Abstract: In order to overcome technical bottleneck of hydroamination，the influences of catalyst dosage，m(NH3)/m(polyether)，reaction time，temperature and pressure on the conversion of one-pot synthesis of polyether amine by the supercritical method were investigated. The results showed the suitable reaction conditions：catalyst dosage 7.5%，m(NH3)/m(polyether)=1.5，7.5 h，160 ℃， 1.0 MPa. The products was characterized with NMR. The development of this technology will provide strong basis for continuous production instead of traditional batch production.

Key words: polyether amine, supercritical, amination

摘要： 采用超临界流体技术，一步反应合成了聚醚胺，旨在解决羟基胺化的技术瓶颈。主要研究了催化剂用量、物料配比、反应时间、反应温度、临氢压力对转化率的影响。确立了较佳反应条件为：催化剂用量7.5%，液氨对聚醚质量比1.5∶1，反应时间7.5 h，反应温度160 ℃，临氢压力1.0 MPa。最后，利用了核磁共振波谱技术对产品结构进行了表征。此工艺路线的成功开发，将为替代聚醚胺传统釜式间歇生产工艺，实现连续生产提供强有力的依据。

关键词: 聚醚胺, 超临界, 胺化