Chemical Industry and Engineering Progress ›› 2019, Vol. 38 ›› Issue (12): 5314-5322.DOI: 10.16085/j.issn.1000-6613.2018-2318
• Energy processes and technology • Previous Articles Next Articles
Yan ZHAO(),Jingzheng WANG,Yan LI,Li JING,Zaihua WANG,Hong CHEN
Received:
2018-11-28
Online:
2019-12-05
Published:
2019-12-05
Contact:
Yan ZHAO
通讯作者:
赵燕
作者简介:
赵燕(1968—),女,高级工程师,主要从事石油化工领域信息跟踪及战略研究。E-mail:CLC Number:
Yan ZHAO,Jingzheng WANG,Yan LI,Li JING,Zaihua WANG,Hong CHEN. Advance on the preparation of isooctane by C4 hydrocarbon superposition-hydrogenation and its application[J]. Chemical Industry and Engineering Progress, 2019, 38(12): 5314-5322.
赵燕,王景政,李琰,景丽,王在花,陈红. 国内C4烃叠合-加氢工艺制异辛烷技术进展及应用前景分析[J]. 化工进展, 2019, 38(12): 5314-5322.
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项目 | 间接烷基化 | 直接烷基化 |
---|---|---|
原料 | 异丁烯 | 异丁烷和C3~C5烯烃 |
典型工艺 | InAlk | Stratco |
NexOctane | Exxonmobil | |
Alkylate 100SM | CDAlky | |
CDIsoehter | Alkylene | |
OilHyd | ||
反应过程 | 二聚(异丁烯二聚成异辛烯)-加氢(异辛烯加氢成异辛烷) | 加氢(双烯烃选择性加氢成单烯烃)-异构(1-丁烯异构化为2- 丁烯)-烷基化(异丁烷和异丁烯摩尔反应) |
催化剂 | 树脂催化剂,反应条件温和 | 液体酸催化剂,具有腐蚀性、毒性 |
工艺特点 | 无需设定异丁烷量 | 较严格的烷烯比 |
增加加氢工段可代替MTBE装置 | 工业化应用相对广泛 | |
辛烷值高 | 更加绿色环保 | |
产品质量 | 异辛烷含量高,辛烷值高(RON=97~103),蒸汽压稍低(11.7kPa) | 异辛烷含量低,辛烷值略低(RON=97~99),蒸汽压略高(31kPa) |
项目 | 间接烷基化 | 直接烷基化 |
---|---|---|
原料 | 异丁烯 | 异丁烷和C3~C5烯烃 |
典型工艺 | InAlk | Stratco |
NexOctane | Exxonmobil | |
Alkylate 100SM | CDAlky | |
CDIsoehter | Alkylene | |
OilHyd | ||
反应过程 | 二聚(异丁烯二聚成异辛烯)-加氢(异辛烯加氢成异辛烷) | 加氢(双烯烃选择性加氢成单烯烃)-异构(1-丁烯异构化为2- 丁烯)-烷基化(异丁烷和异丁烯摩尔反应) |
催化剂 | 树脂催化剂,反应条件温和 | 液体酸催化剂,具有腐蚀性、毒性 |
工艺特点 | 无需设定异丁烷量 | 较严格的烷烯比 |
增加加氢工段可代替MTBE装置 | 工业化应用相对广泛 | |
辛烷值高 | 更加绿色环保 | |
产品质量 | 异辛烷含量高,辛烷值高(RON=97~103),蒸汽压稍低(11.7kPa) | 异辛烷含量低,辛烷值略低(RON=97~99),蒸汽压略高(31kPa) |
典型工艺 | 技术开发商 | 原料 | 催化剂 | 提高剂 | 产品辛烷值 | |
---|---|---|---|---|---|---|
研究法 | 马达法 | |||||
Alkylate 100SM | Lyondel/Aker Kvaerner | 混合C4 | 耐高温树脂催化剂 | 叔丁醇或仲丁醇 | 101 | 97 |
CDIsoehter | Snamprogett/CDTECH | 混合C4 | 耐高温树脂催化剂 | — | 97~103 | 94~98 |
InAlk | UOP | 异丁烯 | 固体磷酸催化剂或阳离子交换树脂 | 低碳醇 | 97 | 101 |
NexOctane | Fortum/Kellogg | 混合C4 | 耐高温树脂催化剂 | 叔丁醇 | 99 | 96 |
OilHyd | 上海石化院/兰州石化公司 | 混合C4 | 固体磷酸催化剂 | — | 100 | 99 |
齐鲁石化C4叠合工艺 | 中国石化齐鲁研究院 | 混合C4 | 阳离子交换树脂 | — | 99.7 | 93.7 |
石科院异丁烯叠合工艺 | 中国石化石科院 | 混合C4 | 固体酸催化剂 | — | 100 | 99 |
典型工艺 | 技术开发商 | 原料 | 催化剂 | 提高剂 | 产品辛烷值 | |
---|---|---|---|---|---|---|
研究法 | 马达法 | |||||
Alkylate 100SM | Lyondel/Aker Kvaerner | 混合C4 | 耐高温树脂催化剂 | 叔丁醇或仲丁醇 | 101 | 97 |
CDIsoehter | Snamprogett/CDTECH | 混合C4 | 耐高温树脂催化剂 | — | 97~103 | 94~98 |
InAlk | UOP | 异丁烯 | 固体磷酸催化剂或阳离子交换树脂 | 低碳醇 | 97 | 101 |
NexOctane | Fortum/Kellogg | 混合C4 | 耐高温树脂催化剂 | 叔丁醇 | 99 | 96 |
OilHyd | 上海石化院/兰州石化公司 | 混合C4 | 固体磷酸催化剂 | — | 100 | 99 |
齐鲁石化C4叠合工艺 | 中国石化齐鲁研究院 | 混合C4 | 阳离子交换树脂 | — | 99.7 | 93.7 |
石科院异丁烯叠合工艺 | 中国石化石科院 | 混合C4 | 固体酸催化剂 | — | 100 | 99 |
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