Chemical Industry and Engineering Progress ›› 2020, Vol. 39 ›› Issue (S2): 440-446.DOI: 10.16085/j.issn.1000-6613.2020-1872

• Resources and environmental engineering • Previous Articles     Next Articles

Influence of additives on the electrowinning process of single membrane and double chamber in the same cell

Yangyang ZHENG1,2(), Xiaosan SONG1,2(), Sanfan WANG1,2, Zhihua ZHANG3, Zhengping SONG3, Lin MA3   

  1. 1.School of Environmental and Municipal Engineering, Lanzhou Jiaotong University, Lanzhou 730070, Gansu, China
    2.Engineering Research Center of Ministry of Education for Comprehensive Utilization of Water Resources in Cold and Drought Areas, Lanzhou Jiaotong University, Lanzhou 730070, Gansu, China
    3.Ningxia Tianyuan Manganese Material Research Institute, Zhongning 755100, Ningxia, China
  • Received:2020-09-15 Online:2020-11-17 Published:2020-11-20
  • Contact: Xiaosan SONG

添加剂对单膜双室同槽电解膜电积工艺的影响

郑洋洋1,2(), 宋小三1,2(), 王三反1,2, 张志华3, 宋正平3, 马林3   

  1. 1.兰州交通大学环境与市政工程学院,甘肃 兰州 730070
    2.兰州交通大学寒旱地区水资源综合利用教育部工程研究中心,甘肃 兰州 730070
    3.宁夏天元锰材料研究院,宁夏 中宁 755100
  • 通讯作者: 宋小三
  • 作者简介:郑洋洋(1994—),男,硕士研究生,研究方向为重金属回收与资源化利用。E-mail:zhengyy8018@163.com
  • 基金资助:
    国家科技支撑计划(2015BAE04B01);国家自然科学基金(21466019);宁夏回族自治区重点研发计划重点项目(2020BDE92023)

Abstract:

The single membrane double chamber membrane electrowinning process is used to electrodeposit manganese metal in the MnSO4+(NH4)2SO4 electrolyte system. At the same time, the anode co-produces electrolytic manganese dioxide and enriches and recovers sulfuric acid. The effect of two typical inorganic and organic compound additives selenious acid, polyacrylamide+thiourea on the effect of membrane electrowinning was studied. The results showed that the use of additives in the single membrane, double chamber, same-cell electrolysis process greatly improved the manganese production rate, acid recovery rate and energy consumption. When the optimal concentration of the inorganic additive selenite is 0.3g/L, the manganese production rate can reach 84.9%, the acid recovery rate is 79.5%, and the energy consumption is 5545kW·h/t; When the concentration of the organic compound additive polyacrylamide is 0.01g/L and thiourea is 0.02g/L, the manganese production rate can reach 75.1%, the acid recovery rate is 76.5%, and the energy consumption is 6034kW·h/t. At this time, the surface of the electrodeposited manganese is white, bright, uniform and detailed, and its morphology and quality are greatly improved.

Key words: single membrane double chamber, additive, manganese production rate, acid recovery rate, energy consumption

摘要:

采用单膜双室膜电积工艺在MnSO4+(NH4)2SO4电解液体系中电沉积金属锰,同时阳极联产电解二氧化锰并富集回收硫酸,研究了两种典型无机、有机复合添加剂亚硒酸、聚丙烯酰胺+硫脲对膜电积工艺效果的影响。结果表明,单膜双室同槽电解工艺中添加剂的使用对产锰率、酸回收率以及能耗等都有较大改善。无机添加剂亚硒酸的最适浓度在0.3g/L时,其产锰率可达84.9%,酸回收率为79.5%,能耗为5545kW·h/t;有机复合添加剂聚丙烯酰胺浓度为0.01g/L、硫脲浓度为0.02g/L时,其产锰率可达75.1%,酸回收率为76.5%,能耗为6034kW·h/t,此时电沉积锰表面白皙光亮、均匀细致,其形貌、质量都有很大的改观。

关键词: 单膜双室, 添加剂, 产锰率, 酸回收率, 能耗

CLC Number: 

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