Chemical Industry and Engineering Progress ›› 2020, Vol. 39 ›› Issue (4): 1550-1557.DOI: 10.16085/j.issn.1000-6613.2019-1162
• Resources and environmental engineering • Previous Articles Next Articles
Chunshan ZHU(),Zhengxin MAO,Lin GAO
Received:
2019-07-19
Online:
2020-04-28
Published:
2020-04-05
Contact:
Chunshan ZHU
通讯作者:
朱春山
作者简介:
朱春山(1968—),男,教授,硕士生导师,研究方向为天然产物基功能高分子。E-mail:基金资助:
CLC Number:
Chunshan ZHU,Zhengxin MAO,Lin GAO. Preparation of furfural residue lignin/poluethyleneimine microspheres[J]. Chemical Industry and Engineering Progress, 2020, 39(4): 1550-1557.
朱春山,毛正鑫,高琳. 糠醛渣木质素/聚乙烯亚胺微球的制备[J]. 化工进展, 2020, 39(4): 1550-1557.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2019-1162
木质素用量/g | 平均粒径/μm | 平均粒径标准差 | |||
---|---|---|---|---|---|
0.400 | 282 | 292 | 284 | 292 | 4.68 |
0.500 | 191 | 192 | 199 | 207 | 6.44 |
0.600 | 241 | 251 | 249 | 240 | 5.00 |
0.700 | 187 | 175 | 175 | 186 | 5.49 |
0.900 | 181 | 170 | 184 | 168 | 6.83 |
木质素用量/g | 平均粒径/μm | 平均粒径标准差 | |||
---|---|---|---|---|---|
0.400 | 282 | 292 | 284 | 292 | 4.68 |
0.500 | 191 | 192 | 199 | 207 | 6.44 |
0.600 | 241 | 251 | 249 | 240 | 5.00 |
0.700 | 187 | 175 | 175 | 186 | 5.49 |
0.900 | 181 | 170 | 184 | 168 | 6.83 |
实验水平 | 温度/℃ | PEI/g | 木质素/g | 交联剂/mL | 油水比 | 分散剂/g |
---|---|---|---|---|---|---|
1 | 56 | 1.75 | 0.400 | 1.50 | 3.0∶1 | 0.050 |
2 | 60 | 2.00 | 0.500 | 1.75 | 3.5∶1 | 0.075 |
3 | 64 | 2.25 | 0.600 | 2.00 | 4.0∶1 | 0.100 |
4 | 68 | 2.50 | 0.700 | 2.25 | 4.5∶1 | 0.125 |
5 | 72 | 2.75 | 0.800 | 2.50 | 5.0∶1 | 0.150 |
实验水平 | 温度/℃ | PEI/g | 木质素/g | 交联剂/mL | 油水比 | 分散剂/g |
---|---|---|---|---|---|---|
1 | 56 | 1.75 | 0.400 | 1.50 | 3.0∶1 | 0.050 |
2 | 60 | 2.00 | 0.500 | 1.75 | 3.5∶1 | 0.075 |
3 | 64 | 2.25 | 0.600 | 2.00 | 4.0∶1 | 0.100 |
4 | 68 | 2.50 | 0.700 | 2.25 | 4.5∶1 | 0.125 |
5 | 72 | 2.75 | 0.800 | 2.50 | 5.0∶1 | 0.150 |
实验号 | 温度/℃ | PEI/g | 木质素/g | EPI/mL | 油水比 | 分散剂/g | 平均粒径/μm | 分散度 |
---|---|---|---|---|---|---|---|---|
1 | 56 | 1.75 | 0.400 | 1.50 | 3.0∶1 | 0.050 | 188 | 0.256 |
2 | 56 | 2.00 | 0.500 | 1.75 | 3.5∶1 | 0.075 | 182 | 0.378 |
3 | 56 | 2.25 | 0.600 | 2.00 | 4.0∶1 | 0.100 | 131 | 0.425 |
4 | 56 | 2.50 | 0.700 | 2.25 | 4.5∶1 | 0.125 | 127 | 0.348 |
5 | 56 | 2.75 | 0.800 | 2.50 | 5.0∶1 | 0.150 | 149 | 0.322 |
6 | 60 | 1.75 | 0.500 | 2.00 | 4.5∶1 | 0.150 | 266 | 0.297 |
7 | 60 | 2.00 | 0.600 | 2.25 | 5.0∶1 | 0.050 | 132 | 0.332 |
8 | 60 | 2.25 | 0.700 | 2.50 | 3.0∶1 | 0.075 | 176 | 0.329 |
9 | 60 | 2.50 | 0.800 | 1.50 | 3.5∶1 | 0.100 | 184 | 0.372 |
10 | 60 | 2.75 | 0.400 | 1.75 | 4.0∶1 | 0.125 | 227 | 0.259 |
11 | 64 | 1.75 | 0.600 | 2.50 | 3.5∶1 | 0.125 | 213 | 0.261 |
12 | 64 | 2.00 | 0.700 | 1.50 | 4.0∶1 | 0.150 | 238 | 0.248 |
13 | 64 | 2.25 | 0.800 | 1.75 | 4.5∶1 | 0.050 | 150 | 0.395 |
14 | 64 | 2.50 | 0.400 | 2.00 | 5.0∶1 | 0.075 | 211 | 0.208 |
15 | 64 | 2.75 | 0.500 | 2.25 | 3.0∶1 | 0.100 | 207 | 0.231 |
16 | 68 | 1.75 | 0.700 | 1.75 | 5.0∶1 | 0.100 | 264 | 0.191 |
17 | 68 | 2.00 | 0.800 | 2.00 | 3.0∶1 | 0.125 | 251 | 0.210 |
18 | 68 | 2.25 | 0.400 | 2.25 | 3.5∶1 | 0.150 | 208 | 0.205 |
19 | 68 | 2.50 | 0.500 | 2.50 | 4.0∶1 | 0.050 | 376 | 0.305 |
20 | 68 | 2.75 | 0.600 | 1.50 | 4.5∶1 | 0.100 | 226 | 0.326 |
21 | 72 | 1.75 | 0.800 | 2.25 | 4.0∶1 | 0.075 | 208 | 0.320 |
22 | 72 | 2.00 | 0.400 | 2.50 | 4.5∶1 | 0.100 | 181 | 0.311 |
23 | 72 | 2.25 | 0.500 | 1.50 | 5.0∶1 | 0.125 | 214 | 0.286 |
24 | 72 | 2.50 | 0.600 | 1.75 | 3.0∶1 | 0.150 | 178 | 0.221 |
25 | 72 | 2.75 | 0.700 | 2.00 | 3.5∶1 | 0.050 | 170 | 0.234 |
均值1 | 155 | 228 | 203 | 210 | 200 | 203 | — | — |
均值2 | 197 | 197 | 249 | 200 | 191 | 194 | — | — |
均值3 | 204 | 176 | 176 | 206 | 236 | 199 | — | — |
均值4 | 265 | 215 | 195 | 176 | 190 | 206 | — | — |
均值5 | 190 | 196 | 188 | 219 | 194 | 208 | — | — |
极差 | 110 | 52.23 | 72.73 | 42.53 | 45.8 | 14.0 | — | — |
实验号 | 温度/℃ | PEI/g | 木质素/g | EPI/mL | 油水比 | 分散剂/g | 平均粒径/μm | 分散度 |
---|---|---|---|---|---|---|---|---|
1 | 56 | 1.75 | 0.400 | 1.50 | 3.0∶1 | 0.050 | 188 | 0.256 |
2 | 56 | 2.00 | 0.500 | 1.75 | 3.5∶1 | 0.075 | 182 | 0.378 |
3 | 56 | 2.25 | 0.600 | 2.00 | 4.0∶1 | 0.100 | 131 | 0.425 |
4 | 56 | 2.50 | 0.700 | 2.25 | 4.5∶1 | 0.125 | 127 | 0.348 |
5 | 56 | 2.75 | 0.800 | 2.50 | 5.0∶1 | 0.150 | 149 | 0.322 |
6 | 60 | 1.75 | 0.500 | 2.00 | 4.5∶1 | 0.150 | 266 | 0.297 |
7 | 60 | 2.00 | 0.600 | 2.25 | 5.0∶1 | 0.050 | 132 | 0.332 |
8 | 60 | 2.25 | 0.700 | 2.50 | 3.0∶1 | 0.075 | 176 | 0.329 |
9 | 60 | 2.50 | 0.800 | 1.50 | 3.5∶1 | 0.100 | 184 | 0.372 |
10 | 60 | 2.75 | 0.400 | 1.75 | 4.0∶1 | 0.125 | 227 | 0.259 |
11 | 64 | 1.75 | 0.600 | 2.50 | 3.5∶1 | 0.125 | 213 | 0.261 |
12 | 64 | 2.00 | 0.700 | 1.50 | 4.0∶1 | 0.150 | 238 | 0.248 |
13 | 64 | 2.25 | 0.800 | 1.75 | 4.5∶1 | 0.050 | 150 | 0.395 |
14 | 64 | 2.50 | 0.400 | 2.00 | 5.0∶1 | 0.075 | 211 | 0.208 |
15 | 64 | 2.75 | 0.500 | 2.25 | 3.0∶1 | 0.100 | 207 | 0.231 |
16 | 68 | 1.75 | 0.700 | 1.75 | 5.0∶1 | 0.100 | 264 | 0.191 |
17 | 68 | 2.00 | 0.800 | 2.00 | 3.0∶1 | 0.125 | 251 | 0.210 |
18 | 68 | 2.25 | 0.400 | 2.25 | 3.5∶1 | 0.150 | 208 | 0.205 |
19 | 68 | 2.50 | 0.500 | 2.50 | 4.0∶1 | 0.050 | 376 | 0.305 |
20 | 68 | 2.75 | 0.600 | 1.50 | 4.5∶1 | 0.100 | 226 | 0.326 |
21 | 72 | 1.75 | 0.800 | 2.25 | 4.0∶1 | 0.075 | 208 | 0.320 |
22 | 72 | 2.00 | 0.400 | 2.50 | 4.5∶1 | 0.100 | 181 | 0.311 |
23 | 72 | 2.25 | 0.500 | 1.50 | 5.0∶1 | 0.125 | 214 | 0.286 |
24 | 72 | 2.50 | 0.600 | 1.75 | 3.0∶1 | 0.150 | 178 | 0.221 |
25 | 72 | 2.75 | 0.700 | 2.00 | 3.5∶1 | 0.050 | 170 | 0.234 |
均值1 | 155 | 228 | 203 | 210 | 200 | 203 | — | — |
均值2 | 197 | 197 | 249 | 200 | 191 | 194 | — | — |
均值3 | 204 | 176 | 176 | 206 | 236 | 199 | — | — |
均值4 | 265 | 215 | 195 | 176 | 190 | 206 | — | — |
均值5 | 190 | 196 | 188 | 219 | 194 | 208 | — | — |
极差 | 110 | 52.23 | 72.73 | 42.53 | 45.8 | 14.0 | — | — |
因素 | 偏差平方和 | 自由度 | F比 | F临界值 | 显著性 |
---|---|---|---|---|---|
反应温度 | 3.16E4 | 4 | 53.9 | 16.0 | * |
PEI | 8.00E3 | 4 | 13.6 | 16.0 | |
木质素 | 1.55E4 | 4 | 26.5 | 16.0 | * |
EPI | 5.13E3 | 4 | 8.74 | 16.0 | |
油水比 | 7.36E3 | 4 | 12.5 | 16.0 | |
分散剂 | 586 | 4 | 1.00 | 16.0 | |
误差 | 586 | 4 |
因素 | 偏差平方和 | 自由度 | F比 | F临界值 | 显著性 |
---|---|---|---|---|---|
反应温度 | 3.16E4 | 4 | 53.9 | 16.0 | * |
PEI | 8.00E3 | 4 | 13.6 | 16.0 | |
木质素 | 1.55E4 | 4 | 26.5 | 16.0 | * |
EPI | 5.13E3 | 4 | 8.74 | 16.0 | |
油水比 | 7.36E3 | 4 | 12.5 | 16.0 | |
分散剂 | 586 | 4 | 1.00 | 16.0 | |
误差 | 586 | 4 |
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