Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (11): 6064-6075.DOI: 10.16085/j.issn.1000-6613.2022-2370
• Resources and environmental engineering • Previous Articles
TIAN Yue(), DONG Xiaohan, SU Yi()
Received:
2022-12-28
Revised:
2023-02-19
Online:
2023-12-15
Published:
2023-11-20
Contact:
SU Yi
通讯作者:
苏毅
作者简介:
田月(1996—),女,硕士研究生,研究方向为资源综合利用。E-mail:1561388678@qq.com。
基金资助:
CLC Number:
TIAN Yue, DONG Xiaohan, SU Yi. Preparation of the SiO2-CTAB composite material and its adsorption properties for PNP[J]. Chemical Industry and Engineering Progress, 2023, 42(11): 6064-6075.
田月, 董晓涵, 苏毅. SiO2-CTAB复合材料的制备及其对PNP的吸附性能[J]. 化工进展, 2023, 42(11): 6064-6075.
Add to citation manager EndNote|Ris|BibTeX
URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-2370
项目 | SiO2 | CaO | MgO | P2O5 | Al2O3 | Fe2O3 | 氟化物 |
---|---|---|---|---|---|---|---|
黄磷炉渣 | 38.33 | 44.21 | 3.93 | 2.68 | 1.92 | 0.65 | 2.57 |
SiO2基体 | 89.90 | 0.18 | 0.16 | 0.69 | 0.50 | 0.36 | 0.26 |
项目 | SiO2 | CaO | MgO | P2O5 | Al2O3 | Fe2O3 | 氟化物 |
---|---|---|---|---|---|---|---|
黄磷炉渣 | 38.33 | 44.21 | 3.93 | 2.68 | 1.92 | 0.65 | 2.57 |
SiO2基体 | 89.90 | 0.18 | 0.16 | 0.69 | 0.50 | 0.36 | 0.26 |
模型 | C0/mg·L-1 | qe,exp/mg·g-1 | qe,cal/mg·g-1 | k1/min-1 | R2 |
---|---|---|---|---|---|
拟一级动力学 | 40 | 25.53 | 6.496 | 7.144×10-2 | 0.8576 |
60 | 37.86 | 11.69 | 6.134×10-2 | 0.8338 | |
80 | 49.93 | 10.97 | 5.706×10-2 | 0.8453 |
模型 | C0/mg·L-1 | qe,exp/mg·g-1 | qe,cal/mg·g-1 | k1/min-1 | R2 |
---|---|---|---|---|---|
拟一级动力学 | 40 | 25.53 | 6.496 | 7.144×10-2 | 0.8576 |
60 | 37.86 | 11.69 | 6.134×10-2 | 0.8338 | |
80 | 49.93 | 10.97 | 5.706×10-2 | 0.8453 |
模型 | C0/mg·L-1 | qe,exp/mg·g-1 | qe,cal/mg·g-1 | k2/g·mg-1·min-1 | R2 |
---|---|---|---|---|---|
拟二级动力学 | 40 | 25.53 | 25.68 | 1.363×10-1 | 0.9999 |
60 | 37.86 | 38.17 | 5.872×10-2 | 0.9999 | |
80 | 49.93 | 50.20 | 6.505×10-2 | 0.9999 |
模型 | C0/mg·L-1 | qe,exp/mg·g-1 | qe,cal/mg·g-1 | k2/g·mg-1·min-1 | R2 |
---|---|---|---|---|---|
拟二级动力学 | 40 | 25.53 | 25.68 | 1.363×10-1 | 0.9999 |
60 | 37.86 | 38.17 | 5.872×10-2 | 0.9999 | |
80 | 49.93 | 50.20 | 6.505×10-2 | 0.9999 |
模型 | C0/mg·L-1 | 阶段 | Kid/mg·g-1·min-0.5 | N/mg·g-1 | R2 |
---|---|---|---|---|---|
颗粒内扩散 | 40 | 1 | 9.484 | 9.938 | 0.9810 |
2 | 2.984×10-1 | 23.80 | 0.8565 | ||
60 | 1 | 17.40 | 8.286 | 0.9901 | |
2 | 6.246×10-1 | 34.18 | 0.8976 | ||
80 | 1 | 18.07 | 19.10 | 0.9715 | |
2 | 4.974×10-1 | 46.80 | 0.7797 |
模型 | C0/mg·L-1 | 阶段 | Kid/mg·g-1·min-0.5 | N/mg·g-1 | R2 |
---|---|---|---|---|---|
颗粒内扩散 | 40 | 1 | 9.484 | 9.938 | 0.9810 |
2 | 2.984×10-1 | 23.80 | 0.8565 | ||
60 | 1 | 17.40 | 8.286 | 0.9901 | |
2 | 6.246×10-1 | 34.18 | 0.8976 | ||
80 | 1 | 18.07 | 19.10 | 0.9715 | |
2 | 4.974×10-1 | 46.80 | 0.7797 |
T/℃ | 拟合方程 | qm/mg·g-1 | KL/L·mg-1 | RL | R2 |
---|---|---|---|---|---|
20 | y=0.0061x+0.1717 | 164.0 | 0.0355 | 0.0340~0.3602 | 0.9967 |
40 | y=0.0071x+0.2158 | 140.9 | 0.0329 | 0.0366~0.3781 | 0.9997 |
80 | y=0.0298x+1.6559 | 33.56 | 0.0180 | 0.0649~0.5264 | 0.9961 |
T/℃ | 拟合方程 | qm/mg·g-1 | KL/L·mg-1 | RL | R2 |
---|---|---|---|---|---|
20 | y=0.0061x+0.1717 | 164.0 | 0.0355 | 0.0340~0.3602 | 0.9967 |
40 | y=0.0071x+0.2158 | 140.9 | 0.0329 | 0.0366~0.3781 | 0.9997 |
80 | y=0.0298x+1.6559 | 33.56 | 0.0180 | 0.0649~0.5264 | 0.9961 |
T/℃ | 拟合方程 | KF | 1/a | R2 |
---|---|---|---|---|
20 | y=0.2792x+3.4273 | 30.80 | 0.2792 | 0.9520 |
40 | y=0.3198x+3.0461 | 21.03 | 0.3198 | 0.8846 |
80 | y=0.3176x+1.4819 | 4.401 | 0.3176 | 0.8535 |
T/℃ | 拟合方程 | KF | 1/a | R2 |
---|---|---|---|---|
20 | y=0.2792x+3.4273 | 30.80 | 0.2792 | 0.9520 |
40 | y=0.3198x+3.0461 | 21.03 | 0.3198 | 0.8846 |
80 | y=0.3176x+1.4819 | 4.401 | 0.3176 | 0.8535 |
T/K | KT | ΔGθ/J·mol-1 | ΔHθ/J·mol-1 | ΔSθ/J·mol-1·K-1 |
---|---|---|---|---|
293 | 4.942×103 | -20.72×103 | -10.16×103 | 36.63 |
313 | 4.577×103 | -21.93×103 | ||
353 | 2.503×103 | -22.97×103 |
T/K | KT | ΔGθ/J·mol-1 | ΔHθ/J·mol-1 | ΔSθ/J·mol-1·K-1 |
---|---|---|---|---|
293 | 4.942×103 | -20.72×103 | -10.16×103 | 36.63 |
313 | 4.577×103 | -21.93×103 | ||
353 | 2.503×103 | -22.97×103 |
样品 | 比表面积/m2·g-1 | Vt/cm3·g-1 | Da/nm |
---|---|---|---|
SiO2基体 | 519.2 | 0.7603 | 5.051 |
黄磷炉渣 | 1.307 | 6.683×10-3 | 34.35 |
样品 | 比表面积/m2·g-1 | Vt/cm3·g-1 | Da/nm |
---|---|---|---|
SiO2基体 | 519.2 | 0.7603 | 5.051 |
黄磷炉渣 | 1.307 | 6.683×10-3 | 34.35 |
项目 | C 1s | Si 2p | O 1s | |
---|---|---|---|---|
C—(C,H) | C—O—C | Si—O | O—Si | |
结合能/eV | 284.74 | 286.26 | 103.39 | 532.84 |
质量分数/% | 10.39 | 3.20 | 28.41 | 58.00 |
项目 | C 1s | Si 2p | O 1s | |
---|---|---|---|---|
C—(C,H) | C—O—C | Si—O | O—Si | |
结合能/eV | 284.74 | 286.26 | 103.39 | 532.84 |
质量分数/% | 10.39 | 3.20 | 28.41 | 58.00 |
项目 | C 1s | Si 2p | O 1s | N 1s | |||
---|---|---|---|---|---|---|---|
C—(C,H) | C—O—C | Si—O | O—Si | O—C | N—SiO2 | N—C | |
结合能/eV | 284.74 | 286.36 | 102.76 | 532.11 | 530.59 | 402.46 | 399.24 |
质量分数/% | 45.40 | 11.10 | 11.44 | 22.21 | 6.68 | 2.21 | 0.95 |
项目 | C 1s | Si 2p | O 1s | N 1s | |||
---|---|---|---|---|---|---|---|
C—(C,H) | C—O—C | Si—O | O—Si | O—C | N—SiO2 | N—C | |
结合能/eV | 284.74 | 286.36 | 102.76 | 532.11 | 530.59 | 402.46 | 399.24 |
质量分数/% | 45.40 | 11.10 | 11.44 | 22.21 | 6.68 | 2.21 | 0.95 |
1 | DIMITROVSKA Olgica, MARKOSKI Blagoja, TOSHEVSKA Biljana Apostolovska, et al. Surface water pollution of major rivers in the republic of macedonia[J]. Procedia Environmental Sciences, 2012, 14: 32-40. |
2 | ZHENG Zexiao, Irene MC LO. Multifunctional photoelectrochemical systems for coupled water treatment and high-value product generation: Current status, mechanisms, remaining challenges, and future opportunities[J]. Current Opinion in Chemical Engineering, 2021, 34: 100711. |
3 | PENG Xiaohui, WANG Ya, LUO Zhen, et al. Facile synthesis of fluorescent sulfur quantum dots for selective detection of p-nitrophenol in water samples[J]. Microchemical Journal, 2021, 170: 106735. |
4 | GERENT Giles G, SPINELLI Almir. Magnetite-platinum nanoparticles-modified glassy carbon electrode as electrochemical detector for nitrophenol isomers[J]. Journal of Hazardous Materials, 2017, 330: 105-115. |
5 | Ganga Ram Chaudhary, Singh Prabjot, Kaur Gurpreet, et al. Multifaceted approach for the fabrication of metallomicelles and metallic nanoparticles using solvophobic bisdodecylaminepalladium (Ⅱ) chloride as precursor[J]. Inorganic Chemistry, 2015, 54(18): 9002-9012. |
6 | NIU Baitong, LI Xinlou, LIN Da, et al. Highly efficient noble metal-free g-C3N4@Ni x Sy nanocomposites for catalytic reduction of nitrophenol, azo dyes and Cr( Ⅵ )[J]. Inorganic Chemistry Communications, 2022, 142: 109589. |
7 | YAN Kunyun, CHEN Jiayi, LI Xinyu, et al. Carboxylic acid enriched porous organic polymer as a platform for highly efficient removal of methylene blue from aqueous solution[J]. Macromolecular Chemistry and Physics, 2020, 221(5): 1900553. |
8 | 夏丞垚, 陈琼珍, 沈文静, 等. 对硝基苯酚的生物降解研究进展[J]. 生物加工过程, 2021, 19(4): 387-395. |
XIA Chengyao, CHEN Qiongzhen, SHEN Wenjing, et al. Advancement inmicrobial degradation of para-nitrophenol[J]. Chinese Journal of Bioprocess Engineering, 2021, 19(4): 387-395. | |
9 | YANG Xiupei, WANG Dan, LUO Na, et al. Green synthesis of fluorescent N, S-carbon dots from bamboo leaf and the interaction with nitrophenol compounds[J]. Spectrochimica Acta A, Molecular and Biomolecular Spectroscopy, 2020, 239: 118462. |
10 | ZHU Guodong, TANG Qian, HUANG Manhong, et al. Polyaniline nanoconical array on carbon nanofiber for supersensitive determination of nitrophenol[J]. Sensors and Actuators B: Chemical, 2020, 320: 128593. |
11 | HAO Xiaoyan, DIAO Xiaogao, YU Shengchen, et al. Nutrient digestibility, rumen microbial protein synthesis, and growth performance in sheep consuming rations containing sea buckthorn pomace[J]. Journal of Animal Science, 2018, 96(8): 3412-3419. |
12 | KAVLOCK R J, DASTON G P, DEROSA C, et al. Research needs for the risk assessment of health and environmental effects of endocrine disruptors: A report of the U.S. EPA-sponsored workshop[J]. Environmental Health Perspectives, 1996, 104(): 715-740. |
13 | KHATAMIAN M, KHANDAR A A, DIVBAND B, et al. Heterogeneous photocatalytic degradation of 4-nitrophenol in aqueous suspension by Ln (La3+, Nd3+ or Sm3+) doped ZnO nanoparticles[J]. Journal of Molecular Catalysis A: Chemical, 2012, 365: 120-127. |
14 | CLARK James H, FARMER Thomas J, Lorenzo HERRERO-DAVILA, et al. Circular economy design considerations for research and process development in the chemical sciences[J]. Green Chemistry, 2016, 18(14): 3914-3934. |
15 | SAMSAMI Shakiba, MOHAMADIZANIANI Maryam, SARRAFZADEH Mohammad-Hossein, et al. Recent advances in the treatment of dye-containing wastewater from textile industries: Overview and perspectives[J]. Process Safety and Environmental Protection, 2020, 143: 138-163. |
16 | WANG Xiaohong, JIANG Chenglong, HOU Bingxia, et al. Carbon composite lignin-based adsorbents for the adsorption of dyes[J]. Chemosphere, 2018, 206: 587-596. |
17 | ZHANG Ting, ZHOU Fa, HUANG Jianhan, et al. Ethylene glycol dimethacrylate modified hyper-cross-linked resins: Porogen effect on pore structure and adsorption performance[J]. Chemical Engineering Journal, 2018, 339: 278-287. |
18 | CHEN Jie, SHENG Ye, SONG Yanhua, et al. Multimorphology mesoporous silica nanoparticles for dye adsorption and multicolor luminescence applications[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(3): 3533-3545. |
19 | 田月, 董晓涵, 蒋宇, 等. 改性吸附法去除废水中对硝基苯酚研究进展[J]. 化工新型材料, 2022, 50(10): 76-80. |
TIAN Yue, DONG Xiaohan, JIANG Yu, et al. Research progress in the removal of PNP from wastewater by modified adsorption[J]. New Chemical Materials, 2022, 50(10): 76-80. | |
20 | Jung-Yeol JO, CHOI Jeong-Hwan, TSANG Yiu Fai, et al. Pelletized adsorbent of alum sludge and bentonite for removal of arsenic[J]. Environmental Pollution, 2021, 277: 116747. |
21 | Petra ZAHAJSKÁ, OPFERGELT Sophie, FRITZ Sherilyn C, et al. What is diatomite?[J]. Quaternary Research, 2020, 96: 48-52. |
22 | DAOU Alan S S, FINDLEY John M, FANG Hanjun, et al. Quantifying impact of intrinsic flexibility on molecular adsorption in zeolites[J]. The Journal of Physical Chemistry C, 2021, 125(9): 5296-5305. |
23 | Facundo BARRAQUÉ, MONTES María L, FERNÁNDEZ Mariela A, et al. Arsenate removal from aqueous solution by montmorillonite and organo-montmorillonite magnetic materials[J]. Environmental Research, 2021, 192: 110247. |
24 | 韩乐. 黄磷炉渣制备SiO2基复合吸附剂及其铜吸附性能研究[D]. 昆明: 昆明理工大学, 2021. |
HAN Le|Yue). Preparation of SiO2-based composite adsorbent from yellow phosphorus slag and its copper adsorption performance[D]. Kunming: Kunming University of Science and Technology, 2021. | |
25 | 郭俊元, 王彬. HDTMA改性沸石的制备及吸附废水中对硝基苯酚的性能和动力学[J]. 环境科学, 2016, 37(5): 1852-1857. |
GUO Junyuan, WANG Bin. Preparation of HDTMA-modified zeolite and its performance in nitro-phenol adsorption from wastewaters[J]. Environmental Science, 2016, 37(5): 1852-1857. | |
26 | 蒋智慧. 固体废弃物热解制备吸附剂的实验研究[D]. 北京: 北京化工大学, 2020. |
JIANG Zhihui. Study on preparation of adsorbent by pyrolysis of solid waste[D]. Beijing: Beijing University of Chemical Technology, 2020. | |
27 | 那立艳, 张丽影, 张凤杰, 等. 固液界面吸附热力学参数的计算[J]. 材料导报, 2020, 34(22): 22030-22035. |
NA Liyan, ZHANG Liying, ZHANG Fengjie, et al. Calculation of adsorption thermodynamic parameters at solid-liquid interfaces[J]. Materials Reports, 2020, 34(22): 22030-22035. |
[1] | SONG Weitao, SONG Huiping, FAN Zhenlian, FAN Biao, XUE Fangbin. Research progress of fly ash in anti-corrosion coatings [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4894-4904. |
[2] | WANG Shangbin, OU Hongxiang, XUE Honglai, CAO Haizhen, WANG Junqi, BI Haipu. Effect of xanthan gum and nano silica on the properties of fluorine-free surfactant mixed solution foam [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4856-4862. |
[3] | LI Yunchuang, XIE Fangming, XI Yanan, WAN Xinyue, SUN Yuhu, ZHAO Yongfeng, LI Gen, LIU Honghai, GAO Xionghou, LIU Hongtao. Low-cost synthesis of hydrothermally stable mesoporous aluminosilicates [J]. Chemical Industry and Engineering Progress, 2023, 42(4): 1877-1884. |
[4] | SHANG Xiaobiao, LI Guangchao, XIAO Liping, BAI Yongzhen, XIAO Renyou, LI Jiajian, ZHANG Zhihao. Wave transmission performance of zirconium aluminum silicate fiberboard under large temperature gradient [J]. Chemical Industry and Engineering Progress, 2023, 42(3): 1551-1561. |
[5] | ZHAO Dongsheng, SONG Jiyu, LIN Zhiquan, LIU Guicai, WU Yibo, HUANG Li. Research progress on influencing factors and control strategies of silica scale formation in nanofiltration/reverse osmosis membranes [J]. Chemical Industry and Engineering Progress, 2023, 42(11): 5920-5928. |
[6] | YANG Chengruixue, HUANG Qiyuan, RAN Jiansu, CUI Yuntong, WANG Jianjian. Palladium nanoparticles supported by phosphoric acid-modified SiO2 as efficient catalysts for low-temperature hydrodeoxygenation of vanillin in water [J]. Chemical Industry and Engineering Progress, 2023, 42(10): 5179-5190. |
[7] | PAN Yuelei, CHENG Xudong, YAN Mingyuan, HE Pan, ZHANG Heping. Silica aerogel and its application in the field of thermal insulation [J]. Chemical Industry and Engineering Progress, 2023, 42(1): 297-309. |
[8] | KONG Qian, SUN Jinchao, GE Jiaqi, ZHANG Peng, MA Yanlong, LIU Baijun. Effect of precipitant on the hydrocracking performance of NiW/TiO2-ASA catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(1): 265-271. |
[9] | GUO Zhenxue, YU Haibin, ZHANG Guohui, ZHANG Jingcheng, LU Yanfei, HE Yanzhen, SUN Yanmin, HAN Enshan. Effect of silica modification on the performance of NiMo/Al2O3 catalyst in hydrodesulfurization [J]. Chemical Industry and Engineering Progress, 2022, 41(S1): 210-220. |
[10] | HUANG Ye, YAN Xing, WU Qiaowei, CHAI Xiaotao, PAN Gongying, ZHANG Jinfeng, LI Xiangqian. Study of silica gel regeneration applied on cyclosporine A column chromatography [J]. Chemical Industry and Engineering Progress, 2022, 41(S1): 461-468. |
[11] | WANG Yiru, SONG Xiaosan, SHUI Boyang, WANG Sanfan. Progress in amine-functionalized mesoporous silica for CO2 capture [J]. Chemical Industry and Engineering Progress, 2022, 41(S1): 536-544. |
[12] | WANG Guangxu, JIN Jing, ZHANG Yunpeng, LIU Bojianzhi, LIANG Shiyu, ZHAI Zhongyuan. Influence of molar ratio of silicon to calcium on mineral evolution and ash melting characteristics during the combustion process of Zhundong coal [J]. Chemical Industry and Engineering Progress, 2022, 41(8): 4140-4146. |
[13] | ZHENG Qi, ZHANG Yuting, ZHAO Fengqing. Steel slag stability treatment and free oxide activation utilization in the production of autoclaved building material [J]. Chemical Industry and Engineering Progress, 2022, 41(7): 3983-3989. |
[14] | WANG Zepeng, YUAN Zhongxian, WANG Jie, WEN Xin, LIU Yimo. Effect of particulate diameter of silica gel on performance of solar adsorption refrigeration system [J]. Chemical Industry and Engineering Progress, 2022, 41(7): 3545-3552. |
[15] | LIN Dong, FENG Xiang, LIU Yibin, CHEN Xiaobo, YANG Chaohe. Research progress on the controllable synthesis of high-performance titanium silicalite and its catalytic propene epoxidation with gaseous hydrogen and oxygen [J]. Chemical Industry and Engineering Progress, 2022, 41(5): 2389-2403. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||
京ICP备12046843号-2;京公网安备 11010102001994号 Copyright © Chemical Industry and Engineering Progress, All Rights Reserved. E-mail: hgjz@cip.com.cn Powered by Beijing Magtech Co. Ltd |