Application of graphene and functionalized graphene in the field of energy storage

doi:10.16085/j.issn.1000-6613.2024-1222

Abstract

Abstract:

Graphene meterial has been widespread concern by the materials science community since its introduction in 2004. Researchers from various countries have successively developed functionalized graphene materials with excellent properties on the basis of graphene. Graphene and functionalized graphene materials are widely used in the fields of electronic information, new resources of energy, water treatment, coating industry and enlarged health due to their excellent electrical and thermal conductivity as well as mechanical properties. This paper focused on summarizing the research progress and applications of graphene and functionalized graphene materials in the field of energy storage, including the preparation methods of the materials as well as their applications in various energy storage devices, and proposed the future development of graphene applied to energy storage devices. It was believed that in-depth study of the structure, mechanism and properties of graphene and its functionalized graphene should be continued because the difference in the morphology of graphene and its functionalized graphene directly affected the electrochemical properties of energy storage devices. The review aimed to provide certain ideas for the research and development of graphene and functionalized graphene materials as well as their applications in the field of energy storage.

Key words: graphene, functionalized graphene materials, energy storage, supercapacitors, lithium-sulphur batteries

摘要：

石墨烯材料自2004年问世以来就备受材料科学界的广泛关注。在石墨烯的基础之上，各国科研人员陆续研发出性能优异的功能化石墨烯材料。石墨烯及功能化石墨烯材料凭借优异的导电、导热以及力学性能等特点，被广泛应用于电子信息、新能源、水处理、涂料工业、大健康等领域。本文重点总结了石墨烯及其功能化石墨烯材料在储能领域的研究进展及应用，包括材料的制备方法以及在各种储能器件的应用，并提出了石墨烯应用于储能器件的未来发展建议，认为应该继续深入研究石墨烯及其功能化石墨烯材料的结构、机理与性能，因石墨烯及其功能化石墨烯材料的形貌不同，直接影响了储能器件的电化学特性。本文旨在为石墨烯及其功能化石墨烯材料的研发以及在储能领域的应用提供一定的思路。

关键词: 石墨烯, 功能化石墨烯材料, 储能, 超级电容器, 锂硫电池

CLC Number:

TQ127.1

HU Liang, ZHANG Kaiyue, GAO Bo, ZHANG Zhibin, LIU Zhuang, FU Haiyang, TANG Yiqiao, YANG Yuanyuan. Application of graphene and functionalized graphene in the field of energy storage[J]. Chemical Industry and Engineering Progress, 2025, 44(9): 5055-5074.

胡亮, 张开悦, 高波, 张志彬, 刘状, 付海洋, 唐一巧, 杨媛媛. 石墨烯及其功能化石墨烯材料在储能领域中的应用[J]. 化工进展, 2025, 44(9): 5055-5074.

Figures/Tables 6

References 121

[1]	YIN Li, DENG Chuan, DENG Fei, et al. Analysis of the interaction energies between and within graphite particles during mechanical exfoliation[J]. New Carbon Materials, 2018, 33(5): 449-459.
[2]	JAYASENA Buddhika, MELKOTE Shreyes N. An investigation of PDMS stamp assisted mechanical exfoliation of large area graphene[J]. Procedia Manufacturing, 2015, 1: 840-853.
[3]	YUSUF Mohammed, KUMAR Mahendra, KHAN Moonis Ali, et al. A review on exfoliation, characterization, environmental and energy applications of graphene and graphene-based composites[J]. Advances in Colloid and Interface Science, 2019, 273: 102036-102059.
[4]	夏永康, 顾明远, 杨红官, 等. CVD法制备三维石墨烯的电化学储能性能[J]. 电化学, 2019, 25(1): 89-103.
	XIA Yongkang, GU Mingyuan, YANG Hongguan, et al. CVD preparation and application of 3D graphene in electrochemical energy storage[J]. Journal of Electrochemistry, 2019, 25(1): 89-103.
[5]	李义春. 全球石墨烯产业研究报告[M]. 上海: 华东理工大学出版社, 2021.
	LI Yichun. Global graphene industry research report[M]. Shanghai: East China University of Science and Technology Press, 2021.
[6]	胡贤飞. 纸团石墨烯在储能材料中的应用[D]. 天津: 天津大学, 2018.
	HU Xianfei. Application of paper graphene in energy storage materials[D]. Tianjin: Tianjin University, 2018.
[7]	HAN Junwei, LI Huan, YANG Quanhong. Compact energy storage enabled by graphenes: Challenges, strategies and progress[J]. Materials Today, 2021, 51: 552-565.
[8]	CAI Yuxuan, ZHANG Nan, CAO Xiaoling, et al. Ultra-light and flexible graphene aerogel-based form-stable phase change materials for energy conversion and energy storage[J]. Solar Energy Materials and Solar Cells, 2023, 252: 112176-112186.
[9]	SETYAWATI Rosana Budi, STULASTI Khikmah Nur Rikhy, AZINUDDIN Yazid Rijal, et al. High power and thermal-stable of graphene modified LiNi_0.8Mn_0.1Co_0.1O₂ cathode by simple method for fast charging-enable lithium ion battery[J]. Results in Engineering, 2024, 21: 101651-101661.
[10]	LIU Zhiru, GUO Yanhong, JIANG Rui, et al. Exploring a preheating strategy for lithium-ion battery pack using graphene-enhanced microencapsulated phase change materials[J]. Journal of Energy Storage, 2024, 104: 114609-114622.
[11]	王雷. 石墨烯三维复合材料的制备及其微波吸收性能研究[D]. 西安: 西北工业大学, 2014.
	WANG Lei. Preparation and microwave absorption properties of graphene three-dimensional composites[D]. Xi’an: Northwestern Polytechnical University, 2014.
[12]	李文鹏, 刘晴, 杨志荣, 等. 液相剥离法高效制备石墨烯的研究进展[J]. 化工进展, 2024, 43(1): 215-231.
	LI Wenpeng, LIU Qing, YANG Zhirong, et al. Advances in efficient preparation of graphene by liquid-phase exfoliation[J]. Chemical Industry and Engineering Progress, 2024, 43(1): 215-231.
[13]	王振廷, 王彦霞, 张永柯. 超临界CO₂流体剥离膨胀石墨制备石墨烯[J]. 广东化工, 2020, 47(1): 6-8.
	WANG Zhenting, WANG Yanxia, ZHANG Yongke. Graphene was prepared by stripping expanded graphite with supercritical CO₂ fluid[J]. Guangdong Chemical Industry, 2020, 47(1): 6-8
[14]	ZHOU Yunshen, XIONG Wei, PARK Jongbok, et al. Laser-assisted nanofabrication of carbon nanostructures[J]. Journal of Laser Applications, 2012, 24(4): 042007.
[15]	SIVAKUMAR Mani, YADAV Sudesh, HUNG Wei-Song, et al. One-pot eco-friendly synthesis of edge-carboxylate graphene via dry ball milling for enhanced removal of acid and basic dyes from single or mixed aqueous solution[J]. Journal of Cleaner Production, 2020, 263: 121498-121509.
[16]	PERRET R, RULAND W. The microstructure of PAN-base carbon fibres[J]. Journal of Applied Crystallography, 1970, 3(6): 525-532.
[17]	王延相, 刘玉兰, 王丽民, 等. 由聚丙烯腈基碳纤维制备石墨烯薄膜的探索研究[J]. 功能材料, 2011, 42(3): 520-523.
	WANG Yanxiang, LIU Yulan, WANG Limin, et al. Preparation and research of graphene sheets from PAN based carbon fibers[J]. Journal of Functional Materials, 2011, 42(3): 520-523.
[18]	段淼, 李四中, 陈国华. 机械法制备石墨烯的研究进展[J]. 材料工程, 2013, 41(12): 85-91.
	DUAN Miao, LI Sizhong, CHEN Guohua. Research progress in preparation of graphene by mechanical exfoliation[J]. Journal of Materials Engineering, 2013, 41(12): 85-91.
[19]	GEIM A K, NOVOSELOV K S.The rise of graphene[J].Nature Materials, 2007, 6: 183-191.
[20]	WEN Ya, LIU Huimin, JIANG Xunyong. Preparation of graphene by exfoliation and its application in lithium-ion batteries[J]. Journal of Alloys and Compounds, 2023, 961: 170885-170900.
[21]	祁帅, 黄国强. 液相剥离法制备石墨烯的新进展[J]. 材料导报, 2017, 31(17): 34-40.
	QI Shuai, HUANG Guoqiang. Progress of graphene preparation by liquid-phase exfoliation[J]. Materials Review, 2017, 31(17): 34-40.
[22]	袁小亚. 石墨烯的制备研究进展[J]. 无机材料学报, 2011, 26(6): 561-570.
	YUAN Xiaoya. Progress in preparation of graphene[J]. Journal of Inorganic Materials, 2011, 26(6): 561-570.
[23]	LI Jianhui, YAN Haiting, DANG Dongfeng, et al. Salt and water co-assisted exfoliation of graphite in organic solvent for efficient and large scale production of high-quality graphene[J]. Journal of Colloid and Interface Science, 2019, 535: 92-99.
[24]	向皓明. 循环超临界CO₂射流空化剥离制备石墨烯研究[D]. 大连: 大连理工大学, 2021.
	XIANG Haoming. Study on preparation of graphene by cyclic supercritical CO₂ jet cavitation stripping[D]. Dalian: Dalian University of Technology, 2021.
[25]	ZHU Hongyue, WANG Qibo, YIN Jianzhong. High-pressure induced exfoliation for regulating the morphology of graphene in supercritical CO₂ system[J]. Carbon, 2021, 178: 211-222.
[26]	LI Lei, XU Jingcheng, LI Genghui, et al. Preparation of graphene nanosheets by shear-assisted supercritical CO₂ exfoliation[J]. Chemical Engineering Journal, 2016, 284: 78-84.
[27]	WEI Ying, SUN Zhenyu. Liquid-phase exfoliation of graphite for mass production of pristine few-layer graphene[J]. Current Opinion in Colloid & Interface Science, 2015, 20(5/6): 311-321.
[28]	LI Dan, MÜLLER Marc B, GILJE Scott, et al. Processable aqueous dispersions of graphene nanosheets[J]. Nature Nanotechnology, 2008, 3: 101-105.
[29]	STANKOVICH Sasha, DIKIN Dmitriy A, PINER Richard D, et al. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide[J]. Carbon, 2007, 45(7): 1558-1565.
[30]	BOURLINOS Athanasios B, GOURNIS Dimitrios, PETRIDIS Dimitrios, et al. Graphite oxide: Chemical reduction to graphite and surface modification with primary aliphatic amines and amino acids[J]. Langmuir, 2003, 19(15): 6050-6055.
[31]	FAN Xiaobin, PENG Wenchao, LI Yang, et al. Deoxygenation of exfoliated graphite oxide under alkaline conditions: A green route to graphene preparation[J]. Advanced Materials, 2008, 20(23): 4490-4493.
[32]	SHER SHAH Md Selim Arif, Reum PARK A, ZHANG Kan, et al. Green synthesis of biphasic TiO₂-reduced graphene oxide nanocomposites with highly enhanced photocatalytic activity[J]. ACS Applied Materials & Interfaces, 2012, 4(8): 3893-3901
[33]	PEI Songfeng, ZHAO Jinping, DU Jinhong, et al. Direct reduction of graphene oxide films into highly conductive and flexible graphene films by hydrohalic acids[J]. Carbon, 2010, 48(15): 4466-4474.
[34]	CHEN Ji, LI Yingru, HUANG Liang, et al. High-yield preparation of graphene oxide from small graphite flakes via an improved Hummers method with a simple purification process[J]. Carbon, 2015, 81: 826-834.
[35]	SHAH Ami A, XU George, ROSEN Antony, et al. Brief report: Anti-RNPC-3 antibodies As a marker of cancer-associated scleroderma[J]. Arthritis & Rheumatology, 2017, 69(6): 1306-1312.
[36]	HSU Steven, HOUSTON Brian A, TAMPAKAKIS Emmanouil, et al. Right ventricular functional reserve in pulmonary arterial hypertension[J]. Circulation, 2016, 133(24): 2413-2422.
[37]	SHAMAILA Sajjad, SAJJAD Ahmed Khan Leghari, IQBAL Anum. Modifications in development of graphene oxide synthetic routes[J]. Chemical Engineering Journal, 2016, 294: 458-477.
[38]	王露. 改进Hummers法制备氧化石墨烯及其表征[J]. 包装学报, 2015, 7(2): 28-31, 37.
	WANG Lu. Synthesis and characterization of graphene oxide with improved hummers method[J]. Packaging Journal, 2015, 7(2): 28-31, 37.
[39]	LOWE Sean E, SHI Ge, ZHANG Yubai, et al. The role of electrolyte acid concentration in the electrochemical exfoliation of graphite: Mechanism and synthesis of electrochemical graphene oxide[J]. Nano Materials Science, 2019, 1(3): 215-223.
[40]	LIU Jilei, Chee Kok POH, ZHAN Da, et al. Improved synthesis of graphene flakes from the multiple electrochemical exfoliation of graphite rod[J]. Nano Energy, 2013, 2(3): 377-386.
[41]	WANG Guoxiu, WANG Bei, PARK Jinsoo, et al. Highly efficient and large-scale synthesis of graphene by electrolytic exfoliation[J]. Carbon, 2009, 47(14): 3242-3246.
[42]	Murat ALANYALıOĞLU, SEGURA Juan Josè, Judith ORÓ-SOLÈ, et al. The synthesis of graphene sheets with controlled thickness and order using surfactant-assisted electrochemical processes[J]. Carbon, 2012, 50(1): 142-152.
[43]	ZHOU Ming, TANG Jie, CHENG Qian, et al. Few-layer graphene obtained by electrochemical exfoliation of graphite cathode[J]. Chemical Physics Letters, 2013, 572: 61-65.
[44]	ABDELKADER Amr M, KINLOCH Ian A, DRYFE Robert A W. Continuous electrochemical exfoliation of micrometer-sized graphene using synergistic ion intercalations and organic solvents[J]. ACS Applied Materials & Interfaces, 2014, 6(3): 1632-1639.
[45]	YANG Yingchang, LU Fang, ZHOU Zhou, et al. Electrochemically cathodic exfoliation of graphene sheets in room temperature ionic liquids N-butyl, methylpyrrolidinium bis(trifluoromethylsulfonyl)imide and their electrochemical properties[J]. Electrochimica Acta, 2013, 113: 9-16.
[46]	SAFITRI R N, SURIANI A B, HTWE Y Z N, et al. Recent development of electrochemically exfoliated graphene and its hybrid conductive inks for printed electronics applications[J]. Synthetic Metals, 2024, 308: 117707-117728.
[47]	GONG Youning, PING Yunjie, LI Delong, et al. Preparation of high-quality graphene via electrochemical exfoliation & spark plasma sintering and its applications[J]. Applied Surface Science, 2017, 397: 213-219.
[48]	CHEN Lingxiu, WANG Dehe, SUN Qingxu, et al. Effect of hydrogen on graphene growth on SiC(0001) under atmospheric pressure[J]. Physica E: Low-dimensional Systems and Nanostructures, 2025, 165: 116088-116091.
[49]	PEDOWITZ Michael, LEWIS Daniel, DEMELL Jennifer, et al. Green growth of mixed valence manganese oxides on quasi-freestanding bilayer epitaxial graphene-silicon carbide substrates[J]. Materials Today Advances, 2024, 21: 100467-100479.
[50]	KAMEL Michael S A, Michael OELGEMÖLLER, JACOB Mohan V. Chemical vapor deposition-grown graphene transparent conducting electrode for organic photovoltaics: Advances towards scalable transfer-free synthesis[J]. Renewable and Sustainable Energy Reviews, 2024, 203: 114740-114771.
[51]	MAULINA Hervin, WIDIANTO Eri, SUBAMA Emmistasega, et al. Optical properties of CVD-grown multilayer graphene on nickel using spectroscopic ellipsometry[J]. Optical Materials, 2024, 157: 116300-116306.
[52]	YAN Xin, CUI Xiao, LI Liangshi. Synthesis of large, stable colloidal graphene quantum dots with tunable size[J]. Journal of the American Chemical Society, 2010, 132(17): 5944-5945.
[53]	JIANG Lang, NIU Tianchao, LU Xiuqiang, et al. Low-temperature, bottom-up synthesis of graphene via a radical-coupling reaction[J]. Journal of the American Chemical Society, 2013, 135(24): 9050-9054.
[54]	DENG Dehui, PAN Xiulian, ZHANG Hui, et al. Freestanding graphene by thermal splitting of silicon carbide granules[J]. Advanced Materials, 2010, 22(19): 2168-2171.
[55]	陆东梅, 杨瑞霞, 孙信华, 等. 石墨烯的SiC外延生长及应用[J]. 半导体技术, 2012, 37(9): 665-669.
	LU Dongmei, YANG Ruixia, SUN Xinhua, et al. Epitaxial growth of graphene on SiC substrate and their application[J]. Semiconductor Technology, 2012, 37(9): 665-669.
[56]	YAZDI Gholam, IAKIMOV Tihomir, YAKIMOVA Rositsa. Epitaxial graphene on SiC: A review of growth and characterization[J]. Crystals, 2016, 6(5): 53.
[57]	RATHORE Shivi, PATEL Dinesh Kumar, THAKUR Mukesh Kumar, et al. Highly sensitive broadband binary photoresponse in gateless epitaxial graphene on 4H-SiC[J]. Carbon, 2021, 184: 72-81.
[58]	VOZDA V, MEDVEDEV N, CHALUPSKÝ J, et al. Detachment of epitaxial graphene from SiC substrate by XUV laser radiation[J]. Carbon, 2020, 161: 36-43.
[59]	ZHU Fengqian, JIA Yuping, SUN Xiaojuan, et al. Ultrafine Si evaporation control technology to inhibit the island nucleation of epitaxial graphene on SiC (000-1)[J]. Journal of Crystal Growth, 2024, 642: 127773-127780.
[60]	CAO Ning, QI Tianyi, QI Hao, et al. An alternative mechanism of dry reforming enhanced growth of high-quality graphene: CO_2-assisted CVD[J]. Chemical Engineering Journal, 2024, 479: 147477-147485.
[61]	FAN Xing, SUN Jie, GUO Weiling, et al. Chemical vapor deposition of graphene on refractory metals: The attempt of growth at much higher temperature[J]. Synthetic Metals, 2019, 247: 233-239.
[62]	AKHTAR Fatima, DABROWSKI Jaroslaw, LISKER Marco, et al. Large-scale chemical vapor deposition of graphene on polycrystalline nickel films: Effect of annealing conditions[J]. Thin Solid Films, 2019, 690: 137565-137572.
[63]	SIMPSON Christopher D, MATTERSTEIG Gunter, MARTIN Kai, et al. Nanosized molecular propellers by cyclodehydrogenation of polyphenylene dendrimers[J]. Journal of the American Chemical Society, 2004, 126(10): 3139-3147.
[64]	TREIER Matthias, PIGNEDOLI Carlo Antonio, LAINO Teodoro, et al. Surface-assisted cyclodehydrogenation provides a synthetic route towards easily processable and chemically tailored nanographenes[J]. Nature Chemistry, 2011, 3(1): 61-67.
[65]	成雪莉, 张维福, 罗城城, 等. 一步水热法制备三维石墨烯/Fe₃O₄复合材料及其储锂性能[J]. 储能科学与技术, 2023, 12(4): 1066-1074.
	CHENG Xueli, ZHANG Weifu, LUO Chengcheng, et al. Preparation of three-dimensional graphene/Fe₃O₄composites by one-step hydrothermal method and their lithium storage performance[J]. Energy Storage Science and Technology, 2023, 12(4): 1066-1074.
[66]	YANG Huafeng, SHAN Changsheng, LI Fenghua, et al. Covalent functionalization of polydisperse chemically-converted graphene sheets with amine-terminated ionic liquid[J]. Chemical Communications, 2009(26): 3880-3882.
[67]	SHEN Jianfeng, HU Yizhe, LI Chen, et al. Synthesis of amphiphilic graphene nanoplatelets[J]. Small, 2009, 5(1): 82-85.
[68]	PAWAR D C, BAGDE A G, THORAT J P, et al. Synthesis of reduced graphene oxide (rGO)/polyaniline (PANI) composite electrode for energy storage: Aqueous asymmetric supercapacitor[J]. European Polymer Journal, 2024, 218: 113366-113377.
[69]	LI Xiaolin, WANG Xinran, ZHANG Li, et al. Chemically derived, ultrasmooth graphene nanoribbon semiconductors[J]. Science, 2008, 319(5867): 1229-1232.
[70]	Cristina VALLÉS, DRUMMOND Carlos, SAADAOUI Hassan, et al. Solutions of negatively charged graphene sheets and ribbons[J]. Journal of the American Chemical Society, 2008, 130(47): 15802-15804.
[71]	PATIL Avinash J, VICKERY Jemma L, SCOTT Thomas B, et al. Aqueous stabilization and self-assembly of graphene sheets into layered bio-nanocomposites using DNA[J]. Advanced Materials, 2009, 21(31): 3159-3164.
[72]	SHEN Hailong, WEI Xiaochun, CEN Zhenqi, et al. Synthesis of nitrogen-doped graphene driven from photothermal decomposition of ammonium bicarbonate and its application in supercapacitors[J]. Journal of Energy Storage, 2022, 56: 105934-105941.
[73]	AMIRI Ahmad, SHANBEDI Mehdi, CHEW B T, et al. Toward improved engine performance with crumpled nitrogen-doped graphene based water-ethylene glycol coolant[J]. Chemical Engineering Journal, 2016, 289: 583-595.
[74]	DU Qinglai, ZHENG Mingbo, ZHANG Lifeng, et al. Preparation of functionalized graphene sheets by a low-temperature thermal exfoliation approach and their electrochemical supercapacitive behaviors[J]. Electrochimica Acta, 2010, 55(12): 3897-3903.
[75]	TAMGADGE Rupesh M, SHUKLA Anupam. A pH-dependent partial electrochemical exfoliation of highly oriented pyrolytic graphite for high areal capacitance electric double layer capacitor electrode[J]. Electrochimica Acta, 2019, 325: 134933-134943.
[76]	朱晓艳. PEDOT增强石墨烯和碳纤维薄膜电容性能研究[D]. 西安: 陕西师范大学, 2022.
	ZHU Xiaoyan. Study on capacitance properties of PEDOT reinforced graphene and carbon fiber films[D]. Xi’an: Shaanxi Normal University, 2022.
[77]	张晴晴. 胺改性石墨烯及含铁氧化物三维炭材料的电化学性能研究[D]. 北京: 中国矿业大学(北京), 2020.
	ZHANG Qingqing. Study on electrochemical properties of amine modified graphene and iron oxide three-dimensional carbon materials[D]. Beijing: China University of Mining & Technology, Beijing, 2020.
[78]	王晓倩. 氮掺杂石墨烯的化学选择性合成及其电化学储能和催化性质研究[D]. 合肥: 中国科学技术大学, 2018.
	WANG Xiaoqian. Chemoselective synthesis of nitrogen doped graphene and its electrochemical energy storage and catalytic properties[D]. Hefei: University of Science and Technology of China, 2018.
[79]	WU Shuilin, CHEN Guanxiong, KIM Na Yeon, et al. Creating pores on graphene platelets by low-temperature KOH activation for enhanced electrochemical performance[J]. Small, 2016, 12(17): 2376-2384.
[80]	叶江林, 朱彦武. 氢氧化钾活化制备超级电容器多孔碳电极材料[J]. 电化学, 2017, 23(5): 548-559.
	YE Jianglin, ZHU Yanwu. Porous carbon materials produced by KOH activation for supercapacitor electrodes[J]. Journal of Electrochemistry, 2017, 23(5): 548-559.
[81]	Hamideh MOHAMMADIAN-SARCHESHMEH, Mohammad MAZLOUM-ARDAKANI. Porous carbohydrate-graphene aerogels synthesized by green method as electroactive supercapacitor materials[J]. Heliyon, 2024, 10(8): 29852-29860.
[82]	ABDOU AHMED ABDOU ELSEHSAH Khaled, AHMAD NOORDEN Zulkarnain, SAMAN Norhafezaidi MAT. Current insights and future prospects of graphene aerogel-enhanced supercapacitors: A systematic review[J]. Heliyon, 2024, 10(17): 37071-37094.
[83]	FU Haiyang, GAO Bo, LI Jiahao, et al. Honeycomb graphene-polyaniline nanocomposites as novel electrode materials for high-performance supercapacitors[J]. New Journal of Chemistry, 2023, 47(23): 11001-11014.
[84]	XIE Hongmei, DAI Juguo, LUO Lili, et al. Terpyridine-functionalized polyaniline/reduced graphene oxide composites for capturing Cr³⁺ ions and its application in supercapacitors[J]. Journal of Energy Storage, 2022, 52: 104965-104974.
[85]	ZHANG Buyuan, WU Chenghan, BAO Yan, et al. Aniline tetramer conjugated N-doped graphene aerogel enabling efficient pH-universal aqueous supercapacitors[J]. Journal of Colloid and Interface Science, 2025, 677: 151-160.
[86]	周红燕. 过渡金属氧化物/石墨烯复合材料的锂电性能研究[D]. 兰州: 兰州大学, 2021.
	ZHOU Hongyan. Study on lithium electrical properties of transition metal oxide/graphene composites[D]. Lanzhou: Lanzhou University, 2021.
[87]	刘然. 基于锰基气凝胶的MnO/C复合材料的可控合成及其电化学储能研究[D]. 北京: 北京化工大学, 2021.
	LIU Ran. Controllable synthesis and electrochemical energy storage of MnO/C composites based on manganese-based aerogels[D]. Beijing: Beijing University of Chemical Technology, 2021.
[88]	宋金聚, 苑仁鲁, 侯若洋. 石墨烯在锂离子电池中的应用进展[J]. 炭素, 2023 (2): 21-29.
	SONG Jinju, YUAN Renlu, HOU Ruoyang. Application progress of graphene in lithium ion batteries[J]. Carbon, 2023 (2): 21-29.
[89]	PAN Yang, XU Meng, YANG Leyan, et al. Porous architectures assembled with ultrathin Cu₂O-Mn₃O₄ hetero-nanosheets vertically anchoring on graphene for high-rate lithium-ion batteries[J]. Journal of Alloys and Compounds, 2020, 819: 152969-152978.
[90]	WU Diben, WANG Chao, WU Huijie, et al. Synthesis of hollow Co₃O₄ nanocrystals in situ anchored on holey graphene for high rate lithium-ion batteries[J]. Carbon, 2020, 163: 137-144.
[91]	WAN Baicen, GUO Jiangcheng, LAI Weihong, et al. Layered mesoporous CoO/reduced graphene oxide with strong interfacial coupling as a high-performance anode for lithium-ion batteries[J]. Journal of Alloys and Compounds, 2020, 843: 156050-156057.
[92]	WU Diben, ZHAO Wenxi, WU Huijie, et al. Holey graphene confined hollow nickel oxide nanocrystals for lithium ion storage[J]. Scripta Materialia, 2020, 178: 187-192.
[93]	KANG Rong, LI Sheng, ZOU Bobo, et al. Design of Nb₂O₅@rGO composites to optimize the lithium-ion storage performance[J]. Journal of Alloys and Compounds, 2021, 865: 158824-158830.
[94]	MIFOUNDE BENGONO D A, ZHANG Bao, YAO Yingying, et al. Fe₃O₄ wrapped by reduced graphene oxide as a highperformance anode material for lithium-ion batteries[J]. International Journal of Ionics, 2020, 26: 1695-1701.
[95]	FU Yuanxiang, DAI Yao, PEI Xian-Yinan, et al. TiO₂ nanorods anchor on reduced graphene oxide (R-TiO₂/rGO) composite as anode for high performance lithium-ion batteries[J]. Applied Surface Science, 2019, 497: 143553-143559.
[96]	QIN Getong, DING Ling, ZENG Min, et al. Mesoporous Fe₂O₃/N-doped graphene composite as an anode material for lithium ion batteries with greatly enhanced electrochemical performance[J]. Journal of Electroanalytical Chemistry, 2020, 866: 114176-114181.
[97]	CHEN Jingqi, BAI Zhenhua, LI Xuetong, et al. In-situ synthesis of reduced graphene oxide wrapped Mn₃O₄ nanocomposite as anode materials for high-performance lithium-ion batteries[J]. Ceramics International, 2022, 48(21): 31923-31930.
[98]	FAN Haiyang, YI Guiyun, TIAN Qiming, et al. Hydrothermal-template synthesis and electrochemical properties of Co₃O₄/nitrogen-doped hemisphere-porous graphene composites with 3D heterogeneous structure[J]. RSC Advances, 2020, 10(60): 36794-36805.
[99]	ERSHADI Mahshid, JAVANBAKHT Mehran, BRANDELL Daniel, et al. Facile synthesis of amino-functionalized mesoporous Fe₃O₄/rGO 3D nanocomposite by diamine compounds as Li-ion battery anodes[J]. Applied Surface Science, 2022, 601: 154120-154137.
[100]	王青林. 钠离子电池正极材料的制备及其与电解液相容性研究[D]. 徐州: 中国矿业大学, 2023.
	WANG Qinglin. Preparation of cathode material for sodium ion battery and its compatibility with electrolyte[D]. Xuzhou: China University of Mining and Technology, 2023.
[101]	罗达. 功能化石墨烯改性及其纳米复合材料的储能应用研究[D]. 南京: 南京理工大学, 2018.
	LUO Da. Study on modification of functionalized graphene and its application in energy storage of nanocomposites[D]. Nanjing: Nanjing University of Science and Technology, 2018.
[102]	ZHU Ming, LI Jialun, YANG Xijia, et al. 3D reduced graphene oxide wrapped MoS₂@Sb₂S₃ heterostructures for high performance sodium-ion batteries[J]. Applied Surface Science, 2023, 624: 157106-157115.
[103]	JIN Youngho, SEONG Honggyu, MOON Joon Ha, et al. Study on colloidal synthesis of ZnS nanospheres embedded in reduced graphene oxide materials for sodium-ion batteries and energy storage mechanism[J]. Journal of Alloys and Compounds, 2023, 943: 169076-169084.
[104]	LI Wenbin, ZHANG Jianghua, HUANG Jianfeng, et al. Constructing VS₄nanorods anchored on reduced graphene oxide surface to enhance rate capability as sodium-ion battery anode[J]. Materials Letters, 2023, 330: 133301-133304.
[105]	ZHANG Lixuan, PENG Fan, ZHANG Man, et al. Heterostructured FeS₂/SnS₂ nanoparticles anchored on graphene for advanced lithium and sodium-ion batteries[J]. Applied Surface Science, 2022, 606: 154864-154873.
[106]	Waleed JAN, KHAN Adnan Daud, IFTIKHAR Faiza Jan, et al. Recent advancements and challenges in deploying lithium sulfur batteries as economical energy storage devices[J]. Journal of Energy Storage, 2023, 72: 108559-108576.
[107]	KAMISAN Ainnur Izzati, TUNKU KUDIN Tunku Ishak, KAMISAN Ainnur Sherene, et al. Recent advances on graphene-based materials as cathode materials in lithium-sulfur batteries[J]. International Journal of Hydrogen Energy, 2022, 47(13): 8630-8657.
[108]	LIN Pengshan, GAO Bo, LI Jiahao, et al. VO₂/VS₄ heterostructures structure-modified 3D reduced graphene oxide aerogel as an advanced host for lithium-sulfur batteries[J]. Diamond and Related Materials, 2024, 147: 111287-111298.
[109]	HONG Jin Young, JUNG Yongju, PARK Dae-Won, et al. Synthesis and electrochemical analysis of electrode prepared from zeolitic imidazolate framework (ZIF)-67/graphene composite for lithium sulfur cells[J]. Electrochimica Acta, 2018, 259: 1021-1029.
[110]	ZHOU Yin, GUO Shaojun. Recent advances in cathode catalyst architecture for lithium-oxygen batteries[J]. eScience, 2023, 3(4): 100123-100138.
[111]	梁师鹏. 还原氧化石墨烯的制备及其锂空气电池的电化学性能研究[D]. 深圳: 深圳大学, 2020.
	LIANG Shipeng. Preparation of reduced graphene oxide and study on electrochemical performance of lithium-air battery[D]. Shenzhen: Shenzhen University, 2020.
[112]	GNANA KUMAR G, CHRISTY Maria, JANG Hosaeng, et al. Cobaltite oxide nanosheets anchored graphene nanocomposite as an efficient oxygen reduction reaction (ORR) catalyst for the application of lithium-air batteries[J]. Journal of Power Sources, 2015, 288: 451-460.
[113]	HUANG Cheng-Chia, POURZOLFAGHAR Hamed, HUANG Chengliang, et al. FeNi nanoalloy-carbon nanotubes on defected graphene as an excellent electrocatalyst for lithium-oxygen batteries[J]. Carbon, 2024, 222: 118973-118982.
[114]	LI Zeming, HUANG Simiao, TAO Daiwen, et al. Reduced graphene oxide coated with amorphous lead as positive additive for enhanced performance of lead-carbon batteries[J]. Electrochemistry Communications, 2023, 157: 107622-107630.
[115]	TAO Daiwen, LIU Xiong, LI Zeming, et al. PbO nanoparticles anchored on reduced graphene oxide for enhanced cycle life of lead-carbon battery[J]. Electrochimica Acta, 2022, 432: 141228-141237.
[116]	中商产业研究院. 2024年中国石墨烯行业市场前景预测研究报告[R/OL]. (2024-09-09) .
	Zhongshang Industry Research Institute Co., Ltd.. China graphene market trends and forecast research report 2024[R/OL]. (2024-09-09) .
[117]	网易（杭州）网络有限公司. 石墨烯电池核心科技再创新高度, 中国超威技术实力跻身全球第一[EB/OL]. (2023-04-17) .
	Netease (Hangzhou) Network Co., Ltd.. Core graphene battery technology reaches new peak: chaowei ranked world's #1 in technical capabilities[EB/OL]. (2023-04-17) .
[118]	北京搜狐互联网信息服务有限公司. 超威黑金5.0巅峰性能傲视行业, 中国超威聚力打造品牌新势能[EB/OL].(2023-01-31) .
	Beijing Sohu Internet Information Service Co., Ltd.. Chaowei black gold 5.0 redefines industry standards as china’s leader cultivates new brand value[EB/OL]. (2023-01-31) .
[119]	北京搜狐互联网信息服务有限公司. 东旭光电发售世界首款石墨烯基锂离子电池“烯王”[EB/OL]. (2016-09-09) .
	Beijing Sohu Internet Information Service Co., Ltd.. World premiere: dongxu optoelectronics launches “king of graphene”, the first graphene-powered lithium-ion battery[EB/OL]. (2016-09-09) .
[120]	北京电鳗快报科技有限公司. 碳世纪发布节能环保石墨烯锂离子5号充电电池烯储霸王[EB/OL].(2017-02-24) .
	Beijing Electric Eel Express Technology Co., Ltd.. Carbon century launches eco-friendly graphene lithium-ion 5 rechargeable battery with graphene storage technology[EB/OL]. (2017-02-24) .
[121]	北京商状元科技有限公司. 真正质保2年的电池！京九长征1号重磅上市，带领行业实现质的飞跃[EB/OL].(2021-08-28) .
	Beijing Business Champion Technology Co., Ltd.. Jingjiu relaunches long march 1 battery with industry-leading 2-year warranty, marking technical breakthrough[EB/OL]. (2021-08-28) .