Chemical Industry and Engineering Progree

Previous Articles     Next Articles

Investigation of oil sand combustion by simultaneous thermal analyzer

JIA Chunxia1,2,LIU Hongpeng2,BAI Jingru2,QIN Hong2,WANG Qing2   

  1. 1School of Energy,Power and Mechanical Engineering,North China Electric Power University,Beijing 102206,China;2Engineering Research Center of Ministry of Education for Comprehensive Utilization of Oil Shale,Northeast Dianli University,Jilin 132012,Jilin,China
  • Online:2013-06-05 Published:2013-06-05

油砂燃烧过程的TG-DSC分析

贾春霞1,2,刘洪鹏2,柏静儒2,秦 宏2,王 擎2   

  1. 1华北电力大学能源动力与机械工程学院,北京 102206;2东北电力大学油页岩综合利用教育部工程研究中心, 吉林 吉林 132012

Abstract: Experiments on combustion of Indonesian oil sands was conducted on thermogravimetric analyzer. The obtained DTG curves revealed that combustion reactions occurred at four different stages in all the samples: low-temperature,medium-temperature,transitional and high-temperature section. The experimental DSC peaks were effectively separated into multiple Gaussian peaks. At last,the most probable kinetic mechanism functions of oil sand pseudo-components were determined according to the Malek’s method,which provided theoretical foundation for further effective exploitation and economical application of oil sands.

Key words: oil sand, combustion, thermogravimetric analysis, Gauss multi-peaks fitting, kinetics, reaction mechanism, oil sand, combustion, thermogravimetric analysis, Gauss multi-peaks, reaction mechanism

摘要: 采用热重分析仪,对印度尼西亚油砂进行了燃烧特性试验。由热重DTG曲线可知,油砂燃烧过程分为4个阶段:燃烧低温、中温、过渡及高温段。采用“非对称高斯多峰拟合法”对油砂燃烧放热峰进行分离拟合,将实验DSC曲线复杂峰分离成为多个高斯函数峰。并结合Malek法确定了油砂燃烧时其伪组分的最概然机理函数。为油砂的有效开发与经济利用提供了理论依据。

关键词: 油砂, 燃烧, 热重分析, 高斯多峰拟合, 动力学, 反应机理, 油砂, 燃烧, 热重分析, 高斯多峰拟合, 反应机理

京ICP备12046843号-2;京公网安备 11010102001994号
Copyright © Chemical Industry and Engineering Progress, All Rights Reserved.
E-mail: hgjz@cip.com.cn
Powered by Beijing Magtech Co. Ltd