Progress of new chromium chemicals：Organic chromium complexes

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Progress of new chromium chemicals：Organic chromium complexes

TANG Haiyan1，2，3，4，XIAO Qinggui1，2，3，XU Hongbin1，2，3，ZHANG Yi1，2，3

1 Institute of Process Engineering，Chinese Academy of Sciences，Beijing 100190，China；2 National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology，Beijing 100190，China；3 Key Laboratory of Green Process and Engineering，Chinese Academy of Sciences，Beijing 100190，China；4 University of Chinese Academy of Sciences，Beijing 100190，China

Online:2013-09-05 Published:2013-09-05

新型铬化学品——有机铬研究进展

唐海燕1，2，3，4，肖清贵1，2，3，徐红彬1，2，3，张懿1，2，3

1中国科学院过程工程研究所，北京 100190；2湿法冶金清洁生产技术国家工程实验室，北京 100190； 3中国科学院绿色过程与工程重点实验室，北京 100190；4中国科学院大学，北京 100190

Abstract

Abstract: Trivalent chromium is an essential trace element for mammals. Recently，various organic chromium compounds have been developed and their biological application has also become a hot topic. The research progress of organic chromium chemicals was reviewed. The characteristics of the ligands in organic chromium complexes were analyzed. The species，characteristics，synthesis methods and applications of organic chromium complexes，including chromium pyridinate，chromium aromatic organic acid，chromium aliphatic acid，chromium amino acid，and other organic chromium complexes were summarized. The development of novel organic chromium products could be an important direction for the deep processing of chromium chemicals.

Key words: chromium chemicals, organic chromium, preparation method, biological application

摘要： 三价铬是哺乳动物必需的微量元素之一，多种具有生物活性的有机铬产品相继被研制开发，其生物应用也逐渐成为业内关注的热点之一。基于此，本文综述了国内外有机铬化学品的研究进展情况，分析了有机铬螯合物中配体的性质，详细介绍了有机铬产品的种类、性质、制备方法和生物学功能，包括吡啶酸铬、芳香族有机酸铬、脂肪族有机酸铬、氨基酸铬以及其它有机铬络合物，并提出新型有机铬的开发是铬盐深加工的重要方向，旨在为新型铬化学品研发和铬化工行业铬系产品工程拓展提供有益参考。

关键词: 铬盐产品, 有机铬, 制备方法, 生物学功能

TANG Haiyan1，2，3，4，XIAO Qinggui1，2，3，XU Hongbin1，2，3，ZHANG Yi1，2，3. Progress of new chromium chemicals：Organic chromium complexes[J]. Chemical Industry and Engineering Progree.

唐海燕1，2，3，4，肖清贵1，2，3，徐红彬1，2，3，张懿1，2，3. 新型铬化学品——有机铬研究进展[J]. 化工进展.

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Progress of new chromium chemicals：Organic chromium complexes

新型铬化学品——有机铬研究进展

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