Research progress of non-noble metal bifunctional catalysts in zinc-air batteries

doi:10.16085/j.issn.1000-6613.2023-0423

Abstract

Abstract:

The slow kinetics of oxygen reduction reaction (ORR) and oxygen reduction reaction (OER) at air cathode restricts the further development of zinc-air battery. Precious metal catalysts have high catalytic activity, but the high cost and poor stability limit their further application. These challenges can be effectively overcome by developing highly active, low-cost non-precious metal bifunctional catalysts. After the introduction of the structure and properties of Zn-air batteries, this review systematically introduces the research progress of different types of non-precious metal catalysts in Zn-air batteries, such as MOF-derived bifunctional catalysts, non-metallic bifunctional catalysts and transition metal bifunctional catalysts. The advantages and disadvantages of different types of catalysts are introduced, and the catalytic activity centers and electrochemical properties of the catalysts are explained. Finally, the addition of metal active sites and the modulation of the morphological structure of specific catalysts are pointed out as research priorities in this field, and measures to be taken in the characterization, performance modulation and cell optimization of zinc-air batteries are suggested.

Key words: electrochemistry, catalyst, composites, oxidation, zinc-air battery

摘要：

基于氧还原反应（ORR）和氧析出反应（OER）的锌空气电池空气阴极动力学缓慢，制约了锌空气电池的进一步发展。贵金属催化剂具有高催化活性，但成本高、稳定性差等问题限制了其进一步应用。通过开发高活性、低成本非贵金属双功能催化剂能够有效解决上述问题。本文在介绍锌空气电池的结构和性质的基础上，系统介绍了不同种类的非贵金属催化剂在锌空气电池中的研究进展，如MOF衍生的双功能催化剂、非金属双功能催化剂、过渡金属双功能催化剂等，介绍了不同种类催化剂的优缺点，并对催化剂的催化活性中心和电化学性质进行阐述。最后，进一步指出对特定催化剂金属活性位点的增加和形貌结构的调控是该领域的研究重点，并提出了锌空气电池在表征方式、性能调控和优化电池中应采取的措施。

关键词: 电化学, 催化剂, 复合材料, 氧化, 锌空气电池

CLC Number:

ZHANG Mingyan, LIU Yan, ZHANG Xueting, LIU Yake, LI Congju, ZHANG Xiuling. Research progress of non-noble metal bifunctional catalysts in zinc-air batteries[J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 276-286.

张明焱, 刘燕, 张雪婷, 刘亚科, 李从举, 张秀玲. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286.

Figures/Tables 4

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