Recent progress on the preparation and applications of metal organic framework membranes

doi:10.16085/j.issn.1000-6613.2018-1094

Abstract

Abstract:

Membrane-based separation is considered to be one of the most promising separation technologies due to its high efficiency and low energy consumption. Owing to the small difference in the mixtures’ physical properties (such as molecular sizes), it is extremely challenging to finely separate them. Metal-organic frameworks are featured to have good adjustability on aperture sizes and high porosity, thus are expected as ideal membrane materials to sieve molecules precisely. In this review, traditional porous membrane materials are compared and the metal-organic framework based membranes are classified into supported metal-organic framework membranes and mixed matrix membranes. Simultaneously, the fabrication methods and their developments of these two types of membranes are introduced and the more advanced fabrication methods are forecasted. Additionally, the applications of metal-organic framework membranes in gas separation, nanofiltration and desalination, and pervaporation are discussed. Finally, several directions to improve the permeability and selectivity of supported metal-organic framework membranes are proposed.

Key words: membrane, separation, molecular sieves, gas, permeation

摘要：

膜分离技术因其高效节能的特点，被认为是最有前景的分离技术之一。由于众多待分离的混合组分在物理性质（如尺寸）上极为接近，实现精确的膜分离仍具有极大的挑战。金属有机骨架材料具有孔径精确可调、孔隙率高等优点，使其有望实现对尺寸相近分子的精确筛分，因此可以作为理想的膜材料。本文对传统的多孔膜材料进行了比较，并对基于金属有机骨架材料的多孔膜进行了分类，包括支撑型金属有机骨架膜和混合基质膜。同时，系统地总结了两大类金属有机骨架膜的制备方法及其发展历程，对先进的膜制备技术进行了展望；总结了金属有机骨架膜在气体分离、纳滤及海水淡化、渗透汽化等方面的应用。最后，针对支撑型金属有机骨架膜提出了改善其透量和选择性的思路。

关键词: 膜, 分离, 分子筛, 气体, 渗透

CLC Number:

TB383

Sheng ZHOU, Qianqian HOU, Yanying WEI, Haihui WANG. Recent progress on the preparation and applications of metal organic framework membranes[J]. Chemical Industry and Engineering Progress, 2019, 38(01): 467-484.

周胜, 侯倩倩, 魏嫣莹, 王海辉. 金属有机骨架膜的制备与应用进展[J]. 化工进展, 2019, 38(01): 467-484.

Figures/Tables 21

References 98

1	TAYLOR P . Energy technology perspectives 2010—Scenarios and strategies to 2050[ R/OL ]. International Energy Agency, Paris, 2010, 74.
2	ADIL K , BELMABKHOUT Y , PILLAI R S , et al . Gas/vapour separation using ultra-microporous metal-organic frameworks: insights into the structure/separation relationship[J]. Chemical Society Reviews, 2017, 46(11): 3402-3430.
3	SHOLL D S , LIVELY R P . Seven chemical separations: to change the world: purifying mixtures without using heat would lower global energy use, emissions and pollution—and open up new routes to resources[J]. Nature, 2016, 532(7600): 435-438.
4	ZOU X , ZHU G . Microporous organic materials for membrane-based gas separation[J]. Advanced Materials, 2018, 30(3): 1700750.
5	DAVIS M E . Ordered porous materials for emerging applications[J]. Nature, 2002, 417(6891): 813-821.
6	VOGT E , WECKHUYSEN B . Fluid catalytic cracking: recent developments on the grand old lady of zeolite catalysis[J]. Chemical Society Reviews, 2015, 44(20): 7342-7370.
7	LI J , CORMA A , YU J . Synthesis of new zeolite structures[J]. Chemical Society Reviews, 2015, 44(20): 7112-7127.
8	JEON M Y , KIM D , KUMAR P , et al . Ultra-selective high-flux membranes from directly synthesized zeolite nanosheets[J]. Nature, 2017, 543(7647): 690.
9	SILVA J A , RODRIGUES A E . Sorption and diffusion of n-pentane in pellets of 5A zeolite[J]. Industrial & Engineering Chemistry Research, 1997, 36(2): 493-500.
10	MCKEOWN N B , BUDD P M . Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage[J]. Chemical Society Reviews, 2006, 35(8): 675-683.
11	SWAIDAN R , GHANEM B , PINNAU I . Fine-tuned intrinsically ultramicroporous polymers redefine the permeability/selectivity upper bounds of membrane-based air and hydrogen separations[J]. ACS Macro Letters, 2015, 4(9): 947-951.
12	ROBESON L M , LIU Q , FREEMAN B D , et al . Comparison of transport properties of rubbery and glassy polymers and the relevance to the upper bound relationship[J]. Journal of Membrane Science, 2015, 476: 421-431.
13	FREEMAN B D . Basis of permeability/selectivity trade off relations in polymeric gas separation membranes[J]. Macromolecules, 1999, 32(2): 375-380.
14	SWAIDAN R , GHANEM B , LITWILLER E , et al . Physical aging, plasticization and their effects on gas permeation in “rigid” polymers of intrinsic microporosity[J]. Macromolecules, 2015, 48(18): 6553-6561.
15	DENNY J M S , MORETON J C , BENZ L , et al . Metal-organic frameworks for membrane-based separations[J]. Nature Reviews Materials, 2016, 1(12): 16078.
16	FURUKAWA H , CORDOVA K E , O’KEEFFE M , et al . The chemistry and applications of metal-organic frameworks[J]. Science, 2013, 341(6149): 1230444.
17	WILMER C E , LEAF M , LEE C Y , et al . Large-scale screening of hypothetical metal-organic frameworks[J]. Nature Chemistry, 2012, 4(2): 83-89.
18	MOULTON B , ZAWOROTKO M J . From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids[J]. Chemical Reviews, 2001, 101(6): 1629-1658.
19	GUILLERM V , KIM D , EUBANK J F , et al . A supermolecular building approach for the design and construction of metal-organic frameworks[J]. Chemical Society Reviews, 2014, 43(16): 6141-6172.
20	YAGHI O M , O’KEEFFE M , OCKWIG N W , et al . Reticular synthesis and the design of new materials[J]. Nature, 2003, 423(6941): 705-714.
21	VAN DE VOORDE B , BUEKEN B , DENAYER J , et al . Adsorptive separation on metal-organic frameworks in the liquid phase[J]. Chemical Society Reviews, 2014, 43(16): 5766-5788.
22	LIU J , THALLAPALLY P K , MCGRAIL B P , et al . Progress in adsorption-based CO₂ capture by metal-organic frameworks[J]. Chemical Society Reviews, 2012, 41(6): 2308-2322.
23	ROSI N L , ECKERT J , EDDAOUDI M , et al . Hydrogen storage in microporous metal-organic frameworks[J]. Science, 2003, 300(5622): 1127-1129.
24	LI N N , FANE A G , HO W W , et al . Advanced membrane technology and applications[M]. New York: John Wiley & Sons, 2011.
25	BURTCH N C , JASUJA H , WALTON K S . Water stability and adsorption in metal-organic frameworks[J]. Chemical Reviews, 2014, 114(20): 10575-10612.
26	SUN Y , YANG F , WEI Q , et al . Oriented nano-microstructure-assisted controllable fabrication of metal-organic framework membranes on nickel foam[J]. Advanced Materials, 2016, 28(12): 2374-2381.
27	HUANG A , BUX H , STEINBACH F , et al . Molecular-sieve membrane with hydrogen permselectivity: ZIF‐22 in LTA topology prepared with 3-aminopropyltriethoxysilane as covalent linker[J]. Angewandte Chemie, 2010, 122(29): 5078-5081.
28	XIE Z , YANG J , WANG J , et al . Deposition of chemically modified α-Al₂O₃ particles for high performance ZIF-8 membrane on a macroporous tube[J]. Chemical Communications, 2012, 48(48): 5977-5979.
29	HUANG A , DOU W , CARO J . Steam-stable zeolitic imidazolate framework ZIF-90 membrane with hydrogen selectivity through covalent functionalization[J]. Journal of the American Chemical Society, 2010, 132(44): 15562-15564.
30	LIU Q , WANG N , CARO J , et al . Bio-inspired polydopamine: a versatile and powerful platform for covalent synthesis of molecular sieve membranes[J]. Journal of the American Chemical Society, 2013, 135(47): 17679-17682.
31	WANG N , LIU Y , QIAO Z , et al . Polydopamine-based synthesis of a zeolite imidazolate framework ZIF-100 membrane with high H₂/CO₂ selectivity[J]. Journal of Materials Chemistry A, 2015, 3(8): 4722-4728.
32	ZHANG X , LIU Y , LI S , et al . New membrane architecture with high performance: ZIF-8 membrane supported on vertically aligned ZnO nanorods for gas permeation and separation[J]. Chemistry of Materials, 2014, 26(5): 1975-1981.
33	ZHOU S , WEI Y , ZHUANG L , et al . Introduction of metal precursors by electrodeposition for the in situ growth of metal-organic framework membranes on porous metal substrates[J]. Journal of Materials Chemistry A, 2017, 5(5): 1948-1951.
34	ADATOZ E , AVCI A K , KESKIN S . Opportunities and challenges of MOF-based membranes in gas separations[J]. Separation and Purification Technology, 2015, 152: 207-237.
35	RUI Z , JAMES J B , KASIK A , et al . Metal-organic framework membrane process for high purity CO₂ production[J]. AIChE Journal, 2016, 62(11): 3836-3841.
36	SHAH M , MCCARTHY M C , SACHDEVA S , et al . Current status of metal-organic framework membranes for gas separations: promises and challenges[J]. Industrial & Engineering Chemistry Research, 2012, 51(5): 2179-2199.
37	LIU X , DEMIR N K , WU Z , et al . Highly water-stable zirconium metal organic framework UiO-66 membranes supported on alumina hollow fibers for desalination[J]. Journal of the American Chemical Society, 2015, 137(22): 6999-7002.
38	SCHNEEMANN A , BON V , SCHWEDLER I , et al . Flexible metal-organic frameworks[J]. Chemical Society Reviews, 2014, 43(16): 6062-6096. -
39	KOLOKOLOV D I , STEPANOV A G , JOBIC H . Mobility of the 2-methylimidazolate linkers in ZIF-8 probed by ²H NMR: saloon doors for the guests[J]. The Journal of Physical Chemistry C, 2015, 119(49): 27512-27520.
40	LIU B , FISCHER R A . Liquid-phase epitaxy of metal organic framework thin films[J]. Science China Chemistry, 2011, 54(12): 1851-1866.
41	SHEKHAH O , SWAIDAN R , BELMABKHOUT Y , et al . The liquid phase epitaxy approach for the successful construction of ultra-thin and defect-free ZIF-8 membranes: pure and mixed gas transport study[J]. Chemical Communications, 2014, 50(17): 2089-2092.
42	ZACHER D , SCHMID R , LL C W , et al . Surface chemistry of metal-organic frameworks at the liquid-solid interface[J]. Angewandte Chemie International Edition, 2011, 50(1): 176-199.
43	CAMPBELL J , DAVIES R , BRADDOCK D C , et al . Improving the permeance of hybrid polymer/metal-organic framework (MOF) membranes for organic solvent nanofiltration (OSN)-development of MOF thin films via interfacial synthesis[J]. Journal of Materials Chemistry A, 2015, 3(18): 9668-9674.
44	YAO J , DONG D , LI D , et al . Contra-diffusion synthesis of ZIF-8 films on a polymer substrate[J]. Chemical Communications, 2011, 47(9): 2559-2561.
45	HUANG K , LI Q , LIU G , et al . A ZIF-71 hollow fiber membrane fabricated by contra-diffusion[J]. ACS Applied Materials & Interfaces, 2015, 7(30): 16157-16160.
46	HOU J , WEI Y , ZHOU S , et al . Highly efficient H₂/CO₂ separation via an ultrathin metal-organic framework membrane[J]. Chemical Engineering Science, 2018, 182: 180-188.
47	MONDLOCH J E , BURY W , FAIREN-JIMENEZ D , et al . Vapor-phase metalation by atomic layer deposition in a metal-organic framework[J]. Journal of the American Chemical Society, 2013, 135(28): 10294-10297.
48	SOTTO A , ORCAJO G , ARSUAGA J M , et al . Preparation and characterization of MOF‐PES ultrafiltration membranes[J]. Journal of Applied Polymer Science, 2015, 132(21): 41633.
49	LI W , ZHANG Y , LI Q , et al . Metal-organic framework composite membranes: synthesis and separation applications[J]. Chemical Engineering Science, 2015, 135: 232-257.
50	BASU S , MAES M , CANO-ODENA A , et al . Solvent resistant nanofiltration (SRNF) membranes based on metal-organic frameworks[J]. Journal of Membrane Science, 2009, 344(1/2): 190-198.
51	AMIRILARGANI M , SADATNIA B . Poly(vinyl alcohol)/zeolitic imidazolate frameworks (ZIF-8) mixed matrix membranes for pervaporation dehydration of isopropanol[J]. Journal of Membrane Science, 2014, 469: 1-10.
52	DUAN J , PAN Y , PACHECO F , et al . High-performance polyamide thin-film-nanocomposite reverse osmosis membranes containing hydrophobic zeolitic imidazolate framework-8[J]. Journal of Membrane Science, 2015, 476: 303-310.
53	ORDO EZ M J C , BALKUS JR K J , FERRARIS J P , et al . Molecular sieving realized with ZIF-8/Matrimid^® mixed-matrix membranes[J]. Journal of Membrane Science, 2010, 361(1/2): 28-37.
54	DENNY M S , COHEN S M . In situ modification of metal-organic frameworks in mixed-matrix membranes[J]. Angewandte Chemie International Edition, 2015, 54(31): 9029-9032.
55	DECOSTE J B , DENNY JR M S , PETERSON G W , et al . Enhanced aging properties of HKUST-1 in hydrophobic mixed-matrix membranes for ammonia adsorption[J]. Chemical Science, 2016, 7(4): 2711-2716.
56	BACHMAN J E , SMITH Z P , LI T , et al . Enhanced ethylene separation and plasticization resistance in polymer membranes incorporating metal-organic framework nanocrystals[J]. Nature Materials, 2016, 15(8): 845-849.
57	FAN H , SHI Q , YAN H , et al . Simultaneous spray self-assembly of highly loaded ZIF-8-PDMS nanohybrid membranes exhibiting exceptionally high biobutanol-permselective pervaporation[J]. Angewandte Chemie International Edition, 2014, 53(22): 5578-5582.
58	YAN H , LI J , FAN H , et al . Sonication-enhanced in situ assembly of organic/inorganic hybrid membranes: evolution of nanoparticle distribution and pervaporation performance[J]. Journal of Membrane Science, 2015, 481: 94-105.
59	COHEN S M . Postsynthetic methods for the functionalization of metal-organic frameworks[J]. Chemical Reviews, 2011, 112(2): 970-1000.
60	ZHANG Y , FENG X , LI H , et al . Photoinduced postsynthetic polymerization of a metal-organic framework toward a flexible stand-alone membrane[J]. Angewandte Chemie International Edition, 2015, 54(14): 4259-4263.
61	YAO B J , JIANG W L , DONG Y , et al . Post-synthetic polymerization of UIO-66-NH₂ nanoparticles and polyurethane oligomer toward stand-alone membranes for dye removal and separation[J]. Chemistry-A European Journal, 2016, 22(30): 10565-10571.
62	MARTI A M , TRAN D , BALKUS K J . Fabrication of a substituted imidazolate material 1 (SIM-1) membrane using post synthetic modification (PSM) for pervaporation of water/ethanol mixtures[J]. Journal of Porous Materials, 2015, 22(5): 1275-1284.
63	DING L , WEI Y , LI L , et al . MXene molecular sieving membranes for highly efficient gas separation[J]. Nature Communications, 2018, 9(1): 155.
64	BUX H , LIANG F , LI Y , et al . Zeolitic imidazolate framework membrane with molecular sieving properties by microwave-assisted solvothermal synthesis[J]. Journal of the American Chemical Society, 2009, 131(44): 16000-16001.
65	HUANG A , WANG N , KONG C , et al . Organosilica-functionalized zeolitic imidazolate framework ZIF-90 membrane with high gas-separation performance[J]. Angewandte Chemie International Edition, 2012, 51(42): 10551-10555.
66	BROWN A J , BRUNELLI N A , EUM K , et al . Interfacial microfluidic processing of metal-organic framework hollow fiber membranes[J]. Science, 2014, 345(6192): 72-75.
67	KWON H T , JEONG H K . In situ synthesis of thin zeolitic-imidazolate framework ZIF-8 membranes exhibiting exceptionally high propylene/propane separation[J]. Journal of the American Chemical Society, 2013, 135(29): 10763-10768.
68	KWON H T , JEONG H K , LEE A S , et al . Heteroepitaxially grown zeolitic imidazolate framework membranes with unprecedented propylene/propane separation performances[J]. Journal of the American Chemical Society, 2015, 137(38): 12304-12311.
69	GHALEI B , SAKURAI K , KINOSHITA Y , et al . Enhanced selectivity in mixed matrix membranes for CO₂ capture through efficient dispersion of amine-functionalized MOF nanoparticles[J]. Nature Energy, 2017, 2(7): 17086.
70	XIANG L , SHENG L , WANG C , et al . Amino-functionalized ZIF-7 nanocrystals: improved intrinsic separation ability and interfacial compatibility in mixed-matrix membranes for CO₂/CH₄ separation[J]. Advanced Materials, 2017, 29(32): 160699.
71	FALCARO P , OKADA K , HARA T , et al . Centimetre-scale micropore alignment in oriented polycrystalline metal-organic framework films via heteroepitaxial growth[J]. Nature Materials, 2017, 16(3): 342-348.
72	LIU G , CHERNIKOVA V , LIU Y , et al . Mixed matrix formulations with MOF molecular sieving for key energy-intensive separations[J]. Nature Materials, 2018, 17(3): 283-289.
73	ZHU Y , GUPTA K M , LIU Q , et al . Synthesis and seawater desalination of molecular sieving zeolitic imidazolate framework membranes[J]. Desalination, 2016, 385: 75-82.
74	SORRIBAS S , GORGOJO P , TÉLLEZ C , et al . High flux thin film nanocomposite membranes based on metal-organic frameworks for organic solvent nanofiltration[J]. Journal of the American Chemical Society, 2013, 135(40): 15201-15208.
75	ZHANG H , HOU J , HU Y , et al . Ultrafast selective transport of alkali metal ions in metal organic frameworks with subnanometer pores[J]. Science Advances, 2018, 4(2): eaaq0066.
76	ZHANG R , JI S , WANG N , et al . Coordination-driven in situ self-assembly strategy for the preparation of metal-organic framework hybrid membranes[J]. Angewandte Chemie International Edition, 2014, 53(37): 9775-9779.
77	LIPNIZKI F , HAUSMANNS S , TEN P K , et al . Organophilic pervaporation: prospects and performance[J]. Chemical Engineering Journal, 1999, 73(2): 113-129.
78	SORRIBAS S , KUDASHEVA A , ALMENDRO E , et al . Pervaporation and membrane reactor performance of polyimide based mixed matrix membranes containing MOF HKUST-1[J]. Chemical Engineering Science, 2015, 124: 37-44.
79	WEE L H , LI Y , ZHANG K , et al . Submicrometer‐sized ZIF-71 filled organophilic membranes for improved bioethanol recovery: mechanistic insights by Monte Carlo simulation and FTIR spectroscopy[J]. Advanced Functional Materials, 2015, 25(4): 516-525.
80	LIU X L , LI Y S , ZHU G Q , et al . An organophilic pervaporation membrane derived from metal-organic framework nanoparticles for efficient recovery of bio-alcohols[J]. Angewandte Chemie International Edition, 2011, 50(45): 10636-10639.
81	YING Y , XIAO Y , MA J, et al . Recovery of acetone from aqueous solution by ZIF-7/PDMS mixed matrix membranes[J]. RSC
	Advances, 2015, 5(36): 28394-28400.
82	LEE M J , KWON H T , JEONG H K . High-flux zeolitic imidazolate framework membranes for propylene/propane separation by postsynthetic linker exchange[J]. Angewandte Chemie International Edition, 2018, 57(1): 156-161.
83	SHAMSAEI E , LIN X , WAN L , et al . A one-dimensional material as a nano-scaffold and a pseudo-seed for facilitated growth of ultrathin, mechanically reinforced molecular sieving membranes[J]. Chemical Communications, 2016, 52(95): 13764-13767.
84	HU Y , WU Y , DEVENDRAN C , et al . Preparation of nanoporous graphene oxide by nanocrystal-masked etching: toward a nacre-mimetic metal-organic framework molecular sieving membrane[J]. Journal of Materials Chemistry A, 2017, 5(31): 16255-16262.
85	HUANG A , LIU Q , WANG N , et al . Highly hydrogen permselective ZIF-8 membranes supported on polydopamine functionalized macroporous stainless-steel-nets[J]. Journal of Materials Chemistry A, 2014, 2(22): 8246-8251.
86	PENG Y , LI Y , BAN Y , et al . Metal-organic framework nanosheets as building blocks for molecular sieving membranes[J]. Science, 2014, 346(6215): 1356-1359.
87	PENG Y , LI Y , BAN Y , et al . Two-dimensional metal-organic framework nanosheets for membrane-based gas separation[J]. Angewandte Chemie International Edition, 2017, 56(33): 9757-9761.
88	ZHOU S , WEI Y , HOU J , et al . Self-sacrificial template strategy coupled with smart in situ seeding for highly oriented metal-organic framework layers: from films to membranes[J]. Chemistry of Materials, 2017, 29(17): 7103-7107.
89	ZHOU M , KORELSKIY D , YE P , et al . A uniformly oriented MFI membrane for improved CO₂ separation[J]. Angewandte Chemie International Edition, 2014, 53(13): 3492-3495.
90	ZHONG Z , YAO J , CHEN R , et al . Oriented two-dimensional zeolitic imidazolate framework-L membranes and their gas permeation properties[J]. Journal of Materials Chemistry A, 2015, 3(30): 15715-15722.
91	QIU S , XUE M , ZHU G . Metal-organic framework membranes: from synthesis to separation application[J]. Chemical Society Reviews, 2014, 43(16): 6116-6140.
92	SHENG L , WANG C , YANG F , et al . Enhanced C₃H₆/C₃H₈ separation perform ance on MOF membranes through blocking defects and hindering framework flexibility by silicone rubber coating[J]. Chemical Communications, 2017, 53(55): 7760-7763.
93	ZHANG C , KOROS W J . Zeolitic imidazolate framework-enabled membranes: challenges and opportunities[J]. The Journal of Physical Chemistry Letters, 2015, 6(19): 3841-3849.
94	ZHANG C , LIVELY R P , ZHANG K , et al . Unexpected molecular sieving properties of zeolitic imidazolate framework-8[J]. The Journal of Physical Chemistry Letters, 2012, 3(16): 2130-2134.
95	THOMPSON J A , BLAD C R , BRUNELLI N A , et al . Hybrid zeolitic imidazolate frameworks: controlling framework porosity and functionality by mixed-linker synthesis[J]. Chemistry of Materials, 2012, 24(10): 1930-1936.
96	DIESTEL L , WANG N , SCHWIEDLAND B , et al . MOF based MMMs with enhanced selectivity due to hindered linker distortion[J]. Journal of Membrane Science, 2015, 492: 181-186.
97	YIN H , WANG J , XIE Z , et al . A highly permeable and selective amino-functionalized MOF CAU-1 membrane for CO₂-N₂ separation[J]. Chemical Communications, 2014, 50(28): 3699-3701.
98	ZHANG F , ZOU X , GAO X , et al . Hydrogen selective NH₂-MIL-53(Al) MOF membranes with high permeability[J]. Advanced Functional Materials, 2012, 22(17): 3583-3590.

[1]	ZHAO Chen, MIAO Tianze, ZHANG Chaoyang, HONG Fangjun, WANG Dahai. Heat transfer characteristics of ethylene glycol aqueous solution in slit channel under negative pressure [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 148-157.
[2]	HUANG Yiping, LI Ting, ZHENG Longyun, QI Ao, CHEN Zhenglin, SHI Tianhao, ZHANG Xinyu, GUO Kai, HU Meng, NI Zeyu, LIU Hui, XIA Miao, ZHU Kai, LIU Chunjiang. Hydrodynamics and mass transfer characteristics of a three-stage internal loop airlift reactor [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 175-188.
[3]	YANG Hanyue, KONG Lingzhen, CHEN Jiaqing, SUN Huan, SONG Jiakai, WANG Sicheng, KONG Biao. Decarbonization performance of downflow tubular gas-liquid contactor of microbubble-type [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 197-204.
[4]	CHEN Kuangyin, LI Ruilan, TONG Yang, SHEN Jianhua. Structure design of gas diffusion layer in proton exchange membrane fuel cell [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 246-259.
[5]	HE Meijin. Application and development trend of molecular management in separation technology in petrochemical field [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 260-266.
[6]	YANG Yudi, LI Wentao, QIAN Yongkang, HUI Junhong. Analysis of influencing factors of natural gas turbulent diffusion flame length in industrial combustion chamber [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 267-275.
[7]	YANG Xiazhen, PENG Yifan, LIU Huazhang, HUO Chao. Regulation of active phase of fused iron catalyst and its catalytic performance of Fischer-Tropsch synthesis [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 310-318.
[8]	ZHANG Zuoqun, GAO Yang, BAI Chaojie, XUE Lixin. Thin-film nanocomposite (TFN) mixed matrix reverse osmosis (MMRO) membranes from secondary interface polymerization containing in situ grown ZIF-8 nano-particles [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 364-373.
[9]	CUI Shoucheng, XU Hongbo, PENG Nan. Simulation analysis of two MOFs materials for O₂/He adsorption separation [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 382-390.
[10]	ZHAO Wei, ZHAO Deyin, LI Shihan, LIU Hongda, SUN Jin, GUO Yanqiu. Synthesis and application of triazine drag reducing agent for nature gas pipeline [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 391-399.
[11]	LI Shilin, HU Jingze, WANG Yilin, WANG Qingji, SHAO Lei. Research progress in separation and extraction of high value components by electrodialysis [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 420-429.
[12]	ZHANG Jie, WANG Fangfang, XIA Zhonglin, ZHAO Guangjin, MA Shuangchen. Current SF₆ emission, emission reduction and future prospects under “carbon peaking and carbon neutrality” [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 447-460.
[13]	ZHANG Tingting, ZUO Xuqian, TIAN Lingdi, WANG Shimeng. Construction method of volatile organic compounds emission inventory and factor database in chemical industry park [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 549-557.
[14]	GUO Qiang, ZHAO Wenkai, XIAO Yonghou. Numerical simulation of enhancing fluid perturbation to improve separation of dimethyl sulfide/nitrogen via pressure swing adsorption [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 64-72.
[15]	XU Youhao, WANG Wei, LU Bona, XU Hui, HE Mingyuan. China’s oil refining innovation: MIP development strategy and enlightenment [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4465-4470.