Construction method of volatile organic compounds emission inventory and factor database in chemical industry park

doi:10.16085/j.issn.1000-6613.2023-0385

Abstract

Abstract:

Volatile organic compounds (VOCs) emission inventory is the basis for promoting VOCs deep governance and formulating effective air pollution control countermeasures. Chemical industry park, as a key emission unit, is an important target for VOCs emission reduction in our country, but currently a mature and standardized compilation method has not been formed based on the micro-scale VOCs emission inventory of chemical parks. Combined with the current research, work experience and ArcGIS technology, this paper discussed the construction method of VOCs emission inventory and emission factor database from the perspective of chemical industry park, optimized the four dimensions of precision, localization, dynamic and visualization, and proposed the technical path of “pollution source identification-pollutant data acquisition-emission inventory compilation-emission factor database construction”, and obtained the emission inventory and factor database with time, space and chemical species distribution. Taking a salt and chemical industry park in Hebei Province as a case, the workflow of VOCs emission inventory compilation in the park was established. The research can provide technical support for effectively promoting regional VOCs comprehensive treatment and fine treatment of air pollutants.

Key words: organic compounds, gas, volatility, emission inventory, emission factor database, chemical industry park

摘要：

挥发性有机物（volatile organic compounds，VOCs）排放清单是推动VOCs深度治理和制定有效大气污染防治对策的基础依据。化工园区作为VOCs重点排放单元，是我国VOCs减排的重要靶点，但目前基于化工园区微观尺度的VOCs排放清单尚未形成一套成熟、规范的编制方法。本文结合当前研究及工作经验，运用ArcGIS空间分析技术，探讨了化工园区视角下VOCs排放清单及排放因子库的构建方法，从精细化、本土化、动态化、可视化四维度进行了优化，提出了“污染源识别-污染物数据获取-排放清单编制-排放因子库构建”的技术路径，从而获取具有时间、空间和化学物种分布的排放清单和因子库，并以河北省某盐化工园区为案例进行实证研究，建立了该园区VOCs排放清单编制的工作流程，为有效推动区域VOCs综合治理和大气污染物精细化治理提供技术支撑。

关键词: 有机化合物, 气体, 挥发性, 排放清单, 排放因子库, 化工园区

CLC Number:

ZHANG Tingting, ZUO Xuqian, TIAN Lingdi, WANG Shimeng. Construction method of volatile organic compounds emission inventory and factor database in chemical industry park[J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 549-557.

张婷婷, 左旭乾, 田玲娣, 王世猛. 化工园区挥发性有机物排放清单及因子库构建方法[J]. 化工进展, 2023, 42(S1): 549-557.

Figures/Tables 8

名称	排放系数法	监测分析法
公式	$E i = ∑ j E F j × A i j × 1 - η j$	$E n = V × C n × 10 - 6$
公式	式中， $E i$ 为i区域VOCs物种的排放量，g； $E F j$ 为j类污染源对应的排放因子，g/kg产品或g/m³燃料等； $A i j$ 为i区域j类污染源对应的活动水平，如燃料消耗量、产品产量、溶剂使用量等，m³或kg等； $η j$ 为污染控制技术对VOCs的去除效率，%	式中， $E n$ 为污染物n的单位时间排放量，kg/h； $V$ 为废气体积流量，m³/h； $C n$ 为实测得到的污染物n的质量浓度，mg/m³
适用范围	大中尺度	小尺度
误差来源	1.活动水平数据不精确 2.排放因子不适用本土	1.采样方案不统一 2.监测分析方法多样化

名称	排放系数法	监测分析法
公式	$E i = ∑ j E F j × A i j × 1 - η j$	$E n = V × C n × 10 - 6$
公式	式中， $E i$ 为i区域VOCs物种的排放量，g； $E F j$ 为j类污染源对应的排放因子，g/kg产品或g/m³燃料等； $A i j$ 为i区域j类污染源对应的活动水平，如燃料消耗量、产品产量、溶剂使用量等，m³或kg等； $η j$ 为污染控制技术对VOCs的去除效率，%	式中， $E n$ 为污染物n的单位时间排放量，kg/h； $V$ 为废气体积流量，m³/h； $C n$ 为实测得到的污染物n的质量浓度，mg/m³
适用范围	大中尺度	小尺度
误差来源	1.活动水平数据不精确 2.排放因子不适用本土	1.采样方案不统一 2.监测分析方法多样化

行业门类	行业大类	涉气企业数量
1制造业	1-1化学原料和化学制品制造业	10
	1-2化学纤维制造业	1
	1-3医药制造业	2
	1-4食品制造业	3
	1-5非金属矿物制品业	2
2电力、热力、燃气及水生产和供应业	2-1电力热力生产和供应业	1
2电力、热力、燃气及水生产和供应业	2-2水的生产和供应业	1
3水利、环境和公共设施管理业	3-1生态保护和环境治理业	1

一级	二级	三级	四级
A化石燃料燃烧源	A1火力发电	—	A1-1煤
B工艺过程源	B1化学原料与化学制品制造业	B1-1基础化学原料制造	B1-1-1氯乙酸/氰尿酸、氨基磺酸
		B1-2农药制造	B1-2-1杀虫剂/杀菌剂
		B1-3肥料制造	B1-3-1高塔复混肥、氨酸复肥、有机无机肥
		B1-4专用化学产品制造	B1-4-1增塑剂、氯乙酸、甜菜碱盐酸盐、无水甜菜碱/3-巯基丙酸
		B1-5合成材料制造	B1-5-1不饱和聚酯树脂/改性己内酰胺
		B1-6涂料、油墨、颜料及类似产品制造	B1-6-1涂料
	B2化学纤维制造业	B2-1纤维素纤维原料及纤维制造	B2-1-1羧甲基纤维素钠
	B3医药制造业	B3-1化学药品制剂制造	B3-1-1氰钴胺、甲钴胺
	B3医药制造业	B3-2化学药品原料药制造	B3-2-1异辛酸钠、异辛酸钾
	B4非金属矿物制品业	B4-1砖瓦、石材等建筑材料制造	B4-1-1改性沥青防水卷材
	B5食品制造业	B5-1其他食品制造	B5-1-1氯化钠；食品级氨基乙酸
	B6生态保护和环境治理业	B6-1环境治理业	B6-1-1危险废物治理
	B7水的生产和供应业	B7-1污水处理及再生利用	B7-1-1污水处理及再生利用

References 25

1	TSAI J H, LIN K H, CHEN C Y, et al. Volatile organic compound constituents from an integrated iron and steel facility[J]. Journal of Hazardous Materials, 2008, 157(2): 569-578.
2	鲁君. 典型石化企业挥发性有机物排放测算及本地化排放系数研究[J]. 环境污染与防治, 2017, 39(6): 604-609.
	LU Jun. A study on VOCs emission inventory of typical petrochemical plant and its local emission factor [J]. Environmental Pollution & Control, 2017, 39(6): 604-609.
3	田亮, 魏巍, 程水源, 等. 典型有机溶剂使用行业VOCs成分谱及臭氧生成潜势[J]. 安全与环境学报, 2017, 17(1): 314-320.
	TIAN Liang, WEI Wei, CHEGN Shuiyuan, et al. Source profiles and ozone formation potential of volatile organic compounds from the use of solvents in typical industry[J]. Journal of Safety and Environment, 2017, 17(1): 314-320.
4	王伯光, 冯志诚, 周炎, 等. 聚氨酯合成革厂空气中挥发性有机物的成分谱[J]. 中国环境科学, 2009, 29(9): 914-918.
	WANG Boguang, FENG Zhicheng, ZHOU Yan, et al. VOC components in the air caused by the local polyurethane synthetic leather industries in the Pearl River Delta region [J]. China Environmental Science, 2009, 29(9): 914-918.
5	薛鹏丽, 孙晓峰, 邵霞, 等. 北京市家具制造业涂料应用过程挥发性有机物排放现状及未来趋势[J]. 环境污染与防治, 2019, 41(2): 236-239.
	XUE Pengli, SUN Xiaofeng, SHAO Xia, et al. Estimation and forecast of volatile organic compounds emitted from paint uses in Beijing furniture industry[J]. Environmental Pollution & Control, 2019, 41(2): 236-239.
6	邓鑫, 赵桂英, 于站良, 等. 云南省汽车维修业维修过程挥发性有机物排放现状及预测研究[J]. 环境科学导刊, 2021, 40(1): 82-85, 96.
	DENG Xin, ZHAO Guiying, YU Zhanliang, et al. Estimation and forecast of volatile organic compounds emitted from maintenance processes in Yunnan automobile maintenance industry[J]. Environmental Science Survey, 2021, 40(1): 82-85, 96.
7	高素莲, 闫学军, 张荣荣, 等. 济南市人为源挥发性有机物排放清单及特征[J]. 环境科学与技术, 2021, 44(S1): 191-198.
	GAO Sulian, YAN Xuejun, ZHANG Rongrong, et al. Emission inventory and characteristics of anthropogenic volatile organic compounds in Jinan[J]. Environmental Science & Technology, 2021, 44(S1): 191-198.
8	邵弈欣, 陆燕, 楼振纲, 等. 制药行业VOCs排放组分特征及其排放因子研究[J]. 环境科学学报, 2020, 40(11): 4145-4155.
	SHAO Yixin, LU Yan, LOU Zhengang, et al. Study on emission characteristics and emission factors of VOC components in the pharmaceutical industry[J]. Acta Scientiae Circumstantiae, 2020, 40(11): 4145-4155.
9	李豪生, 郑人豪, 安东海, 等. 煤炭利用行业VOCs排放种类及分子特征调查[J]. 环境科技, 2021, 34(6): 21-25.
	LI Haosheng, ZHENG Renhao, AN Donghai, et al. Investigation of VOCs emission types and molecular characteristics in coal utilization industry[J]. Environmental Science and Technology, 2021, 34(6): 21-25.
10	PICCOT Stephen D, WATSON Joel J, JONES Julian W. A global inventory of volatile organic compound emissions from anthropogenic sources[J]. Journal of Geophysical Research, 1992, 97(D9): 9897-9912.
11	刘金凤, 赵静, 李湉湉, 等. 我国人为源挥发性有机物排放清单的建立[J]. 中国环境科学, 2008, 28(6): 496-500.
	LIU Jinfeng, ZHAO Jing, LI Tiantian, et al. Establishment of Chinese anthropogenic source volatile organic compounds emission inventory.[J]. China Enviromnenial Science, 2008,28(6):496-500.
12	莫梓伟, 邵敏, 陆思华. 中国挥发性有机物（VOCs）排放源成分谱研究进展[J]. 环境科学学报, 2014, 34(9): 2179-2189.
	MO Ziwei, SHAO Min, LU Sihua. Review on volatile organic compounds (VOCs) source profiles measured in China[J]. Acta Scientiae Circumstantiae, 2014, 34(9): 2179-2189.
13	SIMAYI M, HAO Y F, LI J, et al. Establishment of county-level emission inventory for industrial NMVOCs in China and spatial-temporal characteristics for 2010-2016[J]. Atmospheric Environment, 2019, 211: 194-203.
14	黄成, 陈长虹, 李莉, 等. 长江三角洲地区人为源大气污染物排放特征研究[J]. 环境科学学报, 2011, 31(9): 1858-1871.
	HUANG Cheng, CHENG Changhong, LI Li, et al. Anthropogenic air pollutant emission characteristics in the Yangtze River Delta region, China[J]. Acta Scientiae Circumstantiae, 2011, 31(9): 1858-1871.
15	夏思佳, 刘倩, 赵秋月. 江苏省人为源VOCs排放清单及其对臭氧生成贡献[J]. 环境科学, 2018, 39(2): 592-599.
	XIA Sijia, LIU Qian, ZHAO Qiuyue. Emission inventory of anthropogenically sourced VOCs and its contribution to ozone formation in Jiangsu province[J]. Environmental Science, 2018, 39(2): 592-599.
16	黄碧捷, 陶元, 岳琳, 等. 湖北省优先控制人为源VOCs排放清单研究[J]. 环境科学与技术, 2018, 41(10): 213-218.
	HUANG Bijie, TAO Yuan, YUE Lin, et al. Emission inventory of priority control anthropogenic VOCs in Hubei province[J]. Environmental Science & Technology, 2018, 41(10):213-218.
17	ZHENG J Y, SHAO M, CHE W W, et al. Speciated VOC emission inventory and spatial patterns of ozone formation potential in the Pearl River Delta, China[J]. Environmental Science &Technology, 2009, 43(22): 8580-8586.
18	LIU Y F, SONG M D, LIU X G, et al. Characterization and sources of volatile organic compounds (VOCs) and their related changes during ozone pollution days in 2016 in Beijing, China[J]. Environmental Pollution, 2020, 257: 113599.
19	吕建华, 李瑞芃, 付飞, 等. 青岛市挥发性有机物排放清单及重点行业排放特征研究[J]. 中国环境管理, 2019, 11(1): 60-66.
	LV Jianhua, LI Ruifan, FU Fei, et al. Emission inventory of volatile organic compounds and pollution characteristics of the key VOC-related industries in Qingdao[J]. Chinese Journal of Environmental Management, 2019, 11(1): 60-66.
20	吴冬阳, 傅海燕, 庄马展, 等. 厦门市工业源VOCs排放清单及控制对策分析[J]. 环境科学, 2020, 41(12): 5336-5344.
	WU Dongyang, FU Haiyan, ZHUANG Mazhan, et al. Analysis of industrial VOCs emission inventory and countermeasures in Xiamen[J]. Environmental Science, 2020, 41(12): 5336-5344.
21	范西彩, 张新民, 张晓红, 等. 鹤壁市大气挥发性有机物源排放清单研究[J]. 中国环境科学, 2021, 41(2): 558-565.
	FAN Xicai, ZHANG Xinmin, ZHANG Xiaohong, et al. Research on the emission inventory of volatile organic compounds in Hebi city, Henan Province[J]. China Enviromnenial Science, 2021, 41(2): 558-565.
22	周子航, 邓也, 张碧, 等. 成都市武侯区生活源挥发性有机物排放清单研究[J]. 四川环境, 2017, 36(6): 65-71.
	ZHOU Zihang, DENG Ye, ZHANG Bi, et al. Study on the domestic emission inventory of volatile organic compounds in Wuhou district, Chengdu[J]. Sichuan Environment, 2017, 36(6): 65-71.
23	任何, 卢轩, 刘洋, 等. 基于排放清单和实地测试的工业VOCs排放特征：以郑州市高新区为例[J]. 环境科学, 2021, 42(12): 5687-5697.
	REN He, LU Xuan, LIU Yang, et al. Emission characteristics of industrial VOCs based on emission inventory and field test: A case Zhengzhou High-tech zone[J]. Environmental Science, 2021, 42(12): 5687-5697.
24	张雪驰, 沙青娥, 陆梦华, 等. 珠三角某石化园区VOCs排放特征及影响评价[J]. 环境科学, 2022, 43(4): 1766-1776.
	ZHANG Xuechi, SHA Qinge, LU Menghua, et al. Volatile organic compound emission characteristics and influences assessment of a petrochemical industrial park in the Pearl River Delta gegion[J]. Environmental Science, 2022, 43(4): 1766-1776.
25	封豆豆, 吴成志, 陈必新, 等. 某精细化工园区VOCs污染特征及来源解析[J]. 高校化学工程学报, 2021, 35(5): 935-942.
	FENG Douhou, WU Chengzhi, WU Bixinet al. Characteristics and source analysis of VOCs in a fine chemical industrial park[J]. Journal of Chemical Engineering of Chinese Universities, 2021, 35(5): 935-942.

[1]	ZHAO Chen, MIAO Tianze, ZHANG Chaoyang, HONG Fangjun, WANG Dahai. Heat transfer characteristics of ethylene glycol aqueous solution in slit channel under negative pressure [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 148-157.
[2]	HUANG Yiping, LI Ting, ZHENG Longyun, QI Ao, CHEN Zhenglin, SHI Tianhao, ZHANG Xinyu, GUO Kai, HU Meng, NI Zeyu, LIU Hui, XIA Miao, ZHU Kai, LIU Chunjiang. Hydrodynamics and mass transfer characteristics of a three-stage internal loop airlift reactor [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 175-188.
[3]	YANG Hanyue, KONG Lingzhen, CHEN Jiaqing, SUN Huan, SONG Jiakai, WANG Sicheng, KONG Biao. Decarbonization performance of downflow tubular gas-liquid contactor of microbubble-type [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 197-204.
[4]	CHEN Kuangyin, LI Ruilan, TONG Yang, SHEN Jianhua. Structure design of gas diffusion layer in proton exchange membrane fuel cell [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 246-259.
[5]	YANG Yudi, LI Wentao, QIAN Yongkang, HUI Junhong. Analysis of influencing factors of natural gas turbulent diffusion flame length in industrial combustion chamber [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 267-275.
[6]	YANG Xiazhen, PENG Yifan, LIU Huazhang, HUO Chao. Regulation of active phase of fused iron catalyst and its catalytic performance of Fischer-Tropsch synthesis [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 310-318.
[7]	ZHAO Wei, ZHAO Deyin, LI Shihan, LIU Hongda, SUN Jin, GUO Yanqiu. Synthesis and application of triazine drag reducing agent for nature gas pipeline [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 391-399.
[8]	ZHANG Jie, WANG Fangfang, XIA Zhonglin, ZHAO Guangjin, MA Shuangchen. Current SF₆ emission, emission reduction and future prospects under “carbon peaking and carbon neutrality” [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 447-460.
[9]	DENG Liping, SHI Haoyu, LIU Xiaolong, CHEN Yaoji, YAN Jingying. Non-noble metal modified vanadium titanium-based catalyst for NH₃-SCR denitrification simultaneous control VOCs [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 542-548.
[10]	XU Youhao, WANG Wei, LU Bona, XU Hui, HE Mingyuan. China’s oil refining innovation: MIP development strategy and enlightenment [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4465-4470.
[11]	LUO Cheng, FAN Xiaoyong, ZHU Yonghong, TIAN Feng, CUI Louwei, DU Chongpeng, WANG Feili, LI Dong, ZHENG Hua’an. CFD simulation of liquid distribution in different distributors in medium-low temperature coal tar hydrogenation reactor [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4538-4549.
[12]	ZHU Jie, JIN Jing, DING Zhenghao, YANG Huipan, HOU Fengxiao. Modification of CaSO₄ oxygen carrier by Zhundong coal ash in chemical looping gasification and its mechanism [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4628-4635.
[13]	WANG Peng, SHI Huibing, ZHAO Deming, FENG Baolin, CHEN Qian, YANG Da. Recent advances on transition metal catalyzed carbonylation of chlorinated compounds [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4649-4666.
[14]	GE Yafen, SUN Yu, XIAO Peng, LIU Qi, LIU Bo, SUN Chengying, GONG Yanjun. Research progress of zeolite for VOCs removal [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4716-4730.
[15]	YANG Bin, WANG Xiaodong, WANG Yan, YI Guiyun, WANG Tielang, SHI Chuang, ZHANG Zhanying. Preparation of nano-Pt/ZnO heterostructures and gas sensitive properties [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4817-4827.