Effect of xanthan gum and nano silica on the properties of fluorine-free surfactant mixed solution foam

doi:10.16085/j.issn.1000-6613.2022-1888

Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (9): 4856-4862.DOI: 10.16085/j.issn.1000-6613.2022-1888

• Fine chemicals • Previous Articles Next Articles

Effect of xanthan gum and nano silica on the properties of fluorine-free surfactant mixed solution foam

WANG Shangbin¹(), OU Hongxiang¹(), XUE Honglai¹, CAO Haizhen¹, WANG Junqi², BI Haipu¹

^1.School of Safety Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu, China
^2.Jiangsu Suolong Fire Science and Technology Co. , Ltd. , Taizhou 225753, Jiangsu, China

Received:2022-10-11 Revised:2022-10-27 Online:2023-09-28 Published:2023-09-15
Contact: OU Hongxiang
Supported by:
Foundation of Jiangsu Education Departement(1020220949)

黄原胶和纳米二氧化硅对无氟泡沫性能的影响

王尚彬¹(), 欧红香¹(), 薛洪来¹, 曹海珍¹, 王钧奇², 毕海普¹

^1.常州大学安全科学与工程学院，江苏常州 213164
^2.江苏锁龙消防科技股份有限公司，江苏泰州 225753

通讯作者: 欧红香
作者简介:王尚彬（1996—），男，硕士研究生，研究方向为泡沫灭火剂的制备及性能。E-mail：649829268@qq.com。
基金资助:
国家自然科学基金(21878026);工信部环保安全技术服务平台项目(2020-0107-3-1);2021年江苏省科技副总项目(FZ20211438);2021年江苏省研究生工作站项目(2021-187);常州市重点研发计划(CE20205051);Natural Science

Abstract

Abstract:

The unique advantages of nanoparticles and polymer stabilized foam make it a research hotspot to solve foam stability. In this paper, the effects of hydrophilic silica nanoparticles (NPs) and polymer xanthan gum (XG) on foaming properties, foam stability and spread ability of fluorine-free foam dispersion were explored. The results showed that NPs and XG significantly affected the stability of foam. Compared with NPs, the addition of XG helped to enhance foam stability, but inhibited the foaming performance of foam dispersion. When the mass fraction of NPS was 3.0%, the foaming ability of foam dispersion was improved. When NPs and XG were used together, the additive concentration was controlled, and there was a synergistic effect on the stability of foam. During the spreading process, the viscosity of foam dispersion increased after added NPs and XG that made the spreading speed of foam dispersion on the heptane surface slow down to varying degrees, but it had adversely effect on fire fighting.

Key words: silica nanoparticles, xanthan gum, fluorine free foam dispersion, foaming property, spread property

摘要：

纳米粒子、高分子聚合物稳定泡沫的独特优势使其成为解决泡沫稳定性的研究热点。本文探索了亲水二氧化硅纳米颗粒（NPs）、高分子聚合物黄原胶（XG）对无氟泡沫分散液的发泡性能、泡沫稳定性及铺展性等泡沫性能的影响。研究结果表明，NPs和XG对泡沫稳定性有显著影响。与NPs相比，添加XG有助于增强泡沫稳定性，但对泡沫分散液发泡性能有抑制。NPs添加量为3.0%（质量分数）时，泡沫分散液的发泡能力得到提高。同时添加NPs和XG时，控制二者添加浓度可在稳定泡沫过程中产生协同效应。在铺展过程中，加入NPs、XG后泡沫分散液黏度增加，使泡沫分散液在汽油表面的铺展有不同程度的减缓，但对灭火产生不利影响。

关键词: 纳米二氧化硅, 黄原胶, 无氟泡沫分散液, 发泡性, 铺展性

CLC Number:

X937

WANG Shangbin, OU Hongxiang, XUE Honglai, CAO Haizhen, WANG Junqi, BI Haipu. Effect of xanthan gum and nano silica on the properties of fluorine-free surfactant mixed solution foam[J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4856-4862.

王尚彬, 欧红香, 薛洪来, 曹海珍, 王钧奇, 毕海普. 黄原胶和纳米二氧化硅对无氟泡沫性能的影响[J]. 化工进展, 2023, 42(9): 4856-4862.

Figures/Tables 10

References 28

1	Zenaida BRICEÑO-AHUMADA, SOLTERO-MARTÍNEZ J F A, CASTILLO Rolando. Aqueous foams and emulsions stabilized by mixtures of silica nanoparticles and surfactants: A state-of-the-art review[J]. Chemical Engineering Journal Advances, 2021, 7: 100116.
2	PENG Mengyuan, YANG Yawen, SHA Min, et al. Surface activity, wetting and foaming properties of amine-oxidized nonionic fluorocarbon surfactant and hydrocarbon anionic surfactants mixtures at low concentrations[J]. Journal of Molecular Liquids, 2021, 343: 117701.
3	RAMSDEN W. Separation of solids in the surface-layers of solutions and suspensions[J]. Proceedings of the Royal Society of London, 1903, 72: 156–64.
4	PICKERING S U. CXCVI: Emulsions[J]. Journal of the Chemical Society, Transactions, 1907, 91: 2001–2021.
5	XU Zhisheng, GUO Xing, YAN Long, et al. Fire-extinguishing performance and mechanism of aqueous film-forming foam in diesel pool fire[J]. Case Studies in Thermal Engineering, 2020, 17: 100578.
6	YU Xiaoyang, LIN Yunru, LI Fan, et al. Highly stable fluorine-free foam by synergistically combining hydrolyzed rice protein and ferrous sulfate[J]. Chemical Engineering Science, 2022, 250: 117378.
7	YEKEEN Nurudeen, PADMANABHAN Eswaran, IDRIS Ahmad Kamal. Synergistic effects of nanoparticles and surfactants on n-decane-water interfacial tension and bulk foam stability at high temperature[J]. Journal of Petroleum Science and Engineering, 2019, 179: 814-830.
8	MYKHALICHKO Borys, LAVRENYUK Helen, MYKHALICHKO Oleg. New water-based fire extinguishant: Elaboration, bench-scale tests, and flame extinguishment efficiency determination by cupric chloride aqueous solutions[J]. Fire Safety Journal, 2019, 105: 188-195.
9	PAN Yueyi, BOURNIVAL Ghislain, Seher ATA. Foaming behaviour of frothers in the presence of PAX and salt[J]. Minerals Engineering, 2022, 178: 107405.
10	GILES Spencer L, SNOW Arthur W, HINNANT Katherine M. Modulation of fluorocarbon surfactant diffusion with diethylene glycol butyl ether for improved foam characteristics and fire suppression[J]. Colloids and Surfaces A, 2019, 579: 123660.
11	YU Xiaoyang, JIANG Ning, MIAO Xuyang, et al. Comparative studies on foam stability, oil-film interaction and fire extinguishing performance for fluorine-free and fluorinated foams[J]. Process Safety and Environmental Protection, 2020, 133: 201-215.
12	ZHAO Junchao, FU Yangyang, YIN Zhitao, et al. Preparation of hydrophobic and oleophobic fine sodium bicarbonate by gel-Sol-gel method and enhanced fire extinguishing performance[J]. Materials & Design, 2020, 186: 108331.
13	IBRAHIM Haidar, PATRUNI Jagannadha Rao. Experimental investigation on extinguishing performance of a novel nanocomposite for gaseous fires[J]. Journal of Loss Prevention in the Process Industries, 2020, 65: 104143.
14	LIU Haiqiang, ZONG Ruowen, Siuming LO, et al. Fire extinguishing efficiency of magnesium hydroxide powders under different particle size[J]. Procedia Engineering, 2018, 211: 447-455.
15	ANANTH Ramagopal, SNOW Arthur W, HINNANT Katherine M, et al. Synergisms between siloxane-polyoxyethylene and alkyl polyglycoside surfactants in foam stability and pool fire extinction[J]. Physicochemical and Engineering Aspects, 2019, 579: 123686.
16	张斌, 许莉勇. 超声萃取技术研究与应用进展[J]. 浙江工业大学学报, 2008, 36(5): 558-561.
	ZHANG Bin, XU Liyong. Research and application advance of ultrasound extraction[J]. Journal of Zhejiang University of Technology, 2008, 36(5): 558-561.
17	BASHIR Ahmed, SHARIFI HADDAD Amin, RAFATI Roozbeh. Nanoparticle/polymer-enhanced alpha olefin sulfonate solution for foam generation in the presence of oil phase at high temperature conditions[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2019, 582: 123875.
18	康文东, 徐志胜, 丁发兴, 等. 多糖聚合物对环保型泡沫灭火剂理化性能的影响[J]. 应用化工, 2022, 51(5): 1219-1225.
	KANG Wendong, XU Zhisheng, DING Faxing, et al. Effect of polysaccharide polymers on physicochemical properties of environmental-friendly foam extinguishing agents[J]. Applied Chemical Industry, 2022, 51(5): 1219-1225.
19	FEI Yang, ZHU Jingyi, XU Binyu, et al. Experimental investigation of nanotechnology on worm-like micelles for high-temperature foam stimulation[J]. Journal of Industrial and Engineering Chemistry, 2017, 50: 190-198.
20	CHEN M, SALA G, VAN VALENBERG H J F, et al. Foam and thin films of hydrophilic silica particles modified by β-casein[J]. Journal of Colloid and Interface Science, 2018, 513:357-366.
21	XU Long, Mina Doroudian RAD, TELMADARREIE Ali, et al. Synergy of surface-treated nanoparticle and anionic-nonionic surfactant on stabilization of natural gas foams[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 550: 176-185.
22	JANG Hee Yeon, ZHANG Ke, CHON Bo Hyun, et al. Enhanced oil recovery performance and viscosity characteristics of polysaccharide xanthan gum solution[J]. Journal of Industrial and Engineering Chemistry, 2015, 21: 741-745.
23	ZHANG Pan, CAO Xuewen, LI Xiang, et al. Microscopic mechanisms of inorganic salts affecting the performance of aqueous foams with sodium dodecyl sulfate: View from the gas-liquid interface[J]. Journal of Molecular Liquids, 2021, 343: 117488.
24	AMANI Pouria, FIROUZI Mahshid. Effect of salt and particles on the hydrodynamics of foam flows in relation to foam static characteristics[J]. Chemical Engineering Science, 2022, 254: 117611.
25	SHENG Youjie, XUE Menghua, ZHANG Shanwen, et al. Role of nanoparticles in the performance of foam stabilized by a mixture of hydrocarbon and fluorocarbon surfactants[J]. Chemical Engineering Science, 2020,228: 115977.
26	SHENG Youjie, JIANG Ning, LU Shouxiang, et al. Molecular interaction and foaming property of the mixtures of hydrocarbon, fluorocarbon and silicone surfactants[J]. Journal of Molecular Liquids, 2019, 296: 111836.
27	SHENG Youjie, XUE Menghua, WANG Yubo, et al. Aggregation behavior and foam properties of the mixture of hydrocarbon andfluorocarbon surfactants with addition of nanoparticles[J]. Journal of Molecular Liquids, 2021, 323:115070.
28	AMANI Pouria, KARAKASHEV Stoyan I, GROZEV Nikolay A, et al. Effect of selected monovalent salts on surfactant stabilized foams[J]. Advances in Colloid and Interface Science, 2021, 295: 102490.

样品	无患子皂苷	SDS	CAB	XG	NPs
NX-0#	15	5	5	0	0
N-1#	15	5	5	0	1
N-2#	15	5	5	0	3
X-1#	15	5	5	0.05	0
X-2#	15	5	5	0.1	0
NX-1#	15	5	5	0.05	1
NX-2#	15	5	5	0.05	3
NX-3#	15	5	5	0.1	1
NX-4#	15	5	5	0.1	3

样品	无患子皂苷	SDS	CAB	XG	NPs
NX-0#	15	5	5	0	0
N-1#	15	5	5	0	1
N-2#	15	5	5	0	3
X-1#	15	5	5	0.05	0
X-2#	15	5	5	0.1	0
NX-1#	15	5	5	0.05	1
NX-2#	15	5	5	0.05	3
NX-3#	15	5	5	0.1	1
NX-4#	15	5	5	0.1	3

样品	表面张力/mN·m^-1	黏度/mPa·s
NX-0#	30.28	2.27
N-1#	29.11	2.31
N-2#	29.15	2.45
X-1#	30.21	2.32
X-2#	29.67	2.58
NX-1#	29.88	2.43
NX-2#	29.38	2.51
NX-3#	29.32	2.62
NX-4#	28.94	3.31

样品	表面张力/mN·m^-1	黏度/mPa·s
NX-0#	30.28	2.27
N-1#	29.11	2.31
N-2#	29.15	2.45
X-1#	30.21	2.32
X-2#	29.67	2.58
NX-1#	29.88	2.43
NX-2#	29.38	2.51
NX-3#	29.32	2.62
NX-4#	28.94	3.31

样品	泡沫半衰期/s
NX-0#	270
N-1#	310
N-2#	320
X-1#	289
X-2#	365
NX-1#	340
NX-2#	376
NX-3#	413
NX-4#	490

Effect of xanthan gum and nano silica on the properties of fluorine-free surfactant mixed solution foam

黄原胶和纳米二氧化硅对无氟泡沫性能的影响

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 10

References 28

Related Articles 4

Recommended Articles

Metrics

Comments

[1]	SU Xiuxia，GENG Xiaosha，LI Zhongjin，YANG Yuna. Optimal preparation of a type of super absorbent resin using uniform design [J]. Chemical Industry and Engineering Progree, 2012, 31(06): 1269-1273.
[2]	SU Xiuxia1，LI Yiyang1，LI Zhongjin1，LI Mingjie1，ZHAO Yan1，HAO Mingde2. Preparation and characterization of XG-g-P(AA-co-AM)/AC composite super absorbent resin [J]. Chemical Industry and Engineering Progree, 2011, 30(7): 1556-.
[3]	SU Xiuxia，ZHU Xiaofeng，LI Zhongjin，HAO Mingde，MIAO Zongcheng，ZHANG Chaowu. Synthesis of a new xanthan gum -based superabsorbent resin [J]. Chemical Industry and Engineering Progree, 2009, 28(8): 1386-.
[4]	CHENG Lei，LI Zhongjin，WANG Lei，ZHU Xiaofeng，ZHANG Chaowu. Adsorption properties of graft copolymers of xanthan gum and acrylamide for Cr³⁺ [J]. Chemical Industry and Engineering Progree, 2009, 28(12): 2185-.