.

XUE Xiangxin, XU Dongduo, CHANG Limin. Review on surface enhanced Raman scattering substrates[J]. Chemical Industry and Engineering Progree, 2015, 34(05): 1317-1322.

参考文献

[1] Cialla D,Maerz A,Boehme R,et al. Surface-enhanced Raman spectroscopy (SERS):Progress and trends[J]. Anal. Bioanal. Chem.,2012,403:27-54.

[2] Han X X,Zhao B,Ozaki Y. Surface-enhanced raman scattering for protein detection[J]. Anal. Bioanal. Chem.,2009,394:1719-1727.

[3] Yui H. Electron-enhanced Raman scattering:A history of its discovery and spectroscopic applications to solution and interfacial chemistry[J]. Anal. Bioanal. Chem.,2010,397:1181-1190.

[4] Ren B,Liu G K,Lian X B,et al. Raman spectroscopy on transition metals[J]. Anal. Bioanal. Chem.,2007,388:29-45.

[5] Santaram Chilukuri. Dicke superradiance and stimulated electronic raman scattering of indium[J]. Physical Review A:Atomic Molecular and Optical Physics,1996,54:908-916.

[6] Anh T,Nguyen T T,Shankar C,et al. Plasmonic and sers properties for Ag@Au and Au@Ag core@shell nanoparticles as a function of the size and structure[J]. Abstracts of Papers of the American Chemical Society,2011,6:242-248.

[7] Hayashi S,Koh R,Yamamoto K,et al. Evidence for surface-enhanced raman scattering on nonmetallic surfaces:Copper phthalocyanine molecules on GaP small particles[J]. Phys. Rev. Lett.,1988,60:1085-1088.

[8] Marshall C D,Korenowski G M. AgCl-Ag cluster enhanced optical second harmonic generation from an electrode surface[J]. J. Chem. Phys.,1986,7:4172-4180.

[9] Quagliano L G.. Surface enhanced Raman scattering to study surface contaminants on semiconductors[J]. Surf. Sci.,2004,566:875-879.

[10] Wang X Q,Wen H,He T J,et al. Enhancement mechanism of sers from cyanine dyes adsorbed on Ag₂O colloids[J]. Spectrochimica Acta. Part A:Molecular and Biomolecular Spectroscopy,1997,53:2495-2504.

[11] Wang Y F,Sun Z H,Hu H L,et al. Raman scattering study of molecules adsorbed on ZnS nanocrystals[J]. J. Raman. Spec.,2007,38:34-38.

[12] Chen L,Seo H K,Mao Z,et al. Tunable plasmon properties of Fe₂O₃@Ag substrate for surface-enhanced raman scattering[J]. Anal.Methods,2011,3:1622-1627.

[13] Huang J M,Sun Y H,Huang S H,et al. Crystal engineering and sers properties of Ag-Fe₃O₄ nanohybrids:From heterodimer to core-shell nanostructures[J]. J. Mater. Chem.,2011,21:17930-17937.

[14] Wang Y F,Hu H L,Jing S Y,et al. Enhanced raman scattering as a probe for 4-mercaptopyridine surface-modified copper oxide nanocrystals[J]. Aanl. Sci.,2007,23:787-791.

[15] Wang Y X,Song W,Yang J X,et al. Surface enhanced raman scattering on Cu₂O/Ag composite[J]. Chem. J. Chinese. U,2011,32:1789-1793.

[16] Wang Y F,Zhang J H,Jia H Y,et al. Mercaptopyridine surface-functionalized CdTe quantum dots with enhanced raman scattering properties[J]. J. Phys. Chem. C,2008,112:996-1000.

[17] John R L,Ronald L B. Theory of surface-enhanced raman scattering in semiconductors[J]. J. Phys. Chem. C,2014,118:11120-11130.

[18] Wei J,Yue W,Ichiro T,et al. Semiconductor-drive“turn-off” surface-enhanced raman scattering spectroscopy:Application in selective determination of chromium(Ⅵ) in water[J]. Chem. Sci.,2015,6:342-348.

[19] Alessio P,Saez J A D,Aroca R F,et al. Metal-organic semiconductor nanostructures for surface-enhanced raman scattering[J]. Appl. Spectrosc.,2011,65:152-158.

[20] Chen W P,Chen Y C,Shao F S. Evolution of complete proteomes:Guanine-cytosine pressure,phylogeny and environmental influences blend the proteomic architecture[J]. BMC Evol. Biol.,2013,13:1-15.

[21] Gu X F,Yan Y R,Jiang G Q,et al. Using a silver-enhanced microarray sandwich structure to improve SERS sensitivity for protein detection[J]. Anal. Bioanal. Chem.,2014,406:1885-1893.

[22] Fleischmann M,Hill I,Robinson R J. Surface-enhnaced raman scattering from silver electrodes:Potencial and cation dependences of the very-low-frequency mode[J]. Chem. Phys. Lett.,1974,97:441-445.

[23] Jeanmaire D L,Van Duyne R P. Surface raman spectroelectrochemistry. Part 1. Heterocyclic,Aromatic,and aliphatic-amines adsorbed on anodized silver electrode[J]. J. Electroanal. Chem.,1977,84:1-20.

[24] Lombardi J R,Birke R L. A unified approach to surface-enhanced raman spectroscopy[J]. J. Phys. Chem. C,2008,112:5605-5617.

[25] Stiles P L,Dieringer J A,Shah N C,et al. Surface-enhanced raman spectroscopy[J]. Anal. Chem.,2008,1:601-609.

[26] Chen X,Hu Y J,Gao J,et al. Interaction of melamine molecules with silver nanoparticles explored by surface-enhanced raman scattering and density functional theory calculations[J]. Appl.Spectrosc.,2013,67:491-497.

[27] Muniz-Miranda M. SERS monitoring of the catalytic reduction of 4-nitrophenol on Ag-doped titania nanoparticles[J]. Appl.Catal. B,2014,146:147-155.

[28] Hong S,Li X. One step surface modification of gold nanoparticles for surface-enhanced Raman spectroscopy[J]. Appl. Surf. Sci.,2013,287:318-324.

[29] Pristinski D,Tan S L,Erol M,et al. In situ SERS study of Rhodamine 6G adsorbed on individually immobilized Ag nanoparticles[J]. J. Raman. Spec.,2006,37:762-770.

[30] Schluecker S. SERS Microscopy:Nanoparticle probes and biomedical applications[J]. Chem. Phys. Chem.,2009,10:1344-1354.

[31] Amendola V,Scaramuzza S,Agnoli S,et al. Strong dependence of surface plasmon resonance and surface enhanced Raman scattering on the composition of Au–Fe nanoalloys[J]. Nanoscale,2014,6:1423-1433.

[32] Chen Y Y,Cheng H W,Tram K,et al. A paper-based surface-enhanced resonance raman spectroscopic (SERRS) immunoassay using magnetic separation and enzyme-catalyzed reaction[J]. Analyst,2013,138:2624-2631.

[33] Zhong Q L,Liu F M,Zou D W,et al. 硫脲在HNO₃介质中吸附行为的拉曼光谱研究[J]. Chem. J. Chinese U,1998,19:1640-1644.

[34] Wallace D,Quinn E J,Armstrong D R,et al. Surface science of soft scorpionates[J]. Inorg. Chem.,2010,49:1420-1426.

[35] Li J W,Bai Y,Mo Y J,et al. Calculation of the SERS enhancement factors of pyridine molecules adsorbed on the substrates of Fe,Co and Ni using antenna resonace model[J]. Anal.,2006,26:463-466.

[36] Xue X X,Ji W,Mao Z,et al. Raman investigation of nanosized TiO₂:Effect of crystallite size and quantum confinement[J]. J. Phys.Chem.C,2012,116:8792-8797.

[37] Xue X X,Ji W,Mao Z,et al. Simultaneous enhancement of phonons modes with molecular vibrations due to Mg doping of a TiO₂ substrate[J]. RSC Advances,2013,3:20891-20895.

[38] Zhang P,Wang P,Chuang Y C. Depolarization ratios of resonance raman scattering in the gas phase[J]. J. Chem. Phys.,1989,90:4125-4143.

[39] Dolata A,Kudelski W,Grochala M,et al. Surface-enhanced raman scattering (SERS) at copper(I) oxide[J]. J. Raman Spec.,1998,29:431-435.

[40] Wang X Q,Xiao Y J,Gao X X. Surface-enhanced near-infrared raman spectroscopy of nicotinamide adenine dinucleotides on a gold electrode[J]. J. Electronal. Chem.,1997,433:49-56.

[41] Ling X,Xie L M,Fang Y,et al. Can graphene be used as a substrate for raman enhancement?[J]. Nano Letters,2010,10:553-561.

[42] Xie L M,Ling X,Fang Y,et al. Graphene as a substrate to suppress fluorescence in resonance raman spectroscopy[J]. JACS,2009,131:9890-9891.

[43] Gao L B,Ren W C,Liu B L,et al. Surface and interference coenhanced raman scattering of graphene[J]. ACS Nano.,2009,3:933-939.

[44] Huang J,Zhang L M,Chen B A,et al. Nanocomposites of size-controlled gold nanoparticles and graphene oxide:Formation and applications in sers and catalysis[J]. Nanoscale,2010,2:2733-2738.

[45] Novoselov K S,Geim A K,Morozov S V,et al. Electric field effect in atomically thin carbon films[J]. Science,2004,306:666-669.

[46] Stankovich S,Dikin,Dmitriy A,et al. Graphene-based composite materials[J]. Nature,2006,442:282-286.

[47] 乔玉林,赵海朝,臧艳,等. 石墨烯的功能化修饰及作为润滑添加剂的应用研究进展[J]. 化工进展,2014,33（s1）:216-223.

[48] Chuang K H,Lu C Y,Wey M Y. Effects of microwave power and polyvinyl pyrrolidone on microwave polyol process of carbon-supported Cu catalysts for CO oxidation[J]. Mater. Sci. Eng. B,2011,176:745-749.

[49] Qi J W,Li Y D,Yang M,et al. Fabrication of nanowire network AAO and its application in sers[J]. Nanoscale Rec. Lett.,2013,8:495-499.