Chemical Industry and Engineering Progress ›› 2021, Vol. 40 ›› Issue (5): 2603-2612.DOI: 10.16085/j.issn.1000-6613.2020-0573
• Industrial catalysis • Previous Articles Next Articles
TAO Ning(), XU Yajin, FENG Yuchen, LYU Jianhua, LIU Jidong()
Received:
2020-04-13
Online:
2021-05-24
Published:
2021-05-06
Contact:
LIU Jidong
通讯作者:
刘继东
作者简介:
陶宁(1994—),女,硕士研究生,研究方向为绿色催化过程与工艺。E-mail:CLC Number:
TAO Ning, XU Yajin, FENG Yuchen, LYU Jianhua, LIU Jidong. ZrO2-Al2O3 composite oxide for synthesis of dimethyl carbonate in catalytic reactive distillation[J]. Chemical Industry and Engineering Progress, 2021, 40(5): 2603-2612.
陶宁, 徐亚津, 冯宇辰, 吕建华, 刘继东. ZrO2-Al2O3复合氧化物催化反应精馏合成碳酸二甲酯[J]. 化工进展, 2021, 40(5): 2603-2612.
Add to citation manager EndNote|Ris|BibTeX
URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2020-0573
样品 | 结合能/eV | 表面原子比① Al/(Zr+Al) | 体相中原子比② Al/(Zr+Al) | ||
---|---|---|---|---|---|
Zr 3d5/2 | Al 2p3/2 | O 1s | |||
ZrO2 | 182.8 | — | 530.3 | — | — |
ZA-30 | 182.5 | 73.8 | 530.5 | 0.27 | 0.26 |
ZA-50 | 182.6 | 73.7 | 530.7 | 0.49 | 0.51 |
ZA-70 | 182.4 | 73.7 | 531.3 | 0.68 | 0.69 |
ZA-80 | 182.2 | 73.5 | 531.5 | 0.87 | 0.82 |
Al2O3 | — | 73.3 | 531.7 | — | — |
样品 | 结合能/eV | 表面原子比① Al/(Zr+Al) | 体相中原子比② Al/(Zr+Al) | ||
---|---|---|---|---|---|
Zr 3d5/2 | Al 2p3/2 | O 1s | |||
ZrO2 | 182.8 | — | 530.3 | — | — |
ZA-30 | 182.5 | 73.8 | 530.5 | 0.27 | 0.26 |
ZA-50 | 182.6 | 73.7 | 530.7 | 0.49 | 0.51 |
ZA-70 | 182.4 | 73.7 | 531.3 | 0.68 | 0.69 |
ZA-80 | 182.2 | 73.5 | 531.5 | 0.87 | 0.82 |
Al2O3 | — | 73.3 | 531.7 | — | — |
样品 | 比表面积/m2·g-1 | 孔容/cm3·g-1 | 平均孔径/nm |
---|---|---|---|
ZrO2 | 8.4 | 0.02 | 1.19 |
ZA-30 | 18.5 | 0.07 | 1.19 |
ZA-50 | 80.7 | 0.18 | 1.15 |
ZA-70 | 43.9 | 0.16 | 1.18 |
ZA-80 | 20.6 | 0.09 | 1.19 |
Al2O3 | 279.8 | 0.45 | 1.16 |
样品 | 比表面积/m2·g-1 | 孔容/cm3·g-1 | 平均孔径/nm |
---|---|---|---|
ZrO2 | 8.4 | 0.02 | 1.19 |
ZA-30 | 18.5 | 0.07 | 1.19 |
ZA-50 | 80.7 | 0.18 | 1.15 |
ZA-70 | 43.9 | 0.16 | 1.18 |
ZA-80 | 20.6 | 0.09 | 1.19 |
Al2O3 | 279.8 | 0.45 | 1.16 |
样品 | ATotal/mmol·g-1 | AW/mmol·g-1 | AM/mmol·g-1 | AS/mmol·g-1 | BTotal/mmol·g-1 | BW/mmol·g-1 | BM/mmol·g-1 | BS/mmol·g-1 |
---|---|---|---|---|---|---|---|---|
ZrO2 | 2.92 | 1.98 | 0.64 | 0.30 | 1.34 | 0.88 | 0.35 | 0.11 |
ZA-30 | 3.85 | 2.22 | 1.14 | 0.49 | 3.78 | 1.05 | 1.26 | 1.47 |
ZA-50 | 3.95 | 2.24 | 1.17 | 0.54 | 4.53 | 1.12 | 1.54 | 1.87 |
ZA-70 | 3.97 | 2.20 | 1.14 | 0.63 | 3.96 | 1.26 | 1.42 | 1.28 |
ZA-80 | 4.03 | 2.16 | 1.15 | 0.72 | 3.36 | 1.55 | 0.77 | 1.04 |
Al2O3 | 4.11 | 2.08 | 1.19 | 0.84 | 2.13 | 0.96 | 0.69 | 0.48 |
样品 | ATotal/mmol·g-1 | AW/mmol·g-1 | AM/mmol·g-1 | AS/mmol·g-1 | BTotal/mmol·g-1 | BW/mmol·g-1 | BM/mmol·g-1 | BS/mmol·g-1 |
---|---|---|---|---|---|---|---|---|
ZrO2 | 2.92 | 1.98 | 0.64 | 0.30 | 1.34 | 0.88 | 0.35 | 0.11 |
ZA-30 | 3.85 | 2.22 | 1.14 | 0.49 | 3.78 | 1.05 | 1.26 | 1.47 |
ZA-50 | 3.95 | 2.24 | 1.17 | 0.54 | 4.53 | 1.12 | 1.54 | 1.87 |
ZA-70 | 3.97 | 2.20 | 1.14 | 0.63 | 3.96 | 1.26 | 1.42 | 1.28 |
ZA-80 | 4.03 | 2.16 | 1.15 | 0.72 | 3.36 | 1.55 | 0.77 | 1.04 |
Al2O3 | 4.11 | 2.08 | 1.19 | 0.84 | 2.13 | 0.96 | 0.69 | 0.48 |
样品 | 比表面积 /m2·g-1 | 孔容 /cm3·g-1 | 平均孔径 /nm | 催化剂组分①/% | |
---|---|---|---|---|---|
Zr | Al | ||||
新鲜的ZA-50 | 80.77 | 0.18 | 1.15 | 50.12 | 49.88 |
使用过的ZA-50 | 67.89 | 0.17 | 1.17 | 50.28 | 49.72 |
样品 | 比表面积 /m2·g-1 | 孔容 /cm3·g-1 | 平均孔径 /nm | 催化剂组分①/% | |
---|---|---|---|---|---|
Zr | Al | ||||
新鲜的ZA-50 | 80.77 | 0.18 | 1.15 | 50.12 | 49.88 |
使用过的ZA-50 | 67.89 | 0.17 | 1.17 | 50.28 | 49.72 |
样品 | ATotal/mmol·g-1 | AW/mmol·g-1 | AM/mmol·g-1 | AS/mmol·g-1 | BTotal/mmol·g-1 | BW/mmol·g-1 | BM/mmol·g-1 | BS/mmol·g-1 |
---|---|---|---|---|---|---|---|---|
新鲜的ZA-50 | 3.95 | 2.24 | 1.17 | 0.54 | 4.53 | 1.12 | 1.54 | 1.87 |
使用过的ZA-50 | 3.87 | 2.18 | 1.12 | 0.57 | 4.42 | 1.24 | 1.42 | 1.76 |
样品 | ATotal/mmol·g-1 | AW/mmol·g-1 | AM/mmol·g-1 | AS/mmol·g-1 | BTotal/mmol·g-1 | BW/mmol·g-1 | BM/mmol·g-1 | BS/mmol·g-1 |
---|---|---|---|---|---|---|---|---|
新鲜的ZA-50 | 3.95 | 2.24 | 1.17 | 0.54 | 4.53 | 1.12 | 1.54 | 1.87 |
使用过的ZA-50 | 3.87 | 2.18 | 1.12 | 0.57 | 4.42 | 1.24 | 1.42 | 1.76 |
1 | TAN H Z, WANG Z Q, XU Z N, et al. Review on the synthesis of dimethyl carbonate[J]. Catalysis Today, 2018, 316: 2-12. |
2 | 李波, 宋淑群, 汪志国. 碳酸二甲酯发展现状及前景[J]. 精细石油化工进展, 2011, 12(6): 38-41. |
LI Bo, SONG Shuqun, WANG Zhiguo. Development and application prospect of dimethyl carbonate[J]. Advances in Fine Petrochemicals, 2011, 12(6): 38-41. | |
3 | PACHECO M A, MARSHALL C L. Review of dimethyl carbonate (DMC) manufacture and its characteristics as a fuel additive[J]. Energy & Fuels, 1997, 11(1): 2-29. |
4 | 杜治平, 黄丽明, 林志坤, 等. 甲醇氧化羰基化合成碳酸二甲酯反应机理研究进展[J]. 化工进展, 2012, 31(10): 2213-2220. |
DU Z P, HUANG L M, LIN Z K, et.al. Mechanism for the synthesis of dimethyl carbonate from oxidative carbonylation of methanol[J]. Chemical Industry and Engineering Progress, 2012, 31(10): 2213-2220. | |
5 | 宋一兵, 罗爱国, 杜玉海, 等. 甲醇直接气相氧化羰基化合成碳酸二甲酯[J]. 化学进展, 2008, 20(S1): 221-226. |
SONG Y B, LUO A G, DU Y H, et al. Synthesis of dimethyl carbonate by direct vapor-phase oxycarbonylation of methanol[J]. Progress in Chemistry, 2008, 20(S1): 221-226. | |
6 | 杨彩虹, 李文彬, 柳玉琴, 等. 甲醇和碳酸丙烯酯合成碳酸二甲酯的研究[J]. 燃料化学学报, 2002, 30(6): 551-554. |
YANG C H, LI W B, LIU Y Q, et.al. Synthesis of dimethyl carbonate from methanol and propylene carbonate[J]. Journal of Fuel Chemistry and Technology, 2002, 30(6): 551-554. | |
7 | JEONG E S, KIM K H, PARK D W, et al. Synthesis of dimethyl carbonate and propylene glycol from transesterification of propylene carbonate and methanol using quaternary ammonium salt catalysts[J]. Reaction Kinetics and Catalysis Letters, 2005, 86(2): 241-248. |
8 | SEGOVIA-HERNÁNDEZ J G, HERNÁNDEZ S, BONILLA PETRICIOLET A. Reactive distillation: a review of optimal design using deterministic and stochastic techniques[J]. Chemical Engineering and Processing: Process Intensification, 2015, 97: 134-143. |
9 | 姜忠义, 王泳. 酯交换法合成碳酸二甲酯的催化精馏过程研究[J] .化学工程, 2001, 29(3): 29-32. |
JIANG Z Y, WANG Y. Preparation of dimethyl carbonate through transesterification in a catalytic distillation column[J]. Chemical Engineering, 2001, 29(3): 29-32. | |
10 | HOLTBRUEGGE J, WIERSCJEM M, LUTZE P. Synthesis of dimethyl carbonate and propylene glycol in a membrane-assisted reactive distillation process pilot-scale experiments, modeling and process analysis[J]. Chemical Engineering and Processing: Process Intersification, 2014, 84(4): 54-70. |
11 | HOLTBRUEGGE J, LEIMBRINK M, LUTZE P, et al. Synthesis of dimethyl carbonate and propylene glycol by transesterification of propylene carbonate with methanol: catalyst screening, chemical equilibrium and reaction kinetics[J]. Chemical Engineering Science, 2013, 104(50): 347-360. |
12 | WEI T, WANG M, WEI W. Synthesis of dimethyl carbonate by transesterification over CaO/carbon solid base catalysts[J]. Chinese Academic of Sciences, 2004, 153: 41-46. |
13 | SONG Z, JIN X, HU Y, et al. Intriguing catalyst (CaO) pretreatment effects and mechanistic insights during propylene carbonate transesterification with methanol[J]. ACS Sustainable Chem. Eng., 2017, 5: 4718-4729. |
14 | KUMAR P, SRIVASTAVA V C, MISHRA I M. Synthesis and characterization of Ce-La oxides for the formation of dimethyl carbonate by transesterification of propylene carbonate[J]. Catalysis Communications, 2015, 60: 27-31. |
15 | KUMAR, P, SRIVASTAVA V C, MISHRA I M. Dimethyl carbonate synthesis by transesterification of propylene carbonate with methanol: comparative assessment of Ce-M (M=Co, Fe, Cu and Zn) catalysts[J]. Renewable Energy, 2016, 88: 457-464. |
16 | KUMAR P, SRIVASTAVA V C, MISHRA I M. Dimethyl carbonate synthesis via transesterification of propylene carbonate with methanol by ceria-zinc catalysts: role of catalyst support and reaction parameters[J]. Korean Journal of Chemical Engineering, 2015, 32(9): 1774-1783. |
17 | SONG J H, JUN J O, KANG K H, et.al. Synthesis of dimethyl carbonate from propylene carbonate and methanol over Y2O3/CeO2-La2O3 catalysts[J]. Journal of Nanoscience and Nanotechnology, 2016, 16(10): 10810-10815. |
18 | WANG H, WANG M H, LIU S G, et al. Influence of preparation methods on the structure and performance of CaO-ZrO2 catalyst for the synthesis of dimethyl carbonate via transesterification[J]. Journal of Molecular Catalysis A: Chemical, 2006, 258: 308-312. |
19 | WANG H, SHI S, WANG Y, et al. CaF2-doped ZrO2: a base catalyst for synthesis of dimethyl carbonate[J]. Journal of Shanghai University, 2010, 14(4): 281-285. |
20 | MERCERA P D L, OMMEN J G VAN, DOESBURG E B M, et al. Zirconia as a support for catalysts Influence of additives on the thermal stability of the porous texture of monoclinic zirconia[J]. Applied Catalysis, 1991, 71(2): 363-391. |
21 | DOMINGUEZ J M, HERNANDEZ J L, SANDOVAL G. Surface and catalytic properties of Al2O3-ZrO2 solid solutions prepared by sol-gel methods[J]. Applied Catalysis A: General, 2000, 197: 119-130. |
22 | KUŚTROWSKI P, CHMIELARZ L, BOŹEK E, et al. Acidity and basicity of hydrotalcite derived mixed Mg-Al oxides studied by test reaction of MBOH conversion and temperature programmed desorption of NH3 and CO2[J]. Materials Research Bulletin, 2004, 39(2): 263-281. |
23 | VÁZQUEZ A, L􀆕PEZ T, GMEZ R,et al. X-ray diffraction, FTIR, and NMR characterization of sol-gel alumina doped with lanthanum and cerium[J]. Journal of Solid State Chemistry, 1997, 128(2): 161-168. |
24 | MORÁN-PINEDA M, CASTILLO S, L􀆕PEZ T,et al. Synthesis, characterization and catalytic activity in the reduction of NO by CO on alumina-zirconia sol-gel derived mixed oxides[J]. Applied Catalysis B: Environmental, 1999, 21(2): 79-88. |
25 | WANG J J, TANG C Z, LI G N, et al. High performance MaZrOx(Ma=Cd, Ga) solid solution catalysts for CO2 hydrogenation to methanol[J]. ACS Catalysis, 2019, 9: 10253-10259. |
26 | TAMBOLI A H, CHAUGULE A A, GOSAVI S W, et al. CexZr1-xO2 solid solutions for catalytic synthesis of dimethyl carbonate from CO2: reaction mechanism and the effect of catalyst morphology on catalytic activity[J]. Fuel, 2018, 216: 245-254. |
27 | LI G R, LI W, ZHANG M H, et al. Characterization and catalytic application of homogeneous nano-composite oxides ZrO2-Al2O3[J]. Catalysis Today, 2004, 93-95: 595-601. |
28 | PRESOTT H A, LI Z J, KEMNIZ E, et al. Application of calcined Mg-Al hydrotalcites for Michael additions: an investigation of catalytic activity and acid-base properties[J]. Journal of Catalysis, 2005, 234(1): 119-130. |
29 | MEHER L C, GOPINATH R, NAIK S N, et al. Catalytic hydrogenolysis of glycerol to propylene glycol over mixed oxides derived from a hydrotalcite-type precursor[J]. Industrial & Engineering Chemistry Research, 2009, 48(4): 1840-1846. |
30 | CANTRELL D G, GILLIE L J, LEE A F, et al. Structure-reactivity correlations in MgAl hydrotalcite catalysts for biodiesel synthesis[J]. Applied Catalysis A: General, 2005, 287(2): 183-190. |
31 | 李东. 介孔Ni-Al复合氧化物的结构及其催化乙烷氧化脱氢反应方法的分析[D]. 沈阳: 沈阳师范大学, 2019. |
LI D. Structure of mesoporous Ni-Al composite oxides and its catalytic dehydrogenation of ethane[D]. Shenyang: Shenyang Normal University, 2019. | |
32 | YAN T, BING W, XU M, et al. Acid-base sites synergistic catalysis over Mg-Zr-Al mixed metal oxide toward synthesis of diethyl carbonate[J]. RSC Advances, 2018, 8(9): 4695-4702. |
33 | LIAO Y H, LI F, DAI X, et al. Dimethyl carbonate synthesis over solid base catalysts derived from Ca-Al layered double hydroxides[J]. Chemical Papers, 2018, 72: 1963-1971. |
34 | WANG D F, ZHANG X L, CONG X S, et al. Influence of Zr on the performance of Mg-Al catalysts via hydrotalcite-like precursors for the synthesis of glycerol carbonate from urea and glycerol[J]. Applied Catalysis A: General, 2018, 555: 36-46. |
35 | ZHANG J, YAN T, YANG Y, et al. Zn-Zr-Al oxides derived from hydrotalcite precursors for ethanol conversion to diethyl carbonate[J]. Chinese Journal of Catalysis, 2019, 40(4): 515-522. |
36 | LI C, HE B, LING Y, et al. Glycerol hydrogenolysis to n-propanol over Zr-Al composite oxide-supported Pt catalysts[J]. Chinese Journal of Catalysis, 2018, 39(6): 1121-1128. |
37 | XU J, WU H T, MA C M, et al. Ionic liquid immobilized on mesocellular silica foam as an efficient heterogeneous catalyst for the synthesis of dimethyl carbonate via transesterification[J]. Applied Catalysis A: General, 2013, 464/465: 357-363. |
38 | WANG H, WANG M, ZHANG W, et al. Synthesis of dimethyl carbonate from propylene carbonate and methanol using CaO-ZrO2 solid solutions as highly stable catalysts[J]. Catalysis Today, 2006, 115(1-4): 107-110. |
39 | CROCELLA V, TABANELLI T, VITILLO J G, et al. A multi-technique approach to disclose the reaction mechanism of dimethyl carbonate synthesis over amino-modified SBA-15 catalysts[J]. Applied Catalysis B: Environmental, 2017, 211: 323-336. |
40 | SONG Z, SUBRAMANIAM B, CHAUDHARI R V. Transesterification of propylene carbonate with methanol using Fe-Mn double metal cyanide catalyst[J]. ACS Sustain. Chem. Eng.,2019, 7: 5698-5710. |
41 | TAYLOR R, KRISHNA R. Modelling reactive distillation[J]. Chemical Engineering Science, 2000, 55(22): 5183-5229. |
[1] | CHEN Danyang, ZHU Jianyu, WU Qin, WANG Ziqing, ZHANG Jinli. KF/MgO catalyzed transesterification of glycerol and dimethyl carbonate to glycerol carbonate [J]. Chemical Industry and Engineering Progress, 2022, 41(4): 2082-2089. |
[2] | LIN Zixin, TIAN Wei, AN Weizhong. Separation of dimethyl carbonate/methanol via heat pump assisted pressure swing distillation process and system simulation optimization [J]. Chemical Industry and Engineering Progress, 2022, 41(11): 5722-5730. |
[3] | ZHU Changhui, ZHU Wenchao, LUO Jia, TIAN Baohe, SUN Jialin, ZOU Zhiyun. Recent advances in microwave-intensified transesterification for biodiesel preparation [J]. Chemical Industry and Engineering Progress, 2022, 41(10): 5145-5154. |
[4] | YUE Qianqian, GAO Lijing, XIAO Guomin, WEI Ruiping, LEI Yan. Process of the reactor and progress of biodiesel continuous production [J]. Chemical Industry and Engineering Progress, 2021, 40(S2): 81-88. |
[5] | WANG Yuchun, ZHANG Zhihao, GAO Yuan, LI Zhong, ZHENG Huayan. Extractive distillation separation process of DMC-methanol-water ternary mixture [J]. Chemical Industry and Engineering Progress, 2021, 40(8): 4196-4204. |
[6] | KONG Huina, ZHEGN Wei, CAO Hailong, HUANG Guiming. Process optimization of dimethyl carbonate rectifying in coal-to-ethylene glycol plant [J]. Chemical Industry and Engineering Progress, 2021, 40(7): 3626-3631. |
[7] | Yuchun WANG, Zhaorong LIU, Chao TAN, Hong SUN, Zhong LI. Preparation of chlorine-free CuY catalysts by vapour impregnation and their application for oxidative carbonylation [J]. Chemical Industry and Engineering Progress, 2021, 40(1): 242-246. |
[8] | Jun WANG, Yan ZHAO, Xin ZOU, Na LIU, Jie XU, Bing XUE. Synthesis of ethylene carbonate by transesterification over KF modified MgAl hydrotalcite catalyst [J]. Chemical Industry and Engineering Progress, 2020, 39(7): 2670-2676. |
[9] | Jie ZHANG, Aizhong JIA, Fang LI, Xinqiang ZHAO, Yanji WANG. Research progress on catalysts for synthesis of ethyl methyl carbonate by transesterification [J]. Chemical Industry and Engineering Progress, 2020, 39(11): 4435-4445. |
[10] | Yuchen SUN,Guoqiang ZHANG,Bin LIU,Zhong LI,Ju SHANGGUAN,Shoujun LIU,Pengzheng SHI. Progress of the coupled dehydration systems for synthesis of dimethyl carbonate from CO2 and methanol [J]. Chemical Industry and Engineering Progress, 2019, 38(11): 5127-5135. |
[11] | Dongsen JIA,Guoqiang ZHANG,Jiao YIN,Liangliang ZHANG,Dan ZHAO,Huayan ZHENG,Zhong LI. Effect of surface defects density of carbon spheres on the catalytic performance of the supported Cu catalyst for oxidativecarbonylation of methanol [J]. Chemical Industry and Engineering Progress, 2019, 38(08): 3701-3710. |
[12] | ZOU Jianjun, LU Ting, WANG Jiaxi. Syntheses and UV curing properties of urethane acrylates [J]. Chemical Industry and Engineering Progress, 2019, 38(04): 1947-1952. |
[13] | Xiangcong PENG,Zhimiao WANG,Hongqin LI,Wei XUE,Fang LI,Yanji WANG. Preparation of Zn(OAc)2/SiO2 catalyst with better stability prepared by solvothermal impregnation method and its application in methyl N-phenyl carbamate [J]. Chemical Industry and Engineering Progress, 2019, 38(03): 1396-1402. |
[14] | YUAN Chuan, LU Houfang, LIU Changjun, JIANG Wei, LIU Yingying, LIANG Bin. Effects of water and free fatty acids on biodiesel production using DBU as catalyst [J]. Chemical Industry and Engineering Progress, 2018, 37(09): 3386-3392. |
[15] | SONG Menglu, YANG Xiangui, CAI Xiaodong, WANG Gongying. Process in the preparation and application of polycarbonate diols [J]. Chemical Industry and Engineering Progress, 2018, 37(06): 2295-2301. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||
京ICP备12046843号-2;京公网安备 11010102001994号 Copyright © Chemical Industry and Engineering Progress, All Rights Reserved. E-mail: hgjz@cip.com.cn Powered by Beijing Magtech Co. Ltd |