Chemical Industry and Engineering Progress ›› 2018, Vol. 37 ›› Issue (06): 2295-2301.DOI: 10.16085/j.issn.1000-6613.2017-1505

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Process in the preparation and application of polycarbonate diols

SONG Menglu1,2, YANG Xiangui1, CAI Xiaodong1,2, WANG Gongying1   

  1. 1 Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, Sichuan, China;
    2 University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2017-07-20 Revised:2017-09-26 Online:2018-06-05 Published:2018-06-05

聚碳酸酯二元醇的合成及应用研究进展

宋孟璐1,2, 杨先贵1, 蔡晓东1,2, 王公应1   

  1. 1 中国科学院成都有机化学研究所, 四川 成都 610041;
    2 中国科学院大学, 北京 100049
  • 通讯作者: 杨先贵,研究员,博士生导师,主要从事催化剂和精细化工的研究。
  • 作者简介:宋孟璐(1989-),女,博士研究生,主要从事聚碳酸酯二元醇合成催化剂的研究。E-mail:songlzw@163.com。
  • 基金资助:
    国家科技支撑计划(2013BAC11B05)及四川省科技支撑计划(2016GZ0228)项目。

Abstract: Polycarbonate diols (PCDL) is an important raw material for the synthesis of polycarbonate-based polyurethane. Compared with traditional polyether-or polyester-based polyurethane, the polycarbonate-based polyurethane shows better hydrolytic resistance, mechanical properties and superior antistatic biocompatibility. With the increasing demand of polyurethane, the research on PCDL has got more and more attention. In this paper, the synthesis methods of PCDL were introduced briefly, and then the catalysts for the transesterification method in last decades were reviewed in detail. Moreover, the application of PCDL in polyurethane industry was also introduced. In the future, it should pay more attention to the heterogeneous catalyst or organic base catalyst with high boiling point and the preparation of PCDL with diverse structures.

Key words: polycarbonate diols(PCDL), polyurethane, transesterification, catalysts, application

摘要: 聚碳酸酯二元醇(PCDL)是制备聚碳酸酯型聚氨酯的重要原料,和传统的聚醚型聚氨酯和聚酯型聚氨酯相比,聚碳酸酯型聚氨酯表现出优异的耐水解性、力学性能和生物相容性。随着聚氨酯需求量的增长,聚碳酸酯二元醇的研究受到行业内的高度重视。本文先简要介绍了PCDL的合成方法,重点回顾了近十年来用于酯交换缩聚法制备PCDL的催化剂的研究进展,简述了PCDL在聚氨酯工业中的应用。未来开发非均相催化剂及高沸点的有机碱催化剂、制备不同结构的聚碳酸酯二元醇是PCDL的主要研究方向。

关键词: 聚碳酸酯二元醇, 聚氨酯, 酯交换, 催化剂, 应用

CLC Number: 

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