Preparation and CO2 adsorption performance of metal-organic framework composites

doi:10.16085/j.issn.1000-6613.2016.09.032

Abstract

Abstract: Composites of HKUST-1,MIL-101,UiO-66 with hydroxyl group functionalized siliceous mesocellular foam(MCF-OH) were prepared by in-situ hydrothermal method,and the materials were characterized by means of PXRD,SEM,N2 adsorption,XPS,TGA measurements,and CO₂ adsorption performance was measured at 298K. It was found that the morphologies of MOFs were different because of the different central metals in MOFs. For the HKUST-1^#MOF-OH composite,MCF-OH directed the growth of HKUST-1 on MCF-OH surfaces,new mesopores was formed on the interface between HKUST-1 crystal and MCF-OH and its pore size was closer to the kinetic diameter of CO₂ than that of pure HKUST-1. For other composites,the growth of MOFs crystal particles was hindered, leading to smaller MOFs crystal particles and higher BET surface areas than the pure MOFs. All the composites showed higher CO₂ adsorption capacities than pure MOFs,and because of the decreased micropore sizes and the introduction of new mesoporous structure,the HKUST-1^#MCF-OH composite has the most increment of CO₂ capacity among all the composites.

Key words: CO₂ capture, adsorption, metal-organic framework, siliceous mesocellular foam, composites

摘要： 通过原位溶剂热法分别合成了HKUST-1、MIL-101、UiO-66与羟基化介孔氧化硅泡沫（MCF-OH）的复合物，并对材料进行了PXRD、SEM、低温N2吸-脱附、XPS、TGA表征及298K下的CO₂吸附测试。结果显示：3种复合材料中都形成了对应MOFs的晶型结构，但由于各类MOFs金属中心的不同，MCF-OH对MOFs的形貌产生了不同的影响。其中，HKUST-1^#MOF-OH复合材料中MCF-OH的加入对HKUST-1的生长起到了导向作用，在两者界面间形成了新的介孔结构，并且其微孔孔径尺寸更接近CO₂的动力学直径。另外两种复合材料中MCF-OH的加入主要对其MOFs晶型颗粒的生长起到了限制作用，使其晶型颗粒尺寸减小，从而带来了比表面积的增加。3种复合材料的CO₂吸附量都较纯MOFs材料有所提高，并且由于HKUST-1^#MOF-OH复合材料中微孔孔径尺寸的减小以及新的介孔结构的引入使其对CO₂的吸附更加高效，因此其较纯MOFs材料的吸附性能提升效果最为明显。

关键词: 二氧化碳捕集, 吸附（作用）, 金属有机骨架材料, 介孔氧化硅泡沫, 复合材料

CLC Number:

O614

ZHU Chenming, WANG Baodeng, ZHANG Zhongzheng, WANG Hui, ZHANG Haijiao, SUN Nannan, WEI Wei, SUN Yuhan. Preparation and CO₂ adsorption performance of metal-organic framework composites[J]. Chemical Industry and Engineering Progress, 2016, 35(09): 2875-2884.

朱晨明, 王保登, 张中正, 王慧, 张海娇, 孙楠楠, 魏伟, 孙予罕. 金属-有机骨架复合材料的制备及其二氧化碳吸附性能[J]. 化工进展, 2016, 35(09): 2875-2884.

References

[1] ORR F M. CO₂ capture and storage:are we ready?[J]. Energy Environ. Sci,2009,2(5):449-458.

[2] SANZ R,CALLEJA G,ARENCIBIA A,et al. Development of high efficiency adsorbents for CO₂ capture based on a double-functionalization method of grafting and impregnation[J]. J. Mater. Chem. A,2013,1(6):1956-1962.

[3] BAI R Z,YANG M L,HU G S,et al. A new nanoporous nitrogen-doped highly-efficient carbonaceous CO₂ sorbent synthesized with inexpensive urea and petroleum coke[J]. Carbon, 2015,81:465-473.

[4] SAYARI A,BELMABKHOUTA Y,SEMA-GUERREROB R. Flue gas treatment via CO₂ adsorption[J]. Chem. Eng. J.,2011,171(3):760-774.

[5] HEDIN N,CHEN L J,LAAKSONEN A. Sorbents for CO₂ capture from flue gas-aspects from materials and theoretical chemistry[J]. Nanoscale,2010,2(10):1819-1841.

[6] LIU J,THALLAPALLY P K,MCGRAILl B P,et al. Progress in adsorption-based CO₂ capture by metal-organic frameworks[J]. Chem. Soc. Rev.,2012,41(6):2308-2322.

[7] LI J M,YANG J F,LI L B,et al. Separation of CO₂/CH₄ and CH₄/N₂ mixtures using MOF-5 and Cu₃(BTC)₂[J]. J. Energy Chem.,2014, 23(4):453-460.

[8] CHEN B,WANG X J,ZHANG Q F,et al. Synthesis and characterization of the interpenetrated MOF-5[J]. J. Mater. Chem., 2010,20(18):3758-3767.

[9] MCEWEN J,HAYMAN J D,YAZAYDIN A O. A comparative study of CO₂,CH₄ and N₂ adsorption in ZIF-8,Zeolite-13X and BPL activated carbon[J]. Chem. Phys.,2012,412:72-76.

[10] CHMELIKA C,BATEN J V,KRISHNA R. Hindering effects in diffusion of CO₂/CH₄ mixtures in ZIF-8 crystals[J]. J. Membr. Sci., 2012,397:87-91.

[11] COUCK S, DENAYER J F, BARON G V, et al. An amine-functionalized MIL-53 metal-organic framework with large separation power for CO₂ and CH₄[J]. J. Am. Chem. Soc.,2009,131(18):6326-6327.

[12] YAN Q J,LIN Y C,KONG C L,et al. Remarkable CO₂/CH₄ selectivity and CO₂ adsorption capacity exhibited by polyamine-decorated metal-organic framework adsorbents[J]. Chem. Commun.,2013,49(61):6873-6875.

[13] ABID H R,TIAN H Y,ANG H M,et al. Nanosize Zr-metal organic framework (UiO-66) for hydrogen and carbon dioxide storage[J]. Chem. Eng. J.,2012,187:415-420.

[14] CHAEMCHUEN S,KABIR N A,ZHOU K,et al. Metal-organic frameworks for upgrading biogas via CO₂ adsorption to biogas green energy[J]. Chem. Soc. Rev.,2013,42(24):9304-9332.

[15] CHUI S,LO S,CHARMANT J,et al. A chemically functionalizable nanoporous material[Cu₃(TMA)₂(H₂O)₃]_n[J]. Science,1999,283(5405):1148-1150.

[16] YE S,JIANG X,RUAN L W,et al. Post-combustion CO₂ capture with the HKUST-1 and MIL-101(Cr) metal-organic frameworks:adsorption, separation and regeneration investigations[J]. Microporous Mesoporous Mater.,2013,179:191-197.

[17] YAN X L,KOMARNENI S,ZHANG Z Q,et al. Extremely enhanced CO₂ uptake by HKUST-1 metal-organic framework via a simple chemical treatment[J]. Microporous Mesoporous Mater., 2014,183:69-73.

[18] ZHU Q L,XU Q. Metal-organic framework composites[J]. Chem. Soc. Rev.,2014,43(16):5468-5512.

[19] RALLAPALLI P B,RAJ M C,PATIL D V,et al. Activated carbon@MIL-101(Cr):a potential metal-organic framework composite material for hydrogen storage[J]. Int. J. Energy Res.,2013,37(7):746-753.

[20] XIANG Z H,PENG X,CHENG X,et al. CNT@Cu₃(BTC)₂ and metal-organic frameworks for separation of CO₂/CH₄ mixture[J]. J. Phys. Chem. C,2011,115(40):19864-19871.

[21] YANG S J,CHOI J Y,CHAE H K,et al. Preparation and enhanced hydrostability and hydrogen storage capacity of CNT@MOF-5 hybrid composite[J].Chem. Mater. 2009,21(9):1893-1897.

[22] ZHAO Y X,SEREDYCH M,ZHONG Q,et al. Aminated graphite oxides and their composites with copper-based metal-organic framework:in search for efficient media for CO₂ sequestration[J]. RSC Adv.,2013,3(25):9932-9941.

[23] ZHAO Y X, SEREDYCH M, ZHONG Q, et al. Superior performance of copper based MOF and aminated graphite oxide composites as CO₂ adsorbents at room temperature[J]. ACS Appl. Mater. Interfaces,2013,5(11):4951-4959.

[24] PETIT C,BANDOSZ T J. Engineering the surface of a new class of adsorbents:metal-organic framework/graphite oxide composites[J]. J. Colloid Interface Sci.,2015,447:139-151.

[25] ZHAO Y X,SEREDYCH M,JAGIELLO J,et al. Insight into the mechanism of CO₂ adsorption on Cu-BTC and its composites with graphite oxide or aminated graphite oxide[J]. Chem. Eng. J.,2014, 239:399-407.

[26] ZLOTEA C,CAMPESI R,CUEVAS F,et al. Pd Nanoparticles embedded into a metal-organic framework:synthesis,structural characteristics,and hydrogen sorption properties[J]. J. Am. Chem. Soc.,2010,132(9):2991-2997.

[27] AIJAZ A,KARKAMKAR A,CHOI Y J,et al. Immobilizing highly catalytically active Pt nanoparticles inside the pores of metal-organic framework:A double solvents approach[J]. J. Am. Chem. Soc., 2012,134(34:):13926-13929.

[28] ZHANG T,ZHANG X F,YAN X J,et al. Synthesis of Fe₃O₄@ZIF-8 magnetic core-shell microspheres and their potential application in a capillary microreactor[J]. Chem. Eng. J.,2013,228:398-404.

[29] ZHAN W W, KUANG Q, ZHOU J Z, et al. Semiconductor@metal-organic framework core-shell heterostructures:a case of ZnO@ZIF-8 nanorods with selective photoelectrochemical response[J]. J. Am. Chem. Soc.,2013,135(5):1926-1933.

[30] CAVKA J H,JAKOBSEN S,OLSBYE U,et al. A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability[J]. J. Am. Chem. Soc.,2008,130(42):13850-13851.

[31] KUMAR R S,KUMAR S S,KULANDAINATHAN M A. Efficient electrosynthesis of highly active Cu₃(BTC)₂-MOF and its catalytic application to chemical reduction[J]. Microporous Mesoporous Mater.,2013,168:57-64.

[32] LUO Q X,SONG X D,JIA M,et al. Molecular size-and shape-selective Knoevenagel condensation overmicroporous Cu₃(BTC)₂ immobilized amino-functionalized basic ionicliquid catalyst[J]. Appl. Catal. A-Gen.,2014,478:81-90.

[33] CHIERICATTI C,BASILICO J C,BASILICO M L,et al. Novel application of HKUST-1 metal-organic framework as antifungal:biological tests and physicochemical characterizations[J]. Microporous Mesoporous Mater.,2012,162:60-63.

Preparation and CO₂ adsorption performance of metal-organic framework composites

金属-有机骨架复合材料的制备及其二氧化碳吸附性能

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