Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (5): 2371-2389.DOI: 10.16085/j.issn.1000-6613.2022-1204
• Industrial catalysis • Previous Articles Next Articles
WANG Zijian(), KE Ming(), SONG Zhaozheng, LI Jiahan, TONG Yanbing, SUN Jinru
Received:
2022-06-28
Revised:
2022-09-18
Online:
2023-06-02
Published:
2023-05-10
Contact:
KE Ming
王子健(), 柯明(), 宋昭峥, 李佳涵, 童燕兵, 孙巾茹
通讯作者:
柯明
作者简介:
王子健(1995—),男,博士研究生,研究方向为化学工程与工艺和能量系统优化。E-mail:757496137@qq.com。
基金资助:
CLC Number:
WANG Zijian, KE Ming, SONG Zhaozheng, LI Jiahan, TONG Yanbing, SUN Jinru. Progress in alkylation of gasoline with molecular sieve catalyst for benzene reduction[J]. Chemical Industry and Engineering Progress, 2023, 42(5): 2371-2389.
王子健, 柯明, 宋昭峥, 李佳涵, 童燕兵, 孙巾茹. 分子筛催化汽油烷基化降苯技术研究进展[J]. 化工进展, 2023, 42(5): 2371-2389.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-1204
专利公司 | 年份 | 催化剂类型 | 苯含量 (质量分数) | 反应温度 | 反应压力 | 汽油甲醇比例 | 空速 | 降苯率 |
---|---|---|---|---|---|---|---|---|
催化蒸馏技术公司(美国)[ | 2011 | ZSM-5、β等 | — | 93~371℃ | 1.4MPa(实例) | 醇苯摩尔比(0.1~10)∶1 | — | 降至质量分数小于0.25%(轻馏分) |
长岭石化科技开发有限公司[ | 2009 | ZSM-5、Y | 20%~60% | 380~450℃ | 0.1~0.6MPa | 质量比(0.4~1)∶1 | 0.3~1.5h-1 | >80%(质量分数) |
中石化①和石科院②[ | 2012 | 中孔、大孔分子筛 | >0.5% | 250~550℃ (第一反应区) | 0.2~0.6MPa | 质量比(1~100)∶1(第一反应区) | — | >65%(体积分数) |
中石化和洛阳院③[ | 2014 | ZSM-5、Y以及β | 10%~50% | 300~375℃ | 0.8~3.0MPa | 质量比(2~10)∶1 | 1.0~5.0h-1 | >75%(质量分数) |
中石油[ | 2018 | ZSM-5、MCM-56以及β | 38.1% (实例) | 300~500℃ | 0.5~3.0MPa | 甲醇∶苯(0.5~2)∶1(摩尔比) | 6~10h-1 | >50%(摩尔分数) |
科创石化科技开发有限公司[ | 2020 | ZSM-5 | 20.5% (实例) | — | 0.6~1.2MPa (表压)(实例) | 乙烯∶苯∶甲醇1∶4∶1(摩尔比)(实例) | — | >97%(质量分数)(实例) |
专利公司 | 年份 | 催化剂类型 | 苯含量 (质量分数) | 反应温度 | 反应压力 | 汽油甲醇比例 | 空速 | 降苯率 |
---|---|---|---|---|---|---|---|---|
催化蒸馏技术公司(美国)[ | 2011 | ZSM-5、β等 | — | 93~371℃ | 1.4MPa(实例) | 醇苯摩尔比(0.1~10)∶1 | — | 降至质量分数小于0.25%(轻馏分) |
长岭石化科技开发有限公司[ | 2009 | ZSM-5、Y | 20%~60% | 380~450℃ | 0.1~0.6MPa | 质量比(0.4~1)∶1 | 0.3~1.5h-1 | >80%(质量分数) |
中石化①和石科院②[ | 2012 | 中孔、大孔分子筛 | >0.5% | 250~550℃ (第一反应区) | 0.2~0.6MPa | 质量比(1~100)∶1(第一反应区) | — | >65%(体积分数) |
中石化和洛阳院③[ | 2014 | ZSM-5、Y以及β | 10%~50% | 300~375℃ | 0.8~3.0MPa | 质量比(2~10)∶1 | 1.0~5.0h-1 | >75%(质量分数) |
中石油[ | 2018 | ZSM-5、MCM-56以及β | 38.1% (实例) | 300~500℃ | 0.5~3.0MPa | 甲醇∶苯(0.5~2)∶1(摩尔比) | 6~10h-1 | >50%(摩尔分数) |
科创石化科技开发有限公司[ | 2020 | ZSM-5 | 20.5% (实例) | — | 0.6~1.2MPa (表压)(实例) | 乙烯∶苯∶甲醇1∶4∶1(摩尔比)(实例) | — | >97%(质量分数)(实例) |
专利公司 | 年份 | 催化剂类型 | 反应温度 | 反应压力 | 烷基化试剂 | 降苯率 |
---|---|---|---|---|---|---|
Mobil[ | 1989 | ZSM-5 | 316~399℃ | 0.79~0.83MPa | C4-烯烃 | — |
Mobil[ | 1994 | ZSM-5 | 260~538℃ | 0.35~21MPa | C2~C5烯烃 | >40%(质量分数) |
Mobil[ | 1996 | ZSM-5 | 260~538℃ | 0.35~21MPa | C5+烯烃 | >25%(质量分数) |
EMRE[ | 2006 | MCM-22 | 150~350℃ | <7MPa | C2~C4烯烃 | — |
EMRE[ | 2010 | MCM-22 | <300℃ | >2.5MPa(表压) | 烯烃(质量分数>50%丙烯) | >90% |
贝吉尔技术许可公司[ | 2021 | Beta、Y以及MCM-22 | 50~300℃ | 0.1~15MPa | C5+烯烃 | — |
中石化和抚研院[ | 2004 | ZSM-5、Beta | 340~440℃ | 2.5~4.5MPa | FCC汽油烯烃 | 降至1.5%(体积分数) |
中石化和石科院[ | 2009 | Y | 250~550℃ | 0.1~1.0MPa | 干气、液化气 | >50%(体积分数) |
中科院大连化物所[ | 2009 | ZSM-5/ZSM-11共晶 | 300~450℃ | 0.2~1.5MPa | 干气、乙烯厂尾气 | >45% |
中石化和石科院[ | 2012 | ZSM-5、MCM-22以及Beta等 | 100~300℃ | 0.1~6.0MPa | C2~C4烯烃 | — |
专利公司 | 年份 | 催化剂类型 | 反应温度 | 反应压力 | 烷基化试剂 | 降苯率 |
---|---|---|---|---|---|---|
Mobil[ | 1989 | ZSM-5 | 316~399℃ | 0.79~0.83MPa | C4-烯烃 | — |
Mobil[ | 1994 | ZSM-5 | 260~538℃ | 0.35~21MPa | C2~C5烯烃 | >40%(质量分数) |
Mobil[ | 1996 | ZSM-5 | 260~538℃ | 0.35~21MPa | C5+烯烃 | >25%(质量分数) |
EMRE[ | 2006 | MCM-22 | 150~350℃ | <7MPa | C2~C4烯烃 | — |
EMRE[ | 2010 | MCM-22 | <300℃ | >2.5MPa(表压) | 烯烃(质量分数>50%丙烯) | >90% |
贝吉尔技术许可公司[ | 2021 | Beta、Y以及MCM-22 | 50~300℃ | 0.1~15MPa | C5+烯烃 | — |
中石化和抚研院[ | 2004 | ZSM-5、Beta | 340~440℃ | 2.5~4.5MPa | FCC汽油烯烃 | 降至1.5%(体积分数) |
中石化和石科院[ | 2009 | Y | 250~550℃ | 0.1~1.0MPa | 干气、液化气 | >50%(体积分数) |
中科院大连化物所[ | 2009 | ZSM-5/ZSM-11共晶 | 300~450℃ | 0.2~1.5MPa | 干气、乙烯厂尾气 | >45% |
中石化和石科院[ | 2012 | ZSM-5、MCM-22以及Beta等 | 100~300℃ | 0.1~6.0MPa | C2~C4烯烃 | — |
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