Advances in the coal based high-temperature Fisher-Tropsch synthesis

doi:10.16085/j.issn.1000-6613.2016.s1.021

Abstract

Abstract: The typical processes of high-temperature Fisher-Tropsch synthesis are discussed.The development and recent advances are reviewed.The fusion iron, precipitated iron and supported iron catalyst for high-temperature Fisher-Tropsch synthesis and the deactivation mechanism thereof are described.The downstream processing routes for Gasoline, diesels, oxy-organics and α-olefins are discussed.The technical economics of the process is analyzed.

Key words: indirect coal liquefaction, high-temperature Fisher-Tropsch synthesis, catalyst, α-olefins

摘要： 介绍了煤基高温费托合成的典型工艺路线及技术特点。综述了煤基高温费托合成的发展历程和最新进展。介绍了熔铁、沉淀铁和负载型铁系高温费托合成催化剂及失活规律。讨论了煤基高温费托合成汽柴油、含氧有机物、α-烯烃的加工路线。分析了煤基高温费托合成技术的经济性,对我国发展煤基高温费托合成技术进行了展望。

关键词: 煤间接液化, 高温费托合成, 催化剂, α-烯烃

CLC Number:

TQ529.2

GONG Lei, WU Xiuzhang, LU Weimin, NAN Haiming, WEN Yaoshun. Advances in the coal based high-temperature Fisher-Tropsch synthesis[J]. Chemical Industry and Engineering Progree, 2016, 35(S1): 122-129.

公磊, 吴秀章, 卢卫民, 南海明, 文尧顺. 煤基高温费托合成技术进展[J]. 化工进展, 2016, 35(S1): 122-129.

References

[1] 李克健,吴秀章,舒歌平.煤直接液化技术在中国的发展[J].洁净煤技术,2014(02):39-43.
[2] 李永旺,相宏伟,杨勇.煤炭间接液化:从基础到工业化[J].中国科学:化学,2014(12):1876-1892.
[3] 孙启文.以油品、烯烃和化学品为目标产品的高温费托合成煤液化技术[C].北京:2010中国国际煤化工发展论坛,2010.
[4] DUVENHAGE D J,SHINGLES T.Synthol reactor technology development[J].Catalysis Today,2002,71(3/4):301-305.
[5] DRY M E.Chapter 7-FT catalysts[M].Studies in Surface Science and Catalysis,André S A M D,Elsevier,2004:533-600.
[6] JAGER B,DRY M E,SHINGLES T,et al.Experience with a new type of reactor for Fischer-Tropsch synthesis[J].Catalysis Letters,1990,7(1-4):293-301.
[7] 韩梅.煤间接液化工业示范项目及煤制油主要产品市场前景[J].中国煤炭,2007(07):10-12.
[8] 孙启文,吴建民,张宗森,等.煤间接液化技术及其研究进展[Z].2013:1-12.
[9] 孙启文.煤制油:规模化多联产是方向[J].中国石油和化工,2015(5):15.
[10] 孙启文,朱继承,庞利峰,张宗森.用于费托合成的流化床反应器[P].2006-08-30.
[11] 李娟,吴梁鹏,邱勇,等.费托合成催化剂的研究进展[J].化工进展,2013(s1):100-109.
[12] 杨志琴,贾峰,刘荣.费托合成催化剂的研究进展[J].南京师范大学学报(工程技术版),2011(2):62-67.
[13] 苏海全,张晓红,丁宁,等.费托合成催化剂的研究进展[J].内蒙古大学学报(自然科学版),2009(4):499-513.
[14] STEYNBERG A P,ESPINOZA R L,JAGER B,et al. High temperature Fischer-Tropsch synthesis in commercial practice[J].Applied Catalysis A:General,1999,186(1/2):41-54.
[15] DAVIS B H.Fischer-Tropsch Synthesis:Reaction mechanisms for iron catalysts[J].Catalysis Today,2009,141(1/2):25-33.
[16] 耿加怀,王信,张高博,等.一种微球状费托合成铁基催化剂及其制备方法:1600421[P].2005-03-30.
[17] 孙启文,蒋凡凯,杨文书,等.一种高温费托合成铁基催化剂及其制备方法:1695803[P].2005-11-16.
[18] 孙启文,蒋凡凯,杨文书,等.一种用于高温费托合成的微球状铁基催化剂及其制备方法:1695804[P].2005-11-16.
[19] 孙启文,肖建平,蒋凡凯,等.一种高温费托合成微球型铁基催化剂及其制备方法:1695805[P].2005-11-16.
[20] 毕成通讯员."高温流化床费托合成技术"通过鉴定[N].科技日报,2010-02-08.
[21] 孙博.面向清洁燃料的新型费托合成催化剂的创制和研究[D].上海:复旦大学,2013.
[22] CHENG K,VIRGINIE M,ORDOMSKY V V,et al.Pore size effects in high-temperature Fischer-Tropsch synthesis over supported iron catalysts[J].Journal of Catalysis,2015,328:139-150.
[23] 王野,康金灿,张庆红.费托合成催化剂的研究进展[J].石油化工,2009(12):1255-1263.
[24] DANCUART L P,de Haan R,de Klerk A.Chapter 6-Processing of Primary Fischer-Tropsch Products[M].Studies in Surface Science and Catalysis,André S A M D,Elsevier,2004:482-532.
[25] 许毅.煤间接液化产品结构的发展方向[Z].2015:145-150.
[26] DRY M E.The Fischer-Tropsch process:1950-2000[J].Catalysis Today,2002,71(3/4):227-241.
[27] LECKEL D.Hydroprocessing Euro 4-type diesel from high-temperature Fischer-Tropsch vacuum gas oils[J].Energy Fuels,2009,23(1):38-45.
[28] LAMPRECHT D,DANCUART L P,HARRILALL K. Performance synergies between low-temperature and high-temperature Fischer-Tropsch diesel blends[J].Energy Fuels,2007,21(5):2846-2852.
[29] 煤液化及煤化工国家重点实验室突破一批关键技术[J].中国煤炭,2015(11):67.
[30] 刘敬尧,何畅,李璟,等.以合成气为核心的多联供多联产集成能源化工系统[J].煤炭学报,2010(2):293-298.
[31] 郑洪麻,林巍,肖小清,等.费托合成在我国发展的新机遇[J].动力工程,2002(1):1583-1588.
[32] 唐宏青.合成气化工如何向前推进——煤制油的新思路[J].中氮肥,2015(3):1-3.
[33] 李鑫.陕西煤化工产业链发展路径研究[D].西安:西安石油大学,2012.
[34] 陕西省人民政府关于印发《陕西省产业集群发展规划纲要(2009-2015年)》的通知[J].陕西省人民政府公报,2009(12):9-15.
[35] DRY M E.Chemicals Produced in a Commercial Fischer-Tropsch Process[M].328ed.American Chemical Society,1987:328,18-33.
[36] 舒歌平,等.煤炭液化技术[M].北京:煤炭工业出版社,2003.
[37] 杨正伟,孙启文,张宗森.连续精馏分离高温费托合成反应水中的含氧有机物[J].化学工程,2014(10):29-33.