Chemical Industry and Engineering Progress ›› 2019, Vol. 38 ›› Issue (04): 1930-1940.DOI: 10.16085/j.issn.1000-6613.2018-1272

• Fine chemicals • Previous Articles     Next Articles

Synthesis and adsorpting property of magnetic imprinted crosslinked acrylic acid/acrylamide grafted-esterified cyanoethyl cassava starch microspheres

Heping LI1(),Jun GONG1,2,Shufen ZHANG1,2,Jun ZHANG1,Yingxiang HU1   

  1. 1. College of Chemistry and Biology Engineering,Guilin University of Technology,Guilin 541004,Guangxi,China
    2. State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian 116204,Liaoning,China
  • Received:2018-06-20 Revised:2018-09-10 Online:2019-04-05 Published:2019-04-05

磁性印迹交联AA/AM接枝酯化氰乙基木薯淀粉微球的制备与吸附性能

李和平1(),龚俊1,2,张淑芬1,2,张俊1,胡英相1   

  1. 1. 桂林理工大学化学与生物工程学院,广西 桂林 541004
    2. 大连理工大学精细化工国家重点实验室,辽宁 大连 116024
  • 作者简介:李和平(1961—),男,教授,工学博士,主要从事绿色精细有机合成研究。E-mail:<email>lhpp2008@163.com</email>。
  • 基金资助:
    国家自然科学基金(21466010);桂林市科学研究与技术开发计划(20150105-5)

Abstract:

The crosslinked acrylic acid/acrylamide grafted-esterified cyanoethyl cassava starch was synthesized by using cassava starch as main raw material through three steps of etherification esterification and grafting. Then magnetic composite modified starzzch microspheres were prepared in inverse emulsion by using Fe3O4 as the nucleus. Subsequently the magnetic imprinted crosslinked acrylic acid/acrylamide grafted-esterified cyanoethyl cassava starch microspheres(Cu-IIPs) with selective adsorption to Cu2+was obtained by surface imprinting modification using Cu2+ as template ion. The particle size of Cu-IIPs was uniformly distributed with the averages particle size of 15.60μm. And the adsorption ratio of Cu-IIPs to Cu2+ can reach to 98.18%. The structure of the Cu-IIPs were characterized by IR, SEM,XRD, VSM and TG-DTG techniques. The frontier orbitals,electron density distribution and Fukui index of optimized Cu-IIPs were analysed by quantum chemical calculation. The adsorption mechanism of Cu-IIPs was studied. The results showed that the magnetic imprinted polymers could form stable coordination compounds with Cu2+, and determined the potential adsorption activity sites. The mechanism of electron transfer between adsorbents and Cu2+ was explained by frontier molecular orbital theory and electron distribution.

Key words: grafted-esterified cyanoethyl cassava starch, magnetic imprinted microspheres, ion imprinting, copper ion adsorption

摘要:

以木薯淀粉为主要原料,通过醚化、酯化、接枝三步反应,合成了交联AA/AM接枝酯化氰乙基木薯淀粉。然后以Fe3O4为磁性核中心,在反相乳液中制得磁性复合改性淀粉微球;进一步以Cu2+为模板离子,经表面印迹修饰得到一种对Cu2+具有选择吸附性的磁性印迹交联AA/AM接枝酯化氰乙基木薯淀粉衍生物微球(Cu-IIPs)。Cu-IIPs粒径分布均匀,平均粒径为15.60μm,对Cu2+的吸附率可达98.18%。采用红外光谱、扫描电子显微镜、X射线衍射仪、振动样品磁强计和综合热分析仪对Cu-IIPs的结构进行了表征。通过量子化学计算,对优化结构的Cu-IIPs的前线轨道、电子密度分布以及Fukui指数进行分析,研究了Cu-IIPs的吸附机理,说明Cu-IIPs能够与Cu2+形成稳定的配合物,确定了可能的吸附活性位点。通过分子前线轨道理论和电荷分布解释了吸附剂与Cu2+发生吸附时的电子转移机制。

关键词: 接枝酯化氰乙基木薯淀粉, 磁性印迹微球, 离子印迹, 铜离子吸附

CLC Number: 

京ICP备12046843号-2;京公网安备 11010102001994号
Copyright © Chemical Industry and Engineering Progress, All Rights Reserved.
E-mail: hgjz@cip.com.cn
Powered by Beijing Magtech Co. Ltd