Chemical Industry and Engineering Progress ›› 2019, Vol. 38 ›› Issue (04): 1930-1940.DOI: 10.16085/j.issn.1000-6613.2018-1272
• Fine chemicals • Previous Articles Next Articles
Heping LI1(),Jun GONG1,2,Shufen ZHANG1,2,Jun ZHANG1,Yingxiang HU1
Received:
2018-06-20
Revised:
2018-09-10
Online:
2019-04-05
Published:
2019-04-05
作者简介:
李和平(1961—),男,教授,工学博士,主要从事绿色精细有机合成研究。E-mail:<email>lhpp2008@163.com</email>。
基金资助:
CLC Number:
Heping LI, Jun GONG, Shufen ZHANG, Jun ZHANG, Yingxiang HU. Synthesis and adsorpting property of magnetic imprinted crosslinked acrylic acid/acrylamide grafted-esterified cyanoethyl cassava starch microspheres[J]. Chemical Industry and Engineering Progress, 2019, 38(04): 1930-1940.
李和平, 龚俊, 张淑芬, 张俊, 胡英相. 磁性印迹交联AA/AM接枝酯化氰乙基木薯淀粉微球的制备与吸附性能[J]. 化工进展, 2019, 38(04): 1930-1940.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2018-1272
再生次数 | Q/mg?g-1 | 再生次数 | Q/mg?g-1 |
---|---|---|---|
0 | 25.96 | 3 | 22.68 |
1 | 24.21 | 4 | 21.12 |
2 | 23.07 |
再生次数 | Q/mg?g-1 | 再生次数 | Q/mg?g-1 |
---|---|---|---|
0 | 25.96 | 3 | 22.68 |
1 | 24.21 | 4 | 21.12 |
2 | 23.07 |
配合物 | E HOMO /eV | E LUMO /eV | /eV | μ /Debye | χ /eV | η /eV | |
---|---|---|---|---|---|---|---|
Cu-IIPs | -0.231 | -0.062 | 0.169 | 5.172 | 0.147 | 0.0845 | 0.3006 |
配合物 | E HOMO /eV | E LUMO /eV | /eV | μ /Debye | χ /eV | η /eV | |
---|---|---|---|---|---|---|---|
Cu-IIPs | -0.231 | -0.062 | 0.169 | 5.172 | 0.147 | 0.0845 | 0.3006 |
原子 | f + | f - | 原子 | f + | f - | 原子 | f + | f - |
---|---|---|---|---|---|---|---|---|
C1 | –0.0012 | 0.0021 | O23 | 0.0168 | 0.0082 | O49 | 0.0475 | 0.0059 |
C2 | –0.0021 | –0.0032 | C25 | –0.0011 | 0.0033 | O50 | 0.0631 | –0.0054 |
C3 | –0.0084 | 0.0004 | C28 | 0.0091 | 0.0336 | O52 | 0.0469 | 0.0032 |
C4 | –0.0009 | –0.0030 | N29 | –0.0109 | 0.0088 | S53 | 0.0961 | 0.1394 |
C8 | –0.0059 | –0.0254 | C30 | –0.0054 | –0.0032 | C55 | –0.0104 | 0.0054 |
O11 | 0.0007 | 0.0381 | O32 | 0.0118 | 0.0070 | C58 | –0.0135 | –0.0064 |
C12 | 0.0591 | 0.0875 | C33 | –0.0087 | 0.0033 | C60 | 0.0050 | –0.0022 |
S13 | 0.1749 | 0.2235 | C34 | –0.0108 | 0.0024 | C63 | 0.0062 | –0.0092 |
O14 | 0.0046 | –0.0013 | C35 | –0.0120 | –0.0025 | N66 | 0.0115 | –0.0020 |
O16 | 0.0081 | –0.0052 | C38 | –0.0109 | –0.0004 | C69 | 0.0070 | 0.0771 |
O17 | 0.0173 | 0.0032 | C40 | 0.0109 | 0.0032 | O70 | 0.0085 | 0.0672 |
O19 | 0.0063 | –0.0002 | C44 | 0.0092 | 0.0032 | O71 | 0.0026 | 0.0300 |
C20 | -0.0053 | -0.0050 | O47 | 0.0215 | 0.0117 |
原子 | f + | f - | 原子 | f + | f - | 原子 | f + | f - |
---|---|---|---|---|---|---|---|---|
C1 | –0.0012 | 0.0021 | O23 | 0.0168 | 0.0082 | O49 | 0.0475 | 0.0059 |
C2 | –0.0021 | –0.0032 | C25 | –0.0011 | 0.0033 | O50 | 0.0631 | –0.0054 |
C3 | –0.0084 | 0.0004 | C28 | 0.0091 | 0.0336 | O52 | 0.0469 | 0.0032 |
C4 | –0.0009 | –0.0030 | N29 | –0.0109 | 0.0088 | S53 | 0.0961 | 0.1394 |
C8 | –0.0059 | –0.0254 | C30 | –0.0054 | –0.0032 | C55 | –0.0104 | 0.0054 |
O11 | 0.0007 | 0.0381 | O32 | 0.0118 | 0.0070 | C58 | –0.0135 | –0.0064 |
C12 | 0.0591 | 0.0875 | C33 | –0.0087 | 0.0033 | C60 | 0.0050 | –0.0022 |
S13 | 0.1749 | 0.2235 | C34 | –0.0108 | 0.0024 | C63 | 0.0062 | –0.0092 |
O14 | 0.0046 | –0.0013 | C35 | –0.0120 | –0.0025 | N66 | 0.0115 | –0.0020 |
O16 | 0.0081 | –0.0052 | C38 | –0.0109 | –0.0004 | C69 | 0.0070 | 0.0771 |
O17 | 0.0173 | 0.0032 | C40 | 0.0109 | 0.0032 | O70 | 0.0085 | 0.0672 |
O19 | 0.0063 | –0.0002 | C44 | 0.0092 | 0.0032 | O71 | 0.0026 | 0.0300 |
C20 | -0.0053 | -0.0050 | O47 | 0.0215 | 0.0117 |
产物 | E complex /eV | E metal /eV | E polymer /eV | E binding /eV | E binding /kJ·mol-1 |
---|---|---|---|---|---|
Cu-IIPs | –57800.8341 | –5336.6127 | –52463.2636 | –0.9578 | –92.3292 |
产物 | E complex /eV | E metal /eV | E polymer /eV | E binding /eV | E binding /kJ·mol-1 |
---|---|---|---|---|---|
Cu-IIPs | –57800.8341 | –5336.6127 | –52463.2636 | –0.9578 | –92.3292 |
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